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Optimal high-throughput virtual screening pipeline for efficient selection of redox-active organic materials

Journal Article · · iScience
 [1];  [2];  [2];  [2];  [3]
  1. Brookhaven National Laboratory (BNL), Upton, NY (United States)
  2. Georgia Institute of Technology, Atlanta, GA (United States)
  3. Brookhaven National Laboratory (BNL), Upton, NY (United States); Texas A & M University, College Station, TX (United States)

As global interest in renewable energy continues to increase, there has been a pressing need for developing novel energy storage devices based on organic electrode materials that can overcome the shortcomings of the current lithium-ion batteries. One critical challenge for this quest is to find materials whose redox potential (RP) meets specific design targets. In this study, we propose a computational framework for addressing this challenge through the effective design and optimal operation of a high-throughput virtual screening (HTVS) pipeline that enables rapid screening of organic materials that satisfy the desired criteria. Starting from a high-fidelity model for estimating the RP of a given material, we show how a set of surrogate models with different accuracy and complexity may be designed to construct a highly accurate and efficient HTVS pipeline. We demonstrate that the proposed HTVS pipeline construction and operation strategies substantially enhance the overall screening throughput.

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC); National Science Foundation (NSF)
Grant/Contract Number:
SC0012704
OSTI ID:
2470302
Journal Information:
iScience, Journal Name: iScience Journal Issue: 1 Vol. 26; ISSN 2589-0042
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (51)

Organic Electrode Materials for Rechargeable Lithium Batteries journal May 2012
Organic Cathode Materials for Lithium‐Ion Batteries: Past, Present, and Future journal November 2020
Engineering of a high-throughput screening system to identify cellulosic biomass, pretreatments, and enzyme formulations that enhance sugar release journal February 2010
Electrochemical Properties of Boron‐Doped Fullerene Derivatives for Lithium‐Ion Battery Applications journal February 2018
Systematic Molecular Design of Ketone Derivatives of Aromatic Molecules for Lithium‐Ion Batteries: First‐Principles DFT Modeling journal February 2017
Jaguar: A high-performance quantum chemistry software program with strengths in life and materials sciences journal July 2013
Computation of equilibrium oxidation and reduction potentials for reversible and dissociative electron-transfer reactions in solution journal July 2004
On nearsightedness in metallic systems for O ( N ) Density Functional Theory calculations: A case study on aluminum journal July 2017
Identifying novel factor XIIa inhibitors with PCA-GA-SVM developed vHTS models journal November 2017
Electrochemical and electronic properties of nitrogen doped fullerene and its derivatives for lithium-ion battery applications journal March 2018
Organic electrode materials for fast-rate, high-power battery applications journal February 2021
Molecular structure–redox potential relationship for organic electrode materials: density functional theory–Machine learning approach journal September 2020
First-Principles High-Throughput Screening Pipeline for Nonlinear Optical Materials: Application to Borates journal July 2020
High-Density Lithium-Ion Energy Storage Utilizing the Surface Redox Reactions in Folded Graphene Films journal April 2015
High-Throughput Virtual Screening and Validation of a SARS-CoV-2 Main Protease Noncovalent Inhibitor journal November 2021
Density Functional Theory Modeling-Assisted Investigation of Thermodynamics and Redox Properties of Boron-Doped Corannulenes for Cathodes in Lithium-Ion Batteries journal May 2018
Accurate Multiobjective Design in a Space of Millions of Transition Metal Complexes with Neural-Network-Driven Efficient Global Optimization journal March 2020
Ab Initio Calculations of the Redox Potentials of Additives for Lithium-Ion Batteries and Their Prediction through Machine Learning journal July 2018
Reoptimization of MDL Keys for Use in Drug Discovery journal November 2002
Design and Evaluation of a Molecular Fingerprint Involving the Transformation of Property Descriptor Values into a Binary Classification Scheme journal May 2003
Molecular Similarity Searching Using Atom Environments, Information-Based Feature Selection, and a Naïve Bayesian Classifier journal January 2004
LINGO, an Efficient Holographic Text Based Method To Calculate Biophysical Properties and Intermolecular Similarities journal February 2005
Similarity Searching of Chemical Databases Using Atom Environment Descriptors (MOLPRINT 2D):  Evaluation of Performance journal September 2004
SMIfp (SMILES fingerprint) Chemical Space for Virtual Screening and Visualization of Large Databases of Organic Molecules journal July 2013
Chemical Similarity Using Geometric Atom Pair Descriptors
  • Sheridan, Robert P.; Miller, Michael D.; Underwood, Dennis J.
  • Journal of Chemical Information and Computer Sciences, Vol. 36, Issue 1 https://doi.org/10.1021/ci950275b
journal January 1996
Chemical Fragment Generation and Clustering Software journal January 1997
In silico Design of Porous Polymer Networks: High-Throughput Screening for Methane Storage Materials journal March 2014
First-Principles Density Functional Theory Modeling of Li Binding: Thermodynamics and Redox Properties of Quinone Derivatives for Lithium-Ion Batteries journal February 2016
Structural Interaction Fingerprint (SIFt):  A Novel Method for Analyzing Three-Dimensional Protein−Ligand Binding Interactions journal January 2004
Accelerating Electrolyte Discovery for Energy Storage with High-Throughput Screening journal January 2015
Differential Evolution – A Simple and Efficient Heuristic for global Optimization over Continuous Spaces journal January 1997
Efficient Global Optimization of Expensive Black-Box Functions journal January 1998
Efficient search of compositional space for hybrid organic–inorganic perovskites via Bayesian optimization journal September 2018
A high-throughput pipeline for validation of antibodies journal October 2018
RyR1-targeted drug discovery pipeline integrating FRET-based high-throughput screening and human myofiber dynamic Ca2+ assays journal February 2020
Thermodynamic and redox properties of graphene oxides for lithium-ion battery applications: a first principles density functional theory modeling approach journal January 2016
Self-polymerized dopamine as an organic cathode for Li- and Na-ion batteries journal January 2017
Application of DFT-based machine learning for developing molecular electrode materials in Li-ion batteries journal January 2018
Boron-doped coronenes with high redox potential for organic positive electrodes in lithium-ion batteries: a first-principles density functional theory modeling study journal January 2018
Organic small molecules and polymers as an electrode material for rechargeable lithium ion batteries journal January 2018
Computational electrochemistry: aqueous one-electron oxidation potentials for substituted anilines journal January 2000
Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials journal January 2011
Towards sustainable and versatile energy storage devices: an overview of organic electrode materials journal January 2013
Self‐Consistent Molecular‐Orbital Methods. IX. An Extended Gaussian‐Type Basis for Molecular‐Orbital Studies of Organic Molecules journal January 1971
The Perdew–Burke–Ernzerhof exchange-correlation functional applied to the G2-1 test set using a plane-wave basis set journal June 2005
Solar fuels photoanode materials discovery by integrating high-throughput theory and experiment journal March 2017
RNAither, an automated pipeline for the statistical analysis of high-throughput RNAi screens journal January 2009
tcpl: the ToxCast pipeline for high-throughput screening data journal October 2016
Maximum Likelihood from Incomplete Data Via the EM Algorithm journal September 1977
HTPheno: An image analysis pipeline for high-throughput plant phenotyping journal January 2011
Accelerated Atomistic Modeling of Solid-State Battery Materials With Machine Learning journal June 2021

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