Multi-technique structural analysis of zinc carboxylates (soaps)

Wagner, Molly; Pigliapochi, Roberta; Di Tullio, Valeria; Catalano, Jaclyn; Zumbulyadis, Nicholas; Centeno, Silvia A.; Wang, Xiaoling; Chen, Kuizhi; Hung, Ivan; Gan, Zhehong; Dworzak, Michael R.; Yap, Glenn A.; Dybowski, Cecil

doi:10.1039/d3dt00184a

Multi-technique structural analysis of zinc carboxylates (soaps)

Journal Article · Sat Apr 15 00:00:00 EDT 2023 · Dalton Transactions

DOI:https://doi.org/10.1039/d3dt00184a· OSTI ID:2469933

^[1]; Pigliapochi, Roberta ^[2]; Di Tullio, Valeria ^[3]; Catalano, Jaclyn ^[4]; Zumbulyadis, Nicholas ^[5]; Centeno, Silvia A. ^[6]; Wang, Xiaoling ^[7]; Chen, Kuizhi ^[7]; ^[7]; ^[7]; Dworzak, Michael R. ^[5]; ^[5]; ^[5]

Univ. of Delaware, Newark, DE (United States); Ames Lab., and Iowa State Univ., Ames, IA (United States)
Univ. of Delaware, Newark, DE (United States); Metropolitan Museum of Art, New York, NY (United States); City Univ. of New York (CUNY), NY (United States)
National Council of Research, Rome (Italy). Institute of Heritage Science
Montclair State University, Montclair, NJ (United States)
Univ. of Delaware, Newark, DE (United States)
Metropolitan Museum of Art, New York, NY (United States)
Florida State Univ., Tallahassee, FL (United States). National High Magnetic Field Lab. (MagLab)

A series of medium- and long-chain zinc carboxylates (zinc octanoate, zinc nonanoate, zinc decanoate, zinc undecanoate, zinc dodecanoate, zinc pivalate, zinc stearate, zinc palmitate, zinc oleate, and zinc azelate) was analyzed by ultra-high-field ⁶⁷Zn NMR spectroscopy up to 35.2 T, as well as ¹³C NMR and FTIR spectroscopy. We also report the single-crystal X-ray diffraction structures of zinc nonanoate, zinc decanoate, and zinc oleate—the first long-chain carboxylate single-crystals to be reported for zinc. The NMR and X-ray diffraction data suggest that the carboxylates exist in three distinct geometric groups, based on structural and spectroscopic parameters. The ssNMR results presented here present a future for dynamic nuclear polarization (DNP)-NMR-based minimally invasive methods for testing artwork for the presence of zinc carboxylates.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE; National Science Foundation (NSF); National Institutes of Health (NIH)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 2469933

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 18 Vol. 52; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Multi-technique structural analysis of zinc carboxylates (soaps)

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