Quasi-one-dimensional Pb5Re3O15: A 5d realization of the Heisenberg antiferromagnetic spin-1/2 chain

Powderly, Kelly M.; Zhang, Qiang; Devlin, Kasey P.; Gui, Xin; Ni, Danrui; Xie, Weiwei; Cava, R. J.

doi:10.1103/physrevmaterials.7.114408

Quasi-one-dimensional Pb5 Re3 O15 : A 5d realization of the Heisenberg antiferromagnetic spin-1/2 chain

Journal Article · Mon Nov 20 00:00:00 EST 2023 · Physical Review Materials

DOI:https://doi.org/10.1103/physrevmaterials.7.114408· OSTI ID:2455067

^[1]; ^[2]; Devlin, Kasey P. ^[3]; ^[4]; ^[3]; Xie, Weiwei ^[5]; Cava, R. J. ^[3]

Princeton Univ., NJ (United States); Univ. of Illinois at Urbana-Champaign, IL (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Princeton Univ., NJ (United States)
Princeton Univ., NJ (United States); Univ. of Pittsburgh, PA (United States)
Michigan State Univ., East Lansing, MI (United States)

Quasi-one-dimensional (1D) magnetic compounds connect the exact solutions of low-dimensional magnetic geometries, which promise quantum spin liquid behavior and exotic quasiparticles, with real-world materials, in which competing magnetic interactions affect their implementation in quantum information science. Here, the structural determination and quasi-1D magnetic behavior of a previously unreported compound, Pb₅⁢Re₃⁡O₁₅, is presented. Like the anisotropic triangular A₃⁢ReO₅⁢Cl₂ (A = Ba, Sr, Ca) materials, Pb₅⁢Re₃⁡O₁₅ contains [ReO₅] square pyramids inserted into anion-centered quasi-two-dimensional layers and hosts spin-1/2 moments on the Re⁶⁺ ions. Pb₅⁢Re₃⁡O₁₅, however, has a more ideal quasi-1D geometry than the A₃⁢ReO₅⁢Cl₂ materials, with larger interchain distances and interlayer spacing. Quasi-1D magnetic behavior in Pb₅⁢Re₃⁡O₁₅ is confirmed by fitting the temperature-dependent magnetic susceptibility with the Bonner-Fisher model for a spin-1/2 antiferromagnetically coupled chain, yielding an intrachain coupling constant of |J|/k_B=54.5K. Pb₅⁢Re₃⁡O₁₅ is highly insulating at room temperature, and heat capacity data below 10 K reveal a linear-T contribution that suggests the presence of low-temperature spinon excitations. Finally, with a lack of three-dimensional ordering down to at least 0.6 K, Pb₅⁢Re₃⁡O₁₅ is proposed as a model system for studying the quantum magnetism of quasi-1D Heisenberg chains in a real-world 5d¹ antiferromagnetic material.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; SC0022156

OSTI ID:: 2455067

Journal Information:: Physical Review Materials, Journal Name: Physical Review Materials Journal Issue: 11 Vol. 7; ISSN 2475-9953

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

References (40)

Optical Properties and Electronic Structure of Amorphous Germanium Tauc, J.; Grigorovici, R.; Vancu, A. physica status solidi (b), Vol. 15, Issue 2 https://doi.org/10.1002/pssb.19660150224	journal	January 1966
Specific Heats at Low Temperatures Gopal, E. S. R. https://doi.org/10.1007/978-1-4684-9081-7	book	January 1966
Zur Theorie der Metalle: I. Eigenwerte und Eigenfunktionen der linearen Atomkette Bethe, H. Zeitschrift f�r Physik, Vol. 71, Issue 3-4 https://doi.org/10.1007/BF01341708	journal	March 1931
Thermal and magnetic properties of CuSO4.5H2O and CuSeO4.5H2O below 1°K Miedema, A. R.; Van Kempen, H.; Haseda, T. Physica, Vol. 28, Issue 2 https://doi.org/10.1016/0031-8914(62)90098-8	journal	February 1962
The susceptibilities of the two magnetic systems in CuSO4.5H2O between 4.2°K and 0.3°K Wittekoek, S.; Poulis, N. J.; Miedema, A. R. Physica, Vol. 30, Issue 5 https://doi.org/10.1016/0031-8914(64)90237-X	journal	May 1964
Crystal structure of low temperature form of Bi6V3O16 determined by Rietveld refinement of synchrotron radiation powder diffraction data: A new mixed valence Aurivillius phase Joubert, O.; Jouanneaux, A.; Ganne, M. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 97, Issue 1-4 https://doi.org/10.1016/0168-583X(94)00383-1	journal	May 1995
Chemistry of Quantum Spin Liquids Chamorro, Juan R.; McQueen, Tyrel M.; Tran, Thao T. Chemical Reviews, Vol. 121, Issue 5 https://doi.org/10.1021/acs.chemrev.0c00641	journal	November 2020
Anisotropic Triangular Lattice Realized in Rhenium Oxychlorides A₃ReO₅Cl₂ (A = Ba, Sr) Hirai, Daigorou; Yajima, Takeshi; Nawa, Kazuhiro Inorganic Chemistry, Vol. 59, Issue 14 https://doi.org/10.1021/acs.inorgchem.0c01187	journal	June 2020
How To Correctly Determine the Band Gap Energy of Modified Semiconductor Photocatalysts Based on UV–Vis Spectra Makuła, Patrycja; Pacia, Michał; Macyk, Wojciech The Journal of Physical Chemistry Letters, Vol. 9, Issue 23 https://doi.org/10.1021/acs.jpclett.8b02892	journal	December 2018
Diamagnetic Corrections and Pascal's Constants Bain, Gordon A.; Berry, John F. Journal of Chemical Education, Vol. 85, Issue 4 https://doi.org/10.1021/ed085p532	journal	April 2008
“Visible” 5d Orbital States in a Pleochroic Oxychloride Hirai, Daigorou; Yajima, Takeshi; Nishio-Hamane, Daisuke Journal of the American Chemical Society, Vol. 139, Issue 31 https://doi.org/10.1021/jacs.7b05128	journal	July 2017
Quantum spin transistor with a Heisenberg spin chain Marchukov, O. V.; Volosniev, A. G.; Valiente, M. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13070	journal	October 2016
Fractional spinon excitations in the quantum Heisenberg antiferromagnetic chain Mourigal, Martin; Enderle, Mechthild; Klöpperpieper, Axel Nature Physics, Vol. 9, Issue 7 https://doi.org/10.1038/nphys2652	journal	June 2013
Distinct spinon and holon dispersions in photoemission spectral functions from one-dimensional SrCuO2 Kim, B. J.; Koh, H.; Rotenberg, E. Nature Physics, Vol. 2, Issue 6 https://doi.org/10.1038/nphys316	journal	May 2006
Probing multi-spinon excitations outside of the two-spinon continuum in the antiferromagnetic spin chain cuprate Sr2CuO3 Schlappa, J.; Kumar, U.; Zhou, K. J. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-07838-y	journal	December 2018
Tomonaga–Luttinger liquid behavior and spinon confinement in YbAlO3 Wu, L. S.; Nikitin, S. E.; Wang, Z. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08485-7	journal	February 2019
Multiple fermion scattering in the weakly coupled spin-chain compound YbAlO3 Nikitin, S. E.; Nishimoto, S.; Fan, Y. Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-23585-z	journal	June 2021
Coexistence of metallic and nonmetallic properties in the pyrochlore Lu2Rh2O7 Hallas, Alannah M.; Sharma, Arzoo Z.; Mauws, Cole npj Quantum Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s41535-019-0148-1	journal	March 2019
Conduction in non-crystalline systems V. Conductivity, optical absorption and photoconductivity in amorphous semiconductors Davis, E. A.; Mott, N. F. Philosophical Magazine, Vol. 22, Issue 179 https://doi.org/10.1080/14786437008221061	journal	November 1970
Spin wave energy dispersion in KCuF ₃ : a nearly one-dimensional spin- ¹ / ₂ antiferromagnet Hutchings, M. T.; Milne, J. M.; Ikeda, H. Journal of Physics C: Solid State Physics, Vol. 12, Issue 18 https://doi.org/10.1088/0022-3719/12/18/008	journal	September 1979
Spangolite: ans= 1/2 maple leaf lattice antiferromagnet? Fennell, T.; Piatek, J. O.; Stephenson, R. A. Journal of Physics: Condensed Matter, Vol. 23, Issue 16 https://doi.org/10.1088/0953-8984/23/16/164201	journal	April 2011
Linear Magnetic Chains with Anisotropic Coupling Bonner, Jill C.; Fisher, Michael E. Physical Review, Vol. 135, Issue 3A https://doi.org/10.1103/PhysRev.135.A640	journal	August 1964
NMR, magnetization, and heat capacity studies of the uniform spin- 1 2 chain compound Bi 6 V 3 O 16 Chakrabarty, T.; Heinmaa, I.; Verchenko, V. Yu. Physical Review B, Vol. 100, Issue 9 https://doi.org/10.1103/PhysRevB.100.094431	journal	September 2019
Spinon excitations in the quasi-one-dimensional S = 1 2 chain compound C s 4 CuS b 2 C l 12 Tran, Thao T.; Pocs, Chris A.; Zhang, Yubo Physical Review B, Vol. 101, Issue 23 https://doi.org/10.1103/PhysRevB.101.235107	journal	June 2020
Quasi-one-dimensional magnetism in the spin- 1 2 antiferromagnet BaNa 2 Cu ( VO 4 ) 2 Sebastian, Sebin J.; Somesh, K.; Nandi, M. Physical Review B, Vol. 103, Issue 6 https://doi.org/10.1103/PhysRevB.103.064413	journal	February 2021
Infrared investigation of the broken-symmetry ground state in GeCuO 3 Musfeldt, J. L.; Wang, Y. J.; Jandl, S. Physical Review B, Vol. 54, Issue 1 https://doi.org/10.1103/PhysRevB.54.469	journal	July 1996
Magnetic moment of a spinon and thermodynamic properties of the one-dimensional Heisenberg model McRae, W.; Sushkov, O. P. Physical Review B, Vol. 58, Issue 1 https://doi.org/10.1103/PhysRevB.58.62	journal	July 1998
Thermal conductivity and specific heat of the linear chain cuprate Sr 2 CuO 3 : Evidence for thermal transport via spinons Sologubenko, A. V.; Felder, E.; Giannò, K. Physical Review B, Vol. 62, Issue 10 https://doi.org/10.1103/PhysRevB.62.R6108	journal	September 2000
Antiferromagnetic ordering and dipolar interactions of YbAlO 3 Wu, L. S.; Nikitin, S. E.; Brando, M. Physical Review B, Vol. 99, Issue 19 https://doi.org/10.1103/PhysRevB.99.195117	journal	May 2019
‘‘Spinon gas’’ description of the S =1/2 Heisenberg chain with inverse-square exchange: Exact spectrum and thermodynamics Haldane, F. D. M. Physical Review Letters, Vol. 66, Issue 11 https://doi.org/10.1103/PhysRevLett.66.1529	journal	March 1991
Observation of the spin-Peierls transition in linear Cu 2 + (spin-1/2) chains in an inorganic compound CuGeO 3 Hase, Masashi; Terasaki, Ichiro; Uchinokura, Kunimitsu Physical Review Letters, Vol. 70, Issue 23 https://doi.org/10.1103/PhysRevLett.70.3651	journal	June 1993
Unbound spinons in the S =1/2 antiferromagnetic chain KCuF 3 Tennant, D. A.; Perring, T. G.; Cowley, R. A. Physical Review Letters, Vol. 70, Issue 25 https://doi.org/10.1103/PhysRevLett.70.4003	journal	June 1993
Magnetic Susceptibility of Ideal Spin 1 / 2 Heisenberg Antiferromagnetic Chain Systems, Sr 2 CuO 3 and SrCuO 2 Motoyama, N.; Eisaki, H.; Uchida, S. Physical Review Letters, Vol. 76, Issue 17 https://doi.org/10.1103/PhysRevLett.76.3212	journal	April 1996
Quantum Communication through an Unmodulated Spin Chain Bose, Sougato Physical Review Letters, Vol. 91, Issue 20 https://doi.org/10.1103/PhysRevLett.91.207901	journal	November 2003
OLEX2 : a complete structure solution, refinement and analysis program Dolomanov, Oleg V.; Bourhis, Luc J.; Gildea, Richard J. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889808042726	journal	January 2009
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811038970	journal	October 2011
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
Formation of One-Dimensional Antiferromagnet in KCuF₃ with the Perovskite Structure Kadota, Shozo; Yamada, Isao; Yoneyama, Shin Journal of the Physical Society of Japan, Vol. 23, Issue 4 https://doi.org/10.1143/JPSJ.23.751	journal	October 1967
Low-Temperature Specific Heat of Spin-1/2 Anisotropic Heisenberg Ring Takahashi, M. Progress of Theoretical Physics, Vol. 50, Issue 5 https://doi.org/10.1143/PTP.50.1519	journal	November 1973
One-dimensionalization by Geometrical Frustration in the Anisotropic Triangular Lattice of the 5d Quantum Antiferromagnet Ca₃ReO₅Cl₂ Hirai, Daigorou; Nawa, Kazuhiro; Kawamura, Mitsuaki Journal of the Physical Society of Japan, Vol. 88, Issue 4 https://doi.org/10.7566/JPSJ.88.044708	journal	April 2019

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