Intricate Magnetic Landscape in Antiferromagnetic Kagome Metal TbTi3Bi4 and Interplay with Ln2–xTi6+xBi9 (Ln: Tb···Lu) Shurikagome Metals

Ortiz, Brenden R.; Zhang, Heda; Górnicka, Karolina; Parker, David S.; Samolyuk, German D.; Yang, Fazhi; Miao, Hu; Lu, Qiangsheng; Moore, Robert G.; May, Andrew F.; McGuire, Michael A.

doi:10.1021/acs.chemmater.4c01449

Intricate Magnetic Landscape in Antiferromagnetic Kagome Metal TbTi₃Bi₄ and Interplay with Ln_2–xTi_6+xBi₉ (Ln: Tb···Lu) Shurikagome Metals

Journal Article · Sun Aug 11 04:00:00 EDT 2024 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.4c01449· OSTI ID:2438874

^[1]; Zhang, Heda ^[1]; Górnicka, Karolina ^[1]; ^[1]; ^[1]; ^[1]; ^[1]; ^[1]; ^[1]; ^[1]; ^[1]

Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Here we present the discovery and characterization of the kagome metal TbTi₃Bi₄ in tandem with a new series of compounds, the Ln_2–xTi_6+xBi₉ (Ln: Tb–Lu) shurikagome metals. We previously reported on the growth of the LnTi₃Bi₄ (Ln: La–Gd³⁺, Eu²⁺, Yb²⁺) family, a chemically diverse and exfoliable series of kagome metals with complex and highly anisotropic magnetism. However, unlike the La–Gd analogs, TbTi₃Bi₄ cannot be synthesized by our previous methodology due to phase competition with crystals of Ln_2–xTi_6+xBi₉ (x ~ 1.7–1.2). Here we discuss the phase competition between the LnTi₃Bi₄ and Ln_2–xTi_6+xBi₉ families, helping to frame the difficulty in synthesizing LnTi₃Bi₄ compounds with small Ln species and providing a strategy to circumvent the formation of Ln_2–xTi_6+xBi₉. Detailed characterization of the magnetic and electronic transport properties on single crystals of TbTi₃Bi₄ reveals a highly complex landscape of magnetic phases arising from an antiferromagnetic ground state. A series of metamagnetic transitions creates at least 5 unique magnetic phase pockets, including a 1/3 and 2/3 magnetization plateau. Further, the system exhibits an intimate connection between the magnetism and magnetotransport, exhibiting sharp switching from positive (+40%) to negative magnetoresistance (–50%). Like the LnTi₃Bi₄ kagome metals, the Ln_2–xTi_6+xBi₉ family exhibits quasi-2D networks of titanium and chains of rare earth. Finally, we present the structures and some basic magnetic properties of the Ln_2–xTi_6+xBi₉ family alongside our characterization of the newly discovered TbTi₃Bi₄.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); National Quantum Information Science (QIS) Research Centers (United States). The Quantum Science Center (QSC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2438874

Journal Information:: Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 16 Vol. 36; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Intricate Magnetic Landscape in Antiferromagnetic Kagome Metal TbTi₃Bi₄ and Interplay with Ln_2–xTi_6+xBi₉ (Ln: Tb···Lu) Shurikagome Metals