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Color‐Stable, All‐Phosphorescent White Organic Light Emitting Diodes Using the Polariton‐Enhanced Purcell Effect

Journal Article · · Advanced Functional Materials
 [1];  [1];  [2]
  1. Department of Physics University of Michigan Ann Arbor MI 48109 USA
  2. Department of Physics University of Michigan Ann Arbor MI 48109 USA, Applied Physics Program University of Michigan Ann Arbor MI 48109 USA, Department of Electrical Engineering and Computer Science University of Michigan Ann Arbor MI 48109 USA, Department of Materials Science and Engineering University of Michigan Ann Arbor MI 48109 USA

Abstract

The short operational lifetimes of high efficiency phosphorescent organic blue light emitting devices (PHOLEDs) has limited their use in displays and lighting. Previously, this problem has been avoided by using less efficient fluorescent blue devices in separately biased red, green, and blue emissive elements to achieve stable full color emission. However, the operational lifetime of blue phosphorescent OLEDs has been significantly improved through the utilization of the plasmon‐exciton‐polariton‐enhanced (PEP) Purcell effect. Here, a white emitting PHOLED comprising stacked red, green, and blue elements is demonstrated that exploits PEPs to extend the operational lifetime of the blue element such that all emissive layers degrade at the same rate. The device features white light emission with an external quantum efficiency of 19.1 ± 0.4%, luminous power efficiency of 13.3 ± 0.3 lm W −1 at a luminance of 1000 cd m −2 when measured over 4π solid angle, with a color rendering index of 76 unchanged throughout the device aging to 70% of its initial luminance, T 70 . A 2.9 times enhancement in the operational lifetime of the Purcell‐enhanced device is achieved to yield T 70 = 2900 ± 100 h for an initial luminance of 1000 cd m −2 , compared to devices lacking this enhancement with T 70 = 1000 ± 100 h.

Sponsoring Organization:
USDOE
Grant/Contract Number:
NONE; EE0009688
OSTI ID:
2438644
Alternate ID(s):
OSTI ID: 2438645
OSTI ID: 2441280
Journal Information:
Advanced Functional Materials, Journal Name: Advanced Functional Materials Journal Issue: 52 Vol. 34; ISSN 1616-301X
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
English

References (24)

Extremely Efficient White Organic Light-Emitting Diodes for General Lighting journal September 2014
White Organic LED with a Luminous Efficacy Exceeding 100 lm W −1 without Light Out-Coupling Enhancement Techniques journal June 2017
Exciton-Adjustable Interlayers for High Efficiency, Low Efficiency Roll-Off, and Lifetime Improved Warm White Organic Light-Emitting Diodes (WOLEDs) Based on a Delayed Fluorescence Assistant Host journal January 2018
Efficient, Color‐Stable, and Long‐Lived White Organic Light‐Emitting Diodes Utilizing Phosphorescent Molecular Aggregates journal February 2023
High-Quality White OLEDs with Comparable Efficiencies to LEDs journal February 2018
Recent advances in white organic light-emitting diodes journal September 2016
Understanding molecular fragmentation in blue phosphorescent organic light-emitting devices journal January 2019
Reliable, All-Phosphorescent Stacked White Organic Light Emitting Devices with a High Color Rendering Index journal November 2017
Ultrathin Organic Films Grown by Organic Molecular Beam Deposition and Related Techniques journal October 1997
White organic light-emitting diodes with fluorescent tube efficiency journal May 2009
Hot excited state management for long-lived blue phosphorescent organic light-emitting diodes journal May 2017
Tenfold increase in the lifetime of blue phosphorescent organic light-emitting diodes journal September 2014
Stable blue phosphorescent organic LEDs that use polariton-enhanced Purcell effects journal December 2023
Efficient white phosphorescent organic light-emitting diodes using ultrathin emissive layers (<1 nm) journal April 2018
Nearly 100% internal phosphorescence efficiency in an organic light-emitting device journal November 2001
Stacked white organic light-emitting devices based on a combination of fluorescent and phosphorescent emitters journal July 2006
Intrinsic luminance loss in phosphorescent small-molecule organic light emitting devices due to bimolecular annihilation reactions journal February 2008
Using an ultra-thin non-doped orange emission layer to realize high efficiency white organic light-emitting diodes with low efficiency roll-off journal June 2014
Organic Electronics book August 2020
Weak microcavity effects in organic light-emitting devices journal August 1998
Simplified calculation of dipole energy transport in a multilayer stack using dyadic Green’s functions journal January 2007
Organic Light-Emitting Devices for Solid-State Lighting journal July 2008
54.3: Distinguished Paper: White Stacked OLED with 35 lm/W and 100,000 Hours Lifetime at 1000 cd/m2 for Display and Lighting Applications journal January 2008
52.2: Hybrid Tandem White OLEDs with High Efficiency and Long Life‐time for AMOLED Displays and Solid‐State Lighting journal May 2010

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