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From Methane to Methanol: Pd-iC-CeO 2 Catalysts Engineered for High Selectivity via Mechanochemical Synthesis

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.4c04815· OSTI ID:2429737
 [1];  [2];  [3];  [4];  [5];  [6];  [6];  [6];  [7];  [7];  [3];  [8];  [3];  [2];  [1]
  1. Chemistry Division, Brookhaven National Laboratory, Upton, New York 11973, United States
  2. CSIC, Instituto de Catálisis y Petroleoquímica, C/Marie Curie 2, 28049 Madrid, Spain
  3. Polytechnic Department, University of Udine and INSTM, Via del Cotonificio 108, 33100 Udine, Italy
  4. CSIC, Instituto de Catálisis y Petroleoquímica, C/Marie Curie 2, 28049 Madrid, Spain, Universitat Politècnica de València, Camí de Vera s/n, 46022 València, Spain
  5. Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, United States
  6. National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, New York 11973, United States
  7. Ames National Laboratory, Iowa State University, Ames, Iowa 50011, United States
  8. Chemistry Division, Brookhaven National Laboratory, Upton, New York 11973, United States, Department of Chemistry, State University of New York Stony Brook, Stony Brook, New York 11794, United States
Not Available
Research Organization:
Ames Laboratory (AMES), Ames, IA (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)
Grant/Contract Number:
AC02-07CH11358; SC0012704
OSTI ID:
2429737
Alternate ID(s):
OSTI ID: 2438331
OSTI ID: 2440528
OSTI ID: 2447900
Report Number(s):
BNL--226055-2024-JAAM; IS-J--11,413
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 38 Vol. 146; ISSN 0002-7863
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (47)

Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold-Palladium Alloy Nanoparticles journal December 2012
The Direct Catalytic Oxidation of Methane to Methanol-A Critical Assessment journal November 2017
Outstanding Methane Oxidation Performance of Palladium-Embedded Ceria Catalysts Prepared by a One-Step Dry Ball-Milling Method journal July 2018
Effect of the damping function in dispersion corrected density functional theory journal March 2011
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal July 1996
Low-temperature water-gas shift reaction over Cu- and Ni-loaded cerium oxide catalysts journal August 2000
Tuning the hydrogenation of CO2 to CH4 over mechano-chemically prepared palladium supported on ceria journal June 2023
CeO2 supported Pd dimers boosting CO2 hydrogenation to ethanol journal August 2021
Low temperature selective oxidation of methane using gold-palladium colloids journal February 2020
Low Temperature Activation of Methane on Metal-Oxides and Complex Interfaces: Insights from Surface Science journal July 2020
Direct Conversion of Methane to Methanol under Mild Conditions over Cu-Zeolites and beyond journal January 2017
Identification of Highly Selective Surface Pathways for Methane Dry Reforming Using Mechanochemical Synthesis of Pd–CeO2 journal October 2022
Individual Heat of Adsorption of Adsorbed CO Species on Palladium and Pd–Sn Nanoparticles Supported on Al 2 O 3 by Using Temperature-Programmed Adsorption Equilibrium Methods journal March 2016
Mechanistic Complexity of Methane Oxidation with H 2 O 2 by Single-Site Fe/ZSM-5 Catalyst journal July 2018
Methane-to-Methanol: Activity Descriptors in Copper-Exchanged Zeolites for the Rational Design of Materials journal May 2019
Selective Activation of Methane on Single-Atom Catalyst of Rhodium Dispersed on Zirconia for Direct Conversion journal November 2017
Direct Conversion of Methane to Methanol on Ni-Ceria Surfaces: Metal–Support Interactions and Water-Enabled Catalytic Conversion by Site Blocking journal May 2018
Bioinspired Metal–Organic Framework Catalysts for Selective Methane Oxidation to Methanol journal December 2018
Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts journal November 2017
High-efficiency direct methane conversion to oxygenates on a cerium dioxide nanowires supported rhodium single-atom catalyst journal February 2020
Memory-dictated dynamics of single-atom Pt on CeO2 for CO oxidation journal May 2023
A US perspective on closing the carbon cycle to defossilize difficult-to-electrify segments of our economy journal May 2024
Highly selective oxidation of methane to methanol at ambient conditions by titanium dioxide-supported iron species journal November 2018
Misconceptions and challenges in methane-to-methanol over transition-metal-exchanged zeolites journal May 2019
The HOOH–HOO complex. A matrix isolation study journal January 2004
The influence of water and pH on adsorption and oxidation of CO on Pd/Al 2 O 3 —an investigation by attenuated total reflection infrared spectroscopy journal January 2009
Low temperature selective oxidation of methane to methanol using titania supported gold palladium copper catalysts journal January 2016
Pd–Au bimetallic catalysts: understanding alloy effects from planar models and (supported) nanoparticles journal January 2012
Towards understanding the electronic structure of Fe-doped CeO2 nanoparticles with X-ray spectroscopy journal January 2013
A climbing image nudged elastic band method for finding saddle points and minimum energy paths journal December 2000
The application of infrared spectroscopy to probe the surface morphology of alumina-supported palladium catalysts journal November 2005
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu journal April 2010
Special points for Brillouin-zone integrations journal June 1976
Ab initiomolecular dynamics for liquid metals journal January 1993
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium journal May 1994
Projector augmented-wave method journal December 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal October 1996
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study journal January 1998
From ultrasoft pseudopotentials to the projector augmented-wave method journal January 1999
Generalized Gradient Approximation Made Simple journal October 1996
Iterative minimization techniques for ab initio total-energy calculations: molecular dynamics and conjugate gradients journal October 1992
Ceria Maintains Smaller Metal Catalyst Particles by Strong Metal-Support Bonding journal August 2010
Selective anaerobic oxidation of methane enables direct synthesis of methanol journal May 2017
Low-temperature activation of methane on the IrO 2 (110) surface journal April 2017
Aqueous Au-Pd colloids catalyze selective CH 4 oxidation to CH 3 OH with O 2 under mild conditions journal September 2017
Hydrophobic zeolite modification for in situ peroxide formation in methane oxidation to methanol journal January 2020
Water-promoted interfacial pathways in methane oxidation to methanol on a CeO 2 -Cu 2 O catalyst journal April 2020