Evaluating the Physisorption and Chemisorption of Iodine on Bismuth-Functionalized Carbon Foams

Baskaran, Karthikeyan; Ali, Muhammad; Riley, Brian J.; Zharov, Ilya; Carlson, Krista

doi:10.1021/acsmaterialslett.2c00466

Evaluating the Physisorption and Chemisorption of Iodine on Bismuth-Functionalized Carbon Foams

Journal Article · Thu Aug 11 00:00:00 EDT 2022 · ACS Materials Letters

DOI:https://doi.org/10.1021/acsmaterialslett.2c00466· OSTI ID:2438065

Baskaran, Karthikeyan ^[1]; Ali, Muhammad ^[1]; ^[2]; Zharov, Ilya ^[3]; Carlson, Krista ^[1]

University of Nevada, Reno, NV (United States)
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
University of Utah, Salt Lake City, UT (United States)

Bismuth-containing carbon materials have been shown to be highly promising sorbents for the capture of radioiodine. However, there is still a need to understand the effects of carbon and bismuth on the iodine sorption mechanism. In this study, we show the relationship between the physical and chemical sorption of iodine under different bismuth loading conditions. Here, highly porous and non-friable conductive carbon foams were prepared and bismuth was electrodeposited to provide strong iodine binding sites. For pure carbon foams, equal ratios of physisorbed and chemisorbed iodine-carbon phases were detected before desorption. As the concentration of bismuth increased, the chemisorption between bismuth and iodine dominated the total capture mechanism and physisorption was almost completely eliminated. Additionally, chemisorption of iodine depended upon the size and specific surface area of the bismuth particles present within the framework of the foam.

View Accepted Manuscript (DOE)

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Environmental Management (EM); USDOE Office of Nuclear Energy (NE), Nuclear Energy University Program (NEUP)

Grant/Contract Number:: 89304021CEM000014; AC05-76RL01830; NE0008900

OSTI ID:: 2438065

Report Number(s):: PNNL-SA--173737

Journal Information:: ACS Materials Letters, Journal Name: ACS Materials Letters Journal Issue: 9 Vol. 4; ISSN 2639-4979

Publisher:: ACS PublicationsCopyright Statement

Country of Publication:: United States

Language:: English

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