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Circular Plastics Technologies: Depolymerization of Polymers Into Parent Monomers

Journal Article · · Physical Sciences Reviews
While most commodity plastics were not designed to easily depolymerize, some common plastics can be broken down into their parent monomers in the presence of heat, pressure, catalysts, and/or solvent. Here, we provide a high-level overview of the depolymerization technologies that have been studied and/or scaled as promising monomer-loop recycling processes for selective plastic waste streams. Namely, commodity plastics that are considered unzippable/depolymerizable include polyethylene terephthalate, polyamides, polymethyl methacrylate, and polystyrene. Monomer-loop recycling technologies are one of several pathways toward a circular economy for plastics.
Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE National Renewable Energy Laboratory (NREL)
DOE Contract Number:
AC36-08GO28308
OSTI ID:
2429701
Report Number(s):
NREL/JA-2800-90901; MainId:92679; UUID:3ca228e2-c74d-48ee-82c7-8e629f5a8c6e; MainAdminId:73371
Journal Information:
Physical Sciences Reviews, Journal Name: Physical Sciences Reviews Journal Issue: 7 Vol. 9
Country of Publication:
United States
Language:
English

References (88)

Enzymatic Remediation of Polyethylene Terephthalate (PET)–Based Polymers for Effective Management of Plastic Wastes: An Overview journal November 2020
Selective, Sequential, and “One-Pot” Depolymerization Strategies for Chemical Recycling of Commercial Plastics and Mixed Plastics journal July 2022
Structural and functional studies on a thermostable polyethylene terephthalate degrading hydrolase from Thermobifida fusca journal April 2014
A bacterium that degrades and assimilates poly(ethylene terephthalate) journal March 2016
Technical, Economic, and Environmental Comparison of Closed-Loop Recycling Technologies for Common Plastics journal January 2023
Advances and approaches for chemical recycling of plastic waste journal April 2020
Beyond Mechanical Recycling: Giving New Life to Plastic Waste journal June 2020
Catalyzed hydrolysis of polyethylene terephthalate melts journal August 1994
Study on methanolytic depolymerization of PET with supercritical methanol for chemical recycling journal January 2002
Ultrafast Homogeneous Glycolysis of Waste Polyethylene Terephthalate via a Dissolution-Degradation Strategy journal November 2018
Chemical Recycling of Polyethlylene Terephthalate by Glycolysis Using Deep Eutectic Solvents journal October 2019
Two-stage pyrolysis of polystyrene: Pyrolysis oil as a source of fuels or benzene, toluene, ethylbenzene, and xylenes journal February 2020
A pseudo-homogeneous system for PET glycolysis using a colloidal catalyst of graphite carbon nitride in ethylene glycol journal August 2021
Kinetics of Hydrolysis of Poly(ethylene terephthalate) Powder in Sulfuric Acid by a Modified Shrinking-Core Model journal January 2001
Recycling Nylon 6 Carpet to Caprolactam journal June 1999
Depolymerization of PET Bottle via Methanolysis and Hydrolysis book January 2019
Depolymerization of waste poly(methyl methacrylate) scraps and purification of depolymerized products journal February 2019
Poly(ionic liquid)s as efficient and recyclable catalysts for methanolysis of PET journal May 2022
Monomer recovery by pyrolysis of poly(methyl methacrylate) (PMMA) journal July 1991
Enzymatic Surface Hydrolysis of PET: Effect of Structural Diversity on Kinetic Properties of Cutinases from Thermobifida journal June 2011
Sourcing thermotolerant poly(ethylene terephthalate) hydrolase scaffolds from natural diversity journal December 2022
Chemical Kinetics of Polymethyl Methacrylate (PMMA) Decomposition Assessed by a Microwave-Assisted Digestion System journal March 2008
Ultrasmall Cobalt Nanoparticles as a Catalyst for PET Glycolysis: A Green Protocol for Pure Hydroxyethyl Terephthalate Precipitation without Water journal July 2018
Evaluating water miscible deep eutectic solvents (DESs) and ionic liquids as potential lubricants journal January 2014
Enhanced Cutinase-Catalyzed Hydrolysis of Polyethylene Terephthalate by Covalent Fusion to Hydrophobins journal March 2015
Pyrolysis of Polystyrene Waste: A Review journal January 2021
Tailoring cutinase activity towards polyethylene terephthalate and polyamide 6,6 fibers journal March 2007
Microwave assisted ecofriendly recycling of poly (ethylene terephthalate) bottle waste journal December 2008
Poly(ethylene terephthalate) waste and its utilisation: A review journal November 1984
Depolymerization of poly(ethylene terephthalate) resin under pressure journal March 1991
Glycolysis of poly(ethylene terephthalate) (PET) using basic ionic liquids as catalysts journal April 2011
Microwave–metal interaction pyrolysis of polystyrene journal September 2010
Efficient depolymerization and chemical conversion of polyamide 66 to 1,6-hexanediol journal August 2015
Microwave-assisted pyrolysis of polystyrene for aviation oil production journal March 2022
An engineered PET depolymerase to break down and recycle plastic bottles journal April 2020
Isolation of a Novel Cutinase Homolog with Polyethylene Terephthalate-Degrading Activity from Leaf-Branch Compost by Using a Metagenomic Approach journal December 2011
Chemical and biological catalysis for plastics recycling and upcycling journal July 2021
Feedstock recycling of polymers by pyrolysis in a fluidised bed journal September 2004
Fusion of Binding Domains to Thermobifida cellulosilytica Cutinase to Tune Sorption Characteristics and Enhancing PET Hydrolysis journal May 2013
Thermal degradation of poly(methyl methacrylate) (PMMA): modelling of DTG and TG curves journal January 2003
Life cycle assessment of enzymatic poly(ethylene terephthalate) recycling journal January 2022
Pet Waste Management by Chemical Recycling: A Review journal September 2008
Organocatalytic depolymerization of poly(ethylene terephthalate) journal January 2011
Chemical recycling of waste plastics for new materials production journal June 2017
Kinetic Study on Depolymerization of Poly(ethylene terephthalate) with Methanol at High Temperature and Pressure. journal January 1998
Poly(ethylene terephthalate) Recycling and Recovery of Pure Terephthalic Acid. Kinetics of a Phase Transfer Catalyzed Alkaline Hydrolysis journal October 2001
Glycolysis of poly(ethylene terephthalate) catalyzed by ionic liquids journal May 2009
Low-energy catalytic methanolysis of poly(ethyleneterephthalate) journal January 2021
High-efficiency glycolysis of poly(ethylene terephthalate) by sandwich-structure polyoxometalate catalyst with two active sites journal October 2018
Alkali decomposition of poly(ethylene terephthalate) with sodium hydroxide in nonaqueous ethylene glycol: A study on recycling of terephthalic acid and ethylene glycol journal January 1997
Chemical Recycling of Poly(ethylene terephthalate) journal April 1997
Polymeric Materials for Conversion of Electromagnetic Waves from the Sun to Electric Power journal March 2018
Effects of microwave-assisted digestion on decomposition behavior of polymethyl methacrylate (PMMA) journal April 2008
Carbon Dioxide Synergistic Enhancement of Supercritical Methanol on PET Depolymerization for Chemical Recovery journal May 2022
Recent Developments in the Chemical Recycling of Postconsumer Poly(ethylene terephthalate) Waste journal September 2014
Study of glycolysis of poly(ethylene terephthalate) recycled from postconsumer soft-drink bottles. III. Further investigation journal January 2003
Current knowledge on enzymatic PET degradation and its possible application to waste stream management and other fields journal April 2019
Poly(ethylene terephthalate) recycling and recovery of pure terephthalic acid by alkaline hydrolysis journal January 2002
Glycolysis of poly(ethylene terephthalate) wastes in xylene journal September 1998
Improving the activity and thermostability of PETase from Ideonella sakaiensis through modulating its post-translational glycan modification journal January 2023
Pyrolysis of polystyrene waste in a fluidized-bed reactor to obtain styrene monomer and gasoline fraction journal March 2000
Cutinase-Catalyzed Hydrolysis of Poly(ethylene terephthalate) journal July 2009
Techno-economic, life-cycle, and socioeconomic impact analysis of enzymatic recycling of poly(ethylene terephthalate) journal September 2021
Reductive depolymerization as an efficient methodology for the conversion of plastic waste into value-added compounds journal January 2021
Hydrogenative Depolymerization of Nylons journal July 2020
Characterization and engineering of a two-enzyme system for plastics depolymerization journal September 2020
Catalytic pyrolysis of nylon-6 to recover caprolactam journal June 1998
Pyrolysis of filled PMMA for monomer recovery journal April 2001
Reversibility of the Propagation Reaction in Polymerization Processes and its Manifestation in the Phenomenon of a ‘Ceiling Temperature' journal October 1948
Depolymerization of Technical‐Grade Polyamide 66 and Polyurethane Materials through Hydrogenation journal November 2020
Thermal degradation of PMMA in fluidised beds journal January 2004
A kinetic study of the hydrolytic degradation of polyethylene terephthalate at high temperatures journal April 1993
Design principles for intrinsically circular polymers with tunable properties journal November 2021
Studies on the decomposition behavior of nylon-66 in supercritical water journal March 2004
Characterization and engineering of a plastic-degrading aromatic polyesterase journal April 2018
Kinetics of Hydrolysis of PET Powder in Nitric Acid by a Modified Shrinking-Core Model journal February 1998
Chemical Recycling of Aliphatic Polyamides by Microwave-Assisted Hydrolysis for Efficient Monomer Recovery journal October 2020
Directing Depolymerization of PET with Subcritical and Supercritical Ethanol to Different Monomers through Changes in Operation Conditions journal July 2021
Current State and Perspectives Related to the Polyethylene Terephthalate Hydrolases Available for Biorecycling journal May 2020
Chemical recycling of crosslinked poly(methyl methacrylate) and characterization of polymers produced with the recycled monomer journal June 2018
Screening of commercial enzymes for poly(ethylene terephthalate) (PET) hydrolysis and synergy studies on different substrate sources journal April 2017
Assessing changes on poly(ethylene terephthalate) properties after recycling: Mechanical recycling in laboratory versus postconsumer recycled material journal October 2014
Chemical recycling of poly(methyl methacrylate) by pyrolysis. Potential use of the liquid fraction as a raw material for the reproduction of the polymer journal June 2007
100th Anniversary of Macromolecular Science Viewpoint: Needs for Plastics Packaging Circularity journal September 2020
A novel catalyst for the glycolysis of poly(ethylene terephthalate) journal January 2003
Chemolytic depolymerisation of PET: a review journal January 2021
Catalytic Pyrolysis of Polystyrene over Steel Slag under CO2 Environment journal August 2020
Organocatalysed depolymerisation of PET in a fully sustainable cycle using thermally stable protic ionic salt journal January 2018