Using small building blocks to assemble ultra-complex, multifaceted metal-organic frameworks with zeolitic, mesoporous subnetwork

Li, Jiantang; Sava Gallis, Dorina F.; Guillerm, Vincent; Melliti, Taslim; Luebke, Ryan; Eubank, Jarrod F.; Bhatt, Prashant M.; Jiang, Hao; Bonneau, Mickaele; Belmabkhout, Youssef; Huang, Zhiyuan; Shkurenko, Aleksander; Wojtas, Lukasz; O’Keeffe, Michael; Eddaoudi, Mohamed

doi:10.1016/j.chempr.2023.09.026

Using small building blocks to assemble ultra-complex, multifaceted metal-organic frameworks with zeolitic, mesoporous subnetwork

Journal Article · Mon Oct 23 00:00:00 EDT 2023 · Chem

DOI:https://doi.org/10.1016/j.chempr.2023.09.026· OSTI ID:2428045

Li, Jiantang ^[1]; Sava Gallis, Dorina F. ^[2]; ^[1]; Melliti, Taslim ^[1]; Luebke, Ryan ^[1]; Eubank, Jarrod F. ^[3]; Bhatt, Prashant M. ^[1]; Jiang, Hao ^[1]; Bonneau, Mickaele ^[1]; Belmabkhout, Youssef ^[1]; Huang, Zhiyuan ^[1]; Shkurenko, Aleksander ^[1]; Wojtas, Lukasz ^[3]; O’Keeffe, Michael ^[4]; ^[1]

King Abdullah University of Science and Technology (KAUST), Thuwal (Saudi Arabia)
Univ. of South Florida, Tampa, FL (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Univ. of South Florida, Tampa, FL (United States)
Arizona State Univ., Tempe, AZ (United States)

The assembly of ultra-complex structures from simple building units remains a long-term challenge in chemistry. Using small molecular building blocks (MBBs) in a mixed-ligand approach permitted the assembly of unprecedented metal-organic frameworks (MOFs), M-kum-MOF-1 (M = Y, Tb), exhibiting extra-large mesoporous cavities with small access windows. The ultra-complex cage of M-kum-MOF-1 consists of 240 vertices bridged by 432 edges, leading to a 194 faces-containing tile. This tile exhibits more faces than in any periodic structures (zeolites, MOFs, metal-organic polyhedra [MOPs], etc.) known to date. M-kum-MOF-1 not only possess zeolitic features (anionic framework), but they also contain an underlying wse zeolitic topology, which is observed for the first time.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0003525

OSTI ID:: 2428045

Report Number(s):: SAND--2024-10382J

Journal Information:: Chem, Journal Name: Chem Journal Issue: 2 Vol. 10; ISSN 2451-9294

Publisher:: Cell PressCopyright Statement

Country of Publication:: United States

Language:: English

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Using small building blocks to assemble ultra-complex, multifaceted metal-organic frameworks with zeolitic, mesoporous subnetwork

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