Nitrogen-enriched flexible metal–organic framework for CO 2 adsorption

Lancheros, Andrés; Goswami, Subhadip; Zarate, Ximena; Schott, Eduardo; Hupp, Joseph T.

doi:10.1039/D4DT01457J

Nitrogen-enriched flexible metal–organic framework for CO ₂ adsorption

Journal Article · Mon Jan 01 00:00:00 EST 2024 · Dalton Transactions

DOI:https://doi.org/10.1039/D4DT01457J· OSTI ID:2426979

^[1]; ^[2]; Zarate, Ximena ^[3]; ^[4]; ^[2]

Department of Inorganic Chemistry; Faculty of Chemistry and Pharmacy; UC Energy Center; Center for Research in Nanotechnology and Advanced Materials (CIEN-UC); Pontificia Universidad Católica de Chile; Av. Vicuña Mackenna 4860; Santiago; Chile; ANID – Millennium Science Initiative Program – Millennium Nuclei on Catalytic Process Towards Sustainable Chemistry (CSC); Chile; Department of Chemistry and International Institute for Nanotechnology; Northwestern University; 2145 Sheridan Road; Evanston; Illinois 60208; USA
Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA
Institute of Applied Sciences, Faculty of Engineering, Universidad Autónoma de Chile, Av. Pedro de Valdivia 425, Santiago, Chile
Department of Inorganic Chemistry, Faculty of Chemistry and Pharmacy, UC Energy Center, Center for Research in Nanotechnology and Advanced Materials (CIEN-UC), Pontificia Universidad Católica de Chile, Av. Vicuña Mackenna 4860, Santiago, Chile, ANID – Millennium Science Initiative Program – Millennium Nuclei on Catalytic Process Towards Sustainable Chemistry (CSC), Chile

A novel MOF [Zn ₂ (L)(DMF)] was synthesized showing high crystallinity and stability up to 250 °C. Its nitrogen-rich pyrazole linkers enable good CO ₂ adsorption with a low isosteric enthalpy. Adsorption results were validated by DFT calculations.

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Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: FG02-08ER15967

OSTI ID:: 2426979

Alternate ID(s):: OSTI ID: 2578315

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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