CeO2 Nanoparticle Doping as a Probe of Active Site Speciation in the Catalytic Hydrolysis of Organophosphates

Miura-Stempel, Emily L.; Oregon, Ashley; Harvey, Samantha; De Yoreo, James J.; Chen, Chunlong; Cossairt, Brandi M.

doi:10.1021/acsanm.4c02410

CeO2 Nanoparticle Doping as a Probe of Active Site Speciation in the Catalytic Hydrolysis of Organophosphates

Journal Article · Tue Jun 25 00:00:00 EDT 2024 · ACS Applied Nano Materials

DOI:https://doi.org/10.1021/acsanm.4c02410· OSTI ID:2426959

Miura-Stempel, Emily L. ^[1]; Oregon, Ashley ^[2]; Harvey, Samantha ^[2]; De Yoreo, James J. ^[3]; Chen, Chunlong ^[3]; Cossairt, Brandi M. ^[2]

UNIVERSITY OF WASHINGTON
University of Washington
BATTELLE (PACIFIC NW LAB)

Organophosphate hydrolysis is important for degrading environmentally harmful compounds and recovering phosphate ions in biological molecules. CeO2 nanocrystals have been well-studied for dephosphorylation via hydrolysis owing to the accessible and tunable distribution of Ce3+ and Ce4+ ions. However, there remains uncertainty in the literature regarding which surface defect properties direct catalytic activity, such as the Ce3+/Ce4+ distribution, oxygen vacancies, faceting, and dopants, and to what degree they contribute to efficient hydrolysis. Trivalent (M3+) dopants serve as a tool for manipulating defects, including the concentration of Ce3+ and oxygen vacancies, thereby influencing the hydrolytic activity of CeO2. Herein, trivalent metal ions (M = Y3+, Cr3+, In3+, and Gd3+) were employed to modulate the active sites on the CeO2 nanocrystal surface, and the effects of each metal dopant on the cerium oxide active sites for organophosphate hydrolysis were investigated. M-doped CeO2 nanoparticles were synthesized via hydrothermal methods, followed by annealing to remove ligands and prime the nanocrystal surface for catalysis. Catalytic performance was evaluated using dimethyl-p¬-nitrophenyl phosphate (DMNP) as a model organophosphate substrate, with degradation monitored over time using UV-visible absorption spectroscopy. Powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy revealed successful doping of CeO2 in all cases, albeit with distinctive characteristics demonstrating how M3+ dopants affect catalysis. We show that CeO2 exhibits high sensitivity to dopants that generate lattice strain, Ce3+ ions, and oxygen vacancy defects. Consequently, achieving high catalytic efficiency within CeO2 requires a balanced active site ensemble, wherein defects are maintained at optimal concentrations and distributions on the nanocrystal surface.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 2426959

Report Number(s):: PNNL-SA-200176

Journal Information:: ACS Applied Nano Materials, Journal Name: ACS Applied Nano Materials Journal Issue: 13 Vol. 7

Country of Publication:: United States

Language:: English

References (83)

Protonation of the Binuclear Metal Center within the Active Site of Phosphotriesterase Samples, Cynthia R.; Howard, Timothy; Raushel, Frank M. Biochemistry, Vol. 44, Issue 33 https://doi.org/10.1021/bi0506270	journal	July 2005
Oxygen vacancies and their role on the magnetic character of polycrystalline CeO2 Paulin, M. A.; Alejandro, G.; Lamas, D. G. Ceramics International, Vol. 49, Issue 3 https://doi.org/10.1016/j.ceramint.2022.10.031	journal	February 2023
Zirconium-Based Metal–Organic Frameworks for the Catalytic Hydrolysis of Organophosphorus Nerve Agents Kirlikovali, Kent O.; Chen, Zhijie; Islamoglu, Timur ACS Applied Materials & Interfaces, Vol. 12, Issue 13 https://doi.org/10.1021/acsami.9b20154	journal	January 2020
Ceria-Based Materials for Thermocatalytic and Photocatalytic Organic Synthesis Huang, Xiubing; Zhang, Kaiyue; Peng, Baoxiang ACS Catalysis, Vol. 11, Issue 15 https://doi.org/10.1021/acscatal.1c02443	journal	July 2021
X-ray line broadening from filed aluminium and wolfram Williamson, G. K.; Hall, W. H. Acta Metallurgica, Vol. 1, Issue 1 https://doi.org/10.1016/0001-6160(53)90006-6	journal	January 1953
Temperature-Dependent Reduction of Epitaxial Ce _{1– x} Pr _x O _2−δ ( x = 0–1) Thin Films on Si(111): A Combined Temperature-Programmed Desorption, X-ray Diffraction, X-ray Photoelectron Spectroscopy, and Raman Study Zoellner, Marvin Hartwig; Niu, Gang; Jhang, Jin-Hao The Journal of Physical Chemistry C, Vol. 117, Issue 47 https://doi.org/10.1021/jp4082867	journal	November 2013
Electron Localization Determines Defect Formation on Ceria Substrates Esch, F. Science, Vol. 309, Issue 5735 https://doi.org/10.1126/science.1111568	journal	July 2005
Zr-doped CeO2 nanorods as versatile catalyst in the epoxidation of styrene with tert-butyl hydroperoxide as the oxidant Liu, Xin; Ding, Jing; Lin, Xi Applied Catalysis A: General, Vol. 503 https://doi.org/10.1016/j.apcata.2015.07.010	journal	August 2015
Asymmetric Oxygen Vacancies: the Intrinsic Redox Active Sites in Metal Oxide Catalysts Yu, Kai; Lou, Lan‐Lan; Liu, Shuangxi Advanced Science, Vol. 7, Issue 2 https://doi.org/10.1002/advs.201901970	journal	November 2019
Use of CeO2-based oxides in the three-way catalysis Kašpar, J.; Fornasiero, P.; Graziani, M. Catalysis Today, Vol. 50, Issue 2 https://doi.org/10.1016/S0920-5861(98)00510-0	journal	April 1999
Phosphate ester hydrolysis of biologically relevant molecules by cerium oxide nanoparticles Kuchma, Melissa Hirsch; Komanski, Christopher B.; Colon, Jimmie Nanomedicine: Nanotechnology, Biology and Medicine, Vol. 6, Issue 6 https://doi.org/10.1016/j.nano.2010.05.004	journal	December 2010
Facile Synthesis and Characterization of Nanostructured Transition Metal/Ceria Solid Solutions (TM_xCe_1–xO_2−δ, TM = Mn, Ni, Co, or Fe) for CO Oxidation Lee, Kyung Joo; Kim, Yongseon; Lee, Jae Hwa Chemistry of Materials, Vol. 29, Issue 7 https://doi.org/10.1021/acs.chemmater.6b05098	journal	March 2017
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Use and mis-use of x-ray photoemission spectroscopy Ce3d spectra of Ce ₂ O ₃ and CeO ₂ Paparazzo, Ernesto Journal of Physics: Condensed Matter, Vol. 30, Issue 34 https://doi.org/10.1088/1361-648X/aad248	journal	August 2018
Lattice Defects and Oxygen Storage Capacity of Nanocrystalline Ceria and Ceria-Zirconia Mamontov, E.; Egami, T.; Brezny, R. The Journal of Physical Chemistry B, Vol. 104, Issue 47 https://doi.org/10.1021/jp0023011	journal	November 2000
Role of trivalent La and Nd dopants in lattice distortion and oxygen vacancy generation in cerium oxide nanoparticles Patil, Swanand; Seal, Sudipta; Guo, Yu Applied Physics Letters, Vol. 88, Issue 24 https://doi.org/10.1063/1.2210795	journal	June 2006
Facet‐Dependent Effect of Well‐Defined CeO₂ Nanocrystals on the Adsorption and Dephosphorylation of Phosphorylated Molecules Wang, Zhi‐Gang; Bi, Wen‐Zhi; Ma, Shu‐Cui Particle & Particle Systems Characterization, Vol. 32, Issue 6 https://doi.org/10.1002/ppsc.201400230	journal	January 2015
Oxidative stress induced by cerium oxide nanoparticles in cultured BEAS-2B cells Park, Eun-Jung; Choi, Jinhee; Park, Young-Kwon Toxicology, Vol. 245, Issue 1-2 https://doi.org/10.1016/j.tox.2007.12.022	journal	March 2008
Synthesis of One-Dimensional Ce_1−xY_xO_2−x/2 (0 ≤ x ≤ 1) Solid Solutions and Their Catalytic Properties: The Role of Oxygen Vacancies Yang, Dan; Wang, Lei; Sun, Yangzhao The Journal of Physical Chemistry C, Vol. 114, Issue 19 https://doi.org/10.1021/jp912227p	journal	April 2010
Catalytic properties and biomedical applications of cerium oxide nanoparticles Walkey, Carl; Das, Soumen; Seal, Sudipta Environmental Science: Nano, Vol. 2, Issue 1 https://doi.org/10.1039/C4EN00138A	journal	January 2015
Influence of surface chemical properties of nanocrystalline CeO2 on phosphate adsorption and methyl-paraoxon decomposition Ederer, Jakub; Novák, Adam; Janoš, Pavel Journal of Industrial and Engineering Chemistry, Vol. 123 https://doi.org/10.1016/j.jiec.2023.03.029	journal	July 2023
Pr-Doped CeO ₂ Catalyst in the Prins Condensation–Hydrolysis Reaction: Are All of the Defect Sites Catalytically Active? Zhang, Zhixin; Wang, Yehong; Lu, Jianmin ACS Catalysis, Vol. 8, Issue 4 https://doi.org/10.1021/acscatal.7b04500	journal	February 2018
Influence of particle morphology on nanostructural feature and conducting property in Sm-doped CeO2 sintered body Mori, T. Solid State Ionics, Vol. 175, Issue 1-4 https://doi.org/10.1016/j.ssi.2004.09.046	journal	November 2004
Williamson-Hall analysis in estimation of lattice strain in nanometer-sized ZnO particles Mote, Vd; Purushotham, Y.; Dole, Bn Journal of Theoretical and Applied Physics, Vol. 6, Issue 1 https://doi.org/10.1186/2251-7235-6-6	journal	January 2012
Ultrasmall Metal-Doped CeO₂ Nanoparticles for Low-Temperature CO Oxidation Basina, Georgia; Polychronopoulou, Kyriaki; Zedan, Abdallah F. ACS Applied Nano Materials, Vol. 3, Issue 11 https://doi.org/10.1021/acsanm.0c02090	journal	October 2020
Oxygen Vacancy Promoting Dimethyl Carbonate Synthesis from CO ₂ and Methanol over Zr-Doped CeO ₂ Nanorods Liu, Bin; Li, Congming; Zhang, Guoqiang ACS Catalysis, Vol. 8, Issue 11 https://doi.org/10.1021/acscatal.8b00415	journal	October 2018
Improvement of Stability of CeO₂–Based Catalysts by Mn Doping for the Synthesis of 2-Imidazolidinone from Ethylenediamine Carbamate Fujii, Ryotaro; Yabushita, Mizuho; Li, Yingai ACS Catalysis, Vol. 13, Issue 16 https://doi.org/10.1021/acscatal.3c02476	journal	August 2023
Introduction to x-ray photoelectron spectroscopy Stevie, Fred A.; Donley, Carrie L. Journal of Vacuum Science & Technology A, Vol. 38, Issue 6 https://doi.org/10.1116/6.0000412	journal	December 2020
Unravelling the true active site for CeO2-catalyzed dephosphorylation Tan, Zicong; Wu, Tai-Sing; Soo, Yun-Liang Applied Catalysis B: Environmental, Vol. 264 https://doi.org/10.1016/j.apcatb.2019.118508	journal	May 2020
Metal–Organic Frameworks against Toxic Chemicals Islamoglu, Timur; Chen, Zhijie; Wasson, Megan C. Chemical Reviews, Vol. 120, Issue 16 https://doi.org/10.1021/acs.chemrev.9b00828	journal	March 2020
Catalytic mechanisms for phosphotriesterases Bigley, Andrew N.; Raushel, Frank M. Biochimica et Biophysica Acta (BBA) - Proteins and Proteomics, Vol. 1834, Issue 1, p. 443-453 https://doi.org/10.1016/j.bbapap.2012.04.004	journal	January 2013
Surface-Charge-Dependent Cell Localization and Cytotoxicity of Cerium Oxide Nanoparticles Asati, Atul; Santra, Santimukul; Kaittanis, Charalambos ACS Nano, Vol. 4, Issue 9 https://doi.org/10.1021/nn100816s	journal	August 2010
Raman Spectra of Polycrystalline CeO ₂ : A Density Functional Theory Study Schilling, Christian; Hofmann, Alexander; Hess, Christian The Journal of Physical Chemistry C, Vol. 121, Issue 38 https://doi.org/10.1021/acs.jpcc.7b06643	journal	September 2017
Surface sensitivity of Auger-electron spectroscopy and X-ray photoelectron spectroscopy Powell, C. J.; Jablonski, A.; Tilinin, I. S. Journal of Electron Spectroscopy and Related Phenomena, Vol. 98-99 https://doi.org/10.1016/S0368-2048(98)00271-0	journal	January 1999
To Err is Human; To Reproduce Takes Time Scott, Susannah L.; Gunnoe, T. Brent; Fornasiero, Paolo ACS Catalysis, Vol. 12, Issue 6 https://doi.org/10.1021/acscatal.2c00967	journal	March 2022
Study of Defect Sites in Ce _{1– x} M _x O _2−δ ( x = 0.2) Solid Solutions Using Raman Spectroscopy Li, Lan; Chen, Fang; Lu, Ji-Qing The Journal of Physical Chemistry A, Vol. 115, Issue 27 https://doi.org/10.1021/jp203921m	journal	July 2011
Destruction and Detection of Chemical Warfare Agents Kim, Kibong; Tsay, Olga G.; Atwood, David A. Chemical Reviews, Vol. 111, Issue 9 https://doi.org/10.1021/cr100193y	journal	September 2011
Photolyase-Like Catalytic Behavior of CeO₂ Tian, Zhimin; Yao, Tianzhu; Qu, Chaoyi Nano Letters, Vol. 19, Issue 11 https://doi.org/10.1021/acs.nanolett.9b03836	journal	October 2019
Mode of Action of Bi- and Trinuclear Zinc Hydrolases and Their Synthetic Analogues Weston, Jennie Chemical Reviews, Vol. 105, Issue 6 https://doi.org/10.1021/cr020057z	journal	March 2005
Size-dependent properties of CeO 2 − y nanoparticles as studied by Raman scattering Spanier, Jonathan E.; Robinson, Richard D.; Zhang, Feng Physical Review B, Vol. 64, Issue 24 https://doi.org/10.1103/PhysRevB.64.245407	journal	November 2001
Oxygen Vacancy Engineering of Cerium Oxides for Carbon Dioxide Capture and Reduction Yang, Sheng-Chiang; Su, Wei-Nien; Rick, John ChemSusChem, Vol. 6, Issue 8 https://doi.org/10.1002/cssc.201300219	journal	June 2013
Oxygen Vacancy Induced Room Temperature Ferromagnetism in Pr-Doped CeO₂ Thin Films on Silicon Niu, Gang; Hildebrandt, Erwin; Schubert, Markus Andreas ACS Applied Materials & Interfaces, Vol. 6, Issue 20 https://doi.org/10.1021/am502238w	journal	October 2014
Cr-Doped CeO2 Nanorods for CO Oxidation: Insights into Promotional Effect of Cr on Structure and Catalytic Performance Venkataswamy, Perala; Damma, Devaiah; Jampaiah, Deshetti Catalysis Letters, Vol. 150, Issue 4 https://doi.org/10.1007/s10562-019-03014-z	journal	November 2019
Behavior of nanoceria in biologically-relevant environments Kumar, Amit; Das, Soumen; Munusamy, Prabhakaran Environ. Sci.: Nano, Vol. 1, Issue 6 https://doi.org/10.1039/C4EN00052H	journal	January 2014
Catalytic Dephosphorylation Using Ceria Nanocrystals Manto, Michael J.; Xie, Pengfei; Wang, Chao ACS Catalysis, Vol. 7, Issue 3 https://doi.org/10.1021/acscatal.6b03472	journal	February 2017
Structural and Functional Models of the Active Site of Zinc Phosphotriesterase Carlsson, Håkan; Haukka, Matti; Nordlander, Ebbe Inorganic Chemistry, Vol. 43, Issue 18 https://doi.org/10.1021/ic0354522	journal	August 2004
Conversion of Isobutene and Formaldehyde to Diol using Praseodymium-Doped CeO ₂ Catalyst Zhang, Zhixin; Wang, Yehong; Lu, Jianmin ACS Catalysis, Vol. 6, Issue 12 https://doi.org/10.1021/acscatal.6b02134	journal	November 2016
Cerium oxide for the destruction of chemical warfare agents: A comparison of synthetic routes Janoš, Pavel; Henych, Jiří; Pelant, Ondřej Journal of Hazardous Materials, Vol. 304 https://doi.org/10.1016/j.jhazmat.2015.10.069	journal	March 2016
Defect-induced Raman spectra in doped CeO 2 Nakajima, A.; Yoshihara, A.; Ishigame, M. Physical Review B, Vol. 50, Issue 18 https://doi.org/10.1103/PhysRevB.50.13297	journal	November 1994
Mechanism and stereochemical course at phosphorus of the reaction catalyzed by a bacterial phosphotriesterase Lewis, Vincent E.; Donarski, William J.; Wild, James R. Biochemistry, Vol. 27, Issue 5 https://doi.org/10.1021/bi00405a030	journal	March 1988
Electron inelastic mean free paths in cerium dioxide Krawczyk, M.; Holdynski, M.; Lisowski, W. Applied Surface Science, Vol. 341 https://doi.org/10.1016/j.apsusc.2015.02.177	journal	June 2015
Catalytic Properties of Ceria and CeO ₂ -Containing Materials Trovarelli, Alessandro Catalysis Reviews, Vol. 38, Issue 4 https://doi.org/10.1080/01614949608006464	journal	November 1996
Synthesis of CeO2–MnOx mixed oxides and catalytic performance under oxygen-rich condition Wu, Xiaodong; Liang, Qing; Weng, Duan Catalysis Today, Vol. 126, Issue 3-4 https://doi.org/10.1016/j.cattod.2007.06.014	journal	August 2007
Vacancy-Engineered Nanoceria: Enzyme Mimetic Hotspots for the Degradation of Nerve Agents Vernekar, Amit A.; Das, Tandrila; Mugesh, Govindasamy Angewandte Chemie International Edition, Vol. 55, Issue 4 https://doi.org/10.1002/anie.201510355	journal	December 2015
The evolution of phosphotriesterase for decontamination and detoxification of organophosphorus chemical warfare agents Bigley, Andrew N.; Raushel, Frank M. Chemico-Biological Interactions, Vol. 308 https://doi.org/10.1016/j.cbi.2019.05.023	journal	August 2019
EPR study of ceria nanoparticles containing different concentration of Ce3+ ions Rakhmatullin, R. M.; Semashko, V. V.; Korableva, S. L. Materials Chemistry and Physics, Vol. 219 https://doi.org/10.1016/j.matchemphys.2018.08.028	journal	November 2018
Controlled Synthesis and Self-Assembly of CeO ₂ Nanocubes Yang, Songwang; Gao, Lian Journal of the American Chemical Society, Vol. 128, Issue 29 https://doi.org/10.1021/ja063359h	journal	July 2006
Cerium Oxide Nanoparticles Stabilized within Metal–Organic Frameworks for the Degradation of Nerve Agents Hassan, Mohamed H.; Andreescu, Daniel; Andreescu, Silvana ACS Applied Nano Materials, Vol. 3, Issue 4 https://doi.org/10.1021/acsanm.0c00015	journal	March 2020
The Role of Hydrogen Adsorption Site Diversity in Catalysis on Transition-Metal Phosphide Surfaces Kuo, Ding-Yuan; Nishiwaki, Emily; Rivera-Maldonado, Ricardo A. ACS Catalysis, Vol. 13, Issue 1 https://doi.org/10.1021/acscatal.2c04936	journal	December 2022
New explanation of Raman peak redshift in nanoparticles Meilakhs, A. P.; Koniakhin, S. V. Superlattices and Microstructures, Vol. 110 https://doi.org/10.1016/j.spmi.2017.08.010	journal	October 2017
The Use of the Pseudo-Voigt Function in the Variance Method of X-ray Line-Broadening Analysis Sánchez-Bajo, F.; Cumbrera, F. L. Journal of Applied Crystallography, Vol. 30, Issue 4 https://doi.org/10.1107/S0021889896015464	journal	August 1997
Influence of nano-structural feature on electrolytic properties in Y₂O₃ doped CeO₂ system Mori, Toshiyuki; Drennan, John; Wang, Yarong Science and Technology of Advanced Materials, Vol. 4, Issue 3 https://doi.org/10.1016/S1468-6996(03)00047-0	journal	January 2003
Ceria and Its Defect Structure: New Insights from a Combined Spectroscopic Approach Filtschew, Anastasia; Hofmann, Kathrin; Hess, Christian The Journal of Physical Chemistry C, Vol. 120, Issue 12 https://doi.org/10.1021/acs.jpcc.6b00959	journal	March 2016
Raman and x‐ray studies of Ce _{1− x} RE _x O _{2− y} , where RE=La, Pr, Nd, Eu, Gd, and Tb McBride, J. R.; Hass, K. C.; Poindexter, B. D. Journal of Applied Physics, Vol. 76, Issue 4 https://doi.org/10.1063/1.357593	journal	August 1994
Oxide ionic conductivity and microstructures of Sm- or La-doped CeO2-based systems Mori, T. Solid State Ionics, Vol. 154-155 https://doi.org/10.1016/S0167-2738(02)00483-6	journal	December 2002
Characterization of the zinc binding site of bacterial phosphotriesterase. Omburo, G. A.; Kuo, J. M.; Mullins, L. S. Journal of Biological Chemistry, Vol. 267, Issue 19 https://doi.org/10.1016/S0021-9258(18)42207-7	journal	July 1992
Cerium oxide nanoparticle: a remarkably versatile rare earth nanomaterial for biological applications Xu, Can; Qu, Xiaogang NPG Asia Materials, Vol. 6, Issue 3 https://doi.org/10.1038/am.2013.88	journal	March 2014
Recent Advances in Heterogeneous Catalytic Systems Containing Metal Ions for Phosphate Ester Hydrolysis Gomes, Marco Antônio G. B.; Fernandes, Christiane; Gahan, Lawrence R. Chemistry – A European Journal, Vol. 27, Issue 3 https://doi.org/10.1002/chem.202002333	journal	September 2020
Mobility of Surface Species on Oxides. 1. Isotopic Exchange of ¹⁸ O ₂ with ¹⁶ O of SiO ₂ , Al ₂ O ₃ , ZrO ₂ , MgO, CeO ₂ , and CeO ₂ -Al ₂ O ₃ . Activation by Noble Metals. Correlation with Oxide Basicity ^† Martin, Dominique; Duprez, Daniel The Journal of Physical Chemistry, Vol. 100, Issue 22 https://doi.org/10.1021/jp9531568	journal	January 1996
Synthesis, Characterization, and Photocatalytic Activity of Y-Doped CeO ₂ Nanorods Liyanage, Anjalee D.; Perera, Sanjaya D.; Tan, Kui ACS Catalysis, Vol. 4, Issue 2 https://doi.org/10.1021/cs400889y	journal	December 2013
Electronic Structure and Room Temperature Ferromagnetism in Gd‐doped Cerium Oxide Nanoparticles for Hydrogen Generation via Photocatalytic Water Splitting Soni, Swati; Chouhan, Neelu; Meena, Rajesh Kumar Global Challenges, Vol. 3, Issue 5 https://doi.org/10.1002/gch2.201800090	journal	January 2019
Unravelling the Surface Chemistry of Metal Oxide Nanocrystals, the Role of Acids and Bases De Roo, Jonathan; Van den Broeck, Freya; De Keukeleere, Katrien Journal of the American Chemical Society, Vol. 136, Issue 27 https://doi.org/10.1021/ja5032979	journal	June 2014
Oxygen vacancy and valence engineering in CeO₂ through distinct sized ion doping and their impact on oxygen reduction reaction catalysis Das, Debarati; Prakash, Jyoti; Goutam, U. K. Dalton Transactions, Vol. 51, Issue 48 https://doi.org/10.1039/D2DT03198A	journal	January 2022
Hierarchically Porous Gd³⁺-Doped CeO₂ Nanostructures for the Remarkable Enhancement of Optical and Magnetic Properties Li, Gao-Ren; Qu, Dun-Lin; Arurault, Laurent The Journal of Physical Chemistry C, Vol. 113, Issue 4 https://doi.org/10.1021/jp804572t	journal	January 2009
Rietveld refinement of the structure of CeOCI formed in Pd/CeO2 catalyst: Notes on the existence of a stabilized tetragonal phase of La2O3 in LaPdO system WoŁcyrz, M.; Kepinski, L. Journal of Solid State Chemistry, Vol. 99, Issue 2 https://doi.org/10.1016/0022-4596(92)90330-X	journal	August 1992
Heterogeneous Ceria Catalyst with Water-Tolerant Lewis Acidic Sites for One-Pot Synthesis of 1,3-Diols via Prins Condensation and Hydrolysis Reactions Wang, Yehong; Wang, Feng; Song, Qi Journal of the American Chemical Society, Vol. 135, Issue 4 https://doi.org/10.1021/ja310498c	journal	January 2013
UiO-66-NH ₂ Metal–Organic Framework (MOF) Nucleation on TiO ₂ , ZnO, and Al ₂ O ₃ Atomic Layer Deposition-Treated Polymer Fibers: Role of Metal Oxide on MOF Growth and Catalytic Hydrolysis of Chemical Warfare Agent Simulants Lee, Dennis T.; Zhao, Junjie; Oldham, Christopher J. ACS Applied Materials & Interfaces, Vol. 9, Issue 51 https://doi.org/10.1021/acsami.7b15397	journal	December 2017
Accelerated dephosphorylation of adenosine phosphates and related compounds in the presence of nanocrystalline cerium oxide Janoš, Pavel; Lovászová, Iveta; Pfeifer, Jan Environmental Science: Nano, Vol. 3, Issue 4 https://doi.org/10.1039/C6EN00086J	journal	January 2016
Synthetic Analogues Relevant to the Structure and Function of Zinc Enzymes Parkin, Gerard Chemical Reviews, Vol. 104, Issue 2 https://doi.org/10.1021/cr0206263	journal	February 2004
EPR study of nanocrystalline CeO₂ exhibiting ferromagnetism at room temperature Rakhmatullin, R. M.; Pavlov, V. V.; Semashko, V. V. physica status solidi (b), Vol. 253, Issue 3 https://doi.org/10.1002/pssb.201552542	journal	November 2015
A Quantitative Scale of Oxophilicity and Thiophilicity Kepp, Kasper P. Inorganic Chemistry, Vol. 55, Issue 18 https://doi.org/10.1021/acs.inorgchem.6b01702	journal	August 2016
Fundamentals and Catalytic Applications of CeO ₂ -Based Materials Montini, Tiziano; Melchionna, Michele; Monai, Matteo Chemical Reviews, Vol. 116, Issue 10 https://doi.org/10.1021/acs.chemrev.5b00603	journal	April 2016
Designed Metal-Containing Peptoid Membranes as Enzyme Mimetics for Catalytic Organophosphate Degradation Trinh, Thi Kim Hoang; Jian, Tengyue; Jin, Biao ACS Applied Materials & Interfaces, Vol. 15, Issue 44 https://doi.org/10.1021/acsami.3c11816	journal	October 2023

Similar Records

Chemistry - Oxygen Vacancies and Catalysis on Ceria Surfaces

Journal Article · Fri Jul 29 00:00:00 EDT 2005 · Science · OSTI ID:15017428

CeO2 Nanoparticle Doping as a Probe of Active Site Speciation in the Catalytic Hydrolysis of Organophosphates

Citation Formats

References (83)

Similar Records

Related Subjects