Modulating Electronic Structure of Atomically Dispersed Nickel Sites through Boron and Nitrogen Dual Coordination Boosts Oxygen Reduction

Wang, Fangqing; Zhang, Rui; Zhang, Yangyang; Li, Ying; Zhang, Jun; Yuan, Wenhao; Liu, Hui; Wang, Fei; Xin, Huolin L.

doi:10.1002/adfm.202213863

Modulating Electronic Structure of Atomically Dispersed Nickel Sites through Boron and Nitrogen Dual Coordination Boosts Oxygen Reduction

Journal Article · Tue Jan 31 04:00:00 EST 2023 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.202213863· OSTI ID:2425489

Wang, Fangqing ^[1]; Zhang, Rui ^[2]; Zhang, Yangyang ^[1]; Li, Ying ^[1]; Zhang, Jun ^[3]; Yuan, Wenhao ^[1]; ^[1]; Wang, Fei ^[1]; Xin, Huolin L. ^[2]

Key Laboratory of Special Functional Materials for Ecological Environment and Information (Hebei University of Technology) Ministry of Education Tianjin 300130 P. R. China
Department of Physics and Astronomy University of California Irvine CA 92697 USA
School of Material Science and Engineering Hebei University of Technology Tianjin 300130 P. R. China

Abstract

Atomically dispersed 3D transitional metal active sites with nitrogen coordination anchored on carbon support have emerged as a kind of promising electrocatalyst toward oxygen reduction reaction (ORR) in the field of fuel cells and metal–air cells. However, it is still a challenge to accurately modulate the coordination structure of single‐atom metal sites, especially first‐shell coordination, as well as identify the relationship between the geometric/electronic structure and ORR performance. Herein, a carbon‐supported single‐atom nickel catalyst is fabricated with boron and nitrogen dual coordination (denoted as Ni‐B/N‐C). The hard X‐ray absorption spectrum result reveals that atomically dispersed Ni active sites are coordinated with one B atom and three N atoms in the first shell (denoted as Ni‐B₁N₃). The Ni‐B/N‐C catalyst exhibits a half‐wave potential (E_1/2) of 0.87 V versus RHE, along with a distinguished long‐term durability in alkaline media, which is superior to commercial Pt/C. Density functional theory calculations indicate that the Ni‐B₁N₃active sites are more favorable for the adsorption of ORR intermediates relative to Ni‐N₄, leading to the reduction of thermodynamic barrier and the acceleration of reaction kinetics, which accounts for the increased intrinsic activity.

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0012704

OSTI ID:: 2425489

Journal Information:: Advanced Functional Materials, Journal Name: Advanced Functional Materials Journal Issue: 17 Vol. 33; ISSN 1616-301X

Publisher:: Wiley

Country of Publication:: United States

Language:: English

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