Thermal equation of state of ice-VII revisited by single-crystal X-ray diffraction

Lai, Xiaojing; Zhu, Feng; Zhang, Dongzhou; Tkachev, Sergey; Prakapenka, Vitali B.; Chao, Keng-Hsien; Chen, Bin

doi:10.2138/am-2022-8554

Thermal equation of state of ice-VII revisited by single-crystal X-ray diffraction

Journal Article · Tue Aug 01 04:00:00 EDT 2023 · American Mineralogist

DOI:https://doi.org/10.2138/am-2022-8554· OSTI ID:2423707

Lai, Xiaojing; Zhu, Feng; Zhang, Dongzhou; Tkachev, Sergey; Prakapenka, Vitali B.; Chao, Keng-Hsien; Chen, Bin

Abstract

Ice-VII is a high-pressure polymorph of H2O ice and an important mineral widely present in many planetary environments, such as in the interiors of large icy planetary bodies, within some cold subducted slabs, and in diamonds of deep origin as mineral inclusions. However, its stability at high pressures and high temperatures and thermoelastic properties are still under debate. In this study, we synthesized ice-VII single crystals in externally heated diamond-anvil cells and conducted single-crystal X-ray diffraction experiments up to 78 GPa and 1000 K to revisit the high-pressure and high-temperature phase stability and thermoelastic properties of ice-VII. No obvious unit-cell volume discontinuity or strain anomaly of the high-pressure ice was observed up to the highest achieved pressures and temperatures. The volume-pressure-temperature data were fitted to a high-temperature Birch-Murnaghan equation of state formalism, yielding bulk modulus KT0 = 21.0(4) GPa, its first pressure derivative KT0′ = 4.45(6), dK/dT = –0.009(4) GPa/K, and thermal expansion relation αT = 15(5) × 10–5 + 15(8) × 10–8 × (T – 300) K–1. The determined phase stability and thermoelastic properties of ice-VII can be used to model the inner structure of icy cosmic bodies. Combined with the thermoelastic properties of diamonds, we can reconstruct the isomeke P-T paths of ice-VII inclusions in diamond from depth, offering clues on the water-rich regions in Earth’s deep mantle and the formation environments of those diamonds.

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 2423707

Journal Information:: American Mineralogist, Journal Name: American Mineralogist Journal Issue: 8 Vol. 108; ISSN 0003-004X

Publisher:: Mineralogical Society of America

Country of Publication:: United States

Language:: English

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