Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Hydrogen atom abstraction by a high-spin [FeIII=S] complex

Journal Article · · Chem
Not provided.
Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357
OSTI ID:
2423462
Journal Information:
Chem, Journal Name: Chem Journal Issue: 9 Vol. 9; ISSN 2451-9294
Publisher:
Cell Press
Country of Publication:
United States
Language:
English

References (47)

Structural and Spectroscopic Characterization of an Electrophilic Iron Nitrido Complex journal August 2008
Photolytisch induzierte Reaktionen von CpCo(CO)2(Cp = C5H5, C5H4Me, C5Me5 und C5Ph5) mit Thiiran zu dinuklearen 1,2-Ethandithiolato-S-S-Komplexen / Photolytically Induced Reactions of CpCo(CO)2 (Cp = C5H5, C5H4Me, C5Me5 and C5Ph5) with Thiirane Yielding Dinuclear 1,2-Ethanedithiolato-S,S Complexes journal November 2006
A Terminal Fe III –Oxo in a Tetranuclear Cluster: Effects of Distal Metal Centers on Structure and Reactivity journal May 2019
The expanding utility of iron-sulfur clusters: Their functional roles in biology, synthetic small molecules, maquettes and artificial proteins, biomimetic materials, and therapeutic strategies journal February 2022
Synthesis, Structure, and Reactivity of an Iron(V) Nitride journal February 2011
Formation of a µ-η 22 -disulfide dinuclear copper( II ) complex by thermal decomposition of a thiolate complex via C–S bond cleavage journal January 1994
Simple Ligand-Field Theory of d 4 and d 6 Transition Metal Complexes with a C 3 Symmetry Axis journal May 2012
Developments in the Biomimetic Chemistry of Cubane-Type and Higher Nuclearity Iron–Sulfur Clusters journal January 2014
A Family of Four-Coordinate Iron(II) Complexes Bearing the Sterically Hindered Tris(pyrazolyl)borato Ligand TptBu,Me journal December 2010
Trapping of a Late-Metal Terminal Sulfido Intermediate with Phenyl Isothiocyanate journal November 2022
Synthetic Analogues of the Active Sites of Iron−Sulfur Proteins journal October 2003
A Sulfido-Bridged Diiron(II) Compound and Its Reactions with Nitrogenase-Relevant Substrates journal April 2004
Low-Spin Pseudotetrahedral Iron(I) Sites in Fe 2 (μ-S) Complexes journal April 2014
Comparative Insight into Electronic Properties and Reactivities toward C–H Bond Activation by Iron(IV)–Nitrido, Iron(IV)–Oxo, and Iron(IV)–Sulfido Complexes: A Theoretical Investigation journal February 2013
A Sulfide‐Bridged Diiron(II) Complex with a N2H4 Ligand journal May 2013
Determination of the Cu(III)–OH Bond Distance by Resonance Raman Spectroscopy Using a Normalized Version of Badger’s Rule journal March 2017
A [2Fe–1S] Complex That Affords Access to Bimetallic and Higher-Nuclearity Iron–Sulfur Clusters journal June 2019
Free Energies of Proton-Coupled Electron Transfer Reagents and Their Applications journal December 2021
Trapping of an Ni II Sulfide by a Co I Fulvene Complex journal April 2017
New Synthetic Routes to a Disulfidodinickel(II) Complex: Characterization and Reactivity of a Ni2(µ-η22-S2) Core journal April 2008
Iron Dinitrogen Complexes Supported by Tris(NHC)borate Ligand: Synthesis, Characterization, and Reactivity Study journal January 2018
Chalcogens as Terminal Ligands to Iron:  Synthesis and Structure of Complexes with FeIII−S and FeIII−Se Motifs journal May 2004
Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride journal September 2017
X-ray structure of thiolatocopper(II) complexes bearing close spectroscopic similarities to blue copper proteins journal November 1992
Hydrocarbon Oxidation by an Exposed, Multiply Bonded Iron(III) Oxo Complex journal September 2021
Structural Enzymology of Nitrogenase Enzymes journal June 2020
Facile Nitrite Reduction in a Non-heme Iron System: Formation of an Iron(III)-Oxo journal December 2014
A Molecular Low‐Coordinate [Fe‐S‐Fe] Unit in Three Oxidation States journal March 2021
Evidence for the Existence of a Late-Metal Terminal Sulfido Complex journal April 1999
Isolation and Characterization of Stable Iron(I) Sulfide Complexes journal July 2012
Formation of Ammonia from an Iron Nitrido Complex journal April 2009
Progress toward the Isolation of Late Metal Terminal Sulfides journal August 2020
Comparison of the FeO2+ and FeS2+ complexes in the cyanide and isocyanide ligand environment for methane hydroxylation journal April 2012
Styrene Aziridination by Iron(IV) Nitrides journal July 2015
Iron-sulfur clusters—new features in enzymes and synthetic models journal November 2011
Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride journal October 2015
X-ray Absorption Spectroscopy and Density Functional Theory Studies of [(H3buea)FeIII-X]n- (X = S2-, O2-, OH-):  Comparison of Bonding and Hydrogen Bonding in Oxo and Sulfido Complexes journal July 2006
Iron-Sulfur Clusters: Nature's Modular, Multipurpose Structures journal August 1997
Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(Ex)(CN)2(CO)2]2– (E = S, Se, or Te) journal May 2022
Reactivity of a Nickel Sulfide with Carbon Monoxide and Nitric Oxide journal September 2016
The structure and reactivity of iron nitride complexes journal January 2012
Characterization of Terminal Iron(III)–Oxo and Iron(III)–Hydroxo Complexes Derived from O 2 Activation journal November 2019
The Spectroscopy of Nitrogenases journal April 2020
O2 Activation by Nonheme Iron Complexes: A Monomeric Fe(III)-Oxo Complex Derived From O2 journal August 2000
From a Paramagnetic, Mononuclear Supersulfidonickel(II) Complex to a Diamagnetic Dimer with a Four-Sulfur Two-Electron Bond journal September 2008
Synthesis of a “Masked” Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide journal October 2015
Stabilization of the Dinitrogen Analogue, Phosphorus Nitride journal September 2020

Similar Records

Triple Hydrogen Atom Abstraction from Mn-NH3 Complexes Results in Cyclophosphazenium Cations
Journal Article · 2019 · Chemical Communications · OSTI ID:1614923

Hydrogen atom abstraction by fluorine atoms.
Journal Article · 1972 · J. Phys. Chem. 77: No. 3, 301-307(1 Feb 1973). · OSTI ID:4584321

Hydrogen atom abstraction by metal-oxo and metal-superoxo complexes: Kinetics and thermodynamics
Journal Article · 2000 · Journal of the American Chemical Society · OSTI ID:20017358

Related Subjects