Vanadium and Niobium MXenes—Bilayered V2O5 Asymmetric Supercapacitors

Saraf, Mohit; Zhang, Teng; Averianov, Timofey; Shuck, Christopher E.; Lord, Robert W.; Pomerantseva, Ekaterina; Gogotsi, Yury

doi:10.1002/smtd.202201551

Vanadium and Niobium MXenes—Bilayered V₂O₅ Asymmetric Supercapacitors

Journal Article · Sat Feb 18 23:00:00 EST 2023 · Small Methods

DOI:https://doi.org/10.1002/smtd.202201551· OSTI ID:2422604

^[1]; Zhang, Teng ^[1]; ^[1]; ^[1]; Lord, Robert W. ^[1]; Pomerantseva, Ekaterina ^[1]; ^[1]

Drexel Univ., Philadelphia, PA (United States). A. J. Drexel Nanotechnology Inst.

MXenes offer high metallic conductivity and redox capacitance that are attractive for high-power, high-energy storage devices. However, they operate limitedly under high anodic potentials due to irreversible oxidation. Pairing them with oxides to design asymmetric supercapacitors may expand the voltage window and increase the energy storage capabilities. Hydrated lithium preintercalated bilayered V₂O₅ ( δ-Li_xV₂O₅·nH₂O) is attractive for aqueous energy storage due to its high Li capacity at high potentials; however, its poor cyclability remains a challenge. To overcome its limitations and achieve a wide voltage window and excellent cyclability, it is combined with V₂C and Nb₄C₃ MXenes. Asymmetric supercapacitors employing lithium intercalated V₂C (Li-V₂C) or tetramethylammonium intercalated Nb₄C₃ (TMA-Nb₄C₃) MXenes as the negative electrode, and a δ-Li_xV₂O₅·nH₂O composite with carbon nanotubes as the positive electrode in 5 m LiCl electrolyte operate over wide voltage windows of 2 and 1.6 V, respectively. The latter shows remarkably high cyclability—capacitance retention of ≈95% after 10 000 cycles. Here, this work highlights the importance of selecting appropriate MXenes to achieve a wide voltage window and a long cycle life in combination with oxide anodes to demonstrate the potential of MXenes beyond Ti₃C₂ in energy storage.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Fulbright-Nehru Postdoctoral Fellowship

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2422604

Alternate ID(s):: OSTI ID: 1957664

Journal Information:: Small Methods, Journal Name: Small Methods Journal Issue: 8 Vol. 7; ISSN 2366-9608

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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