Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Surface Immobilization of a Re(I) Tricarbonyl Phenanthroline Complex to Si(111) through Sonochemical Hydrosilylation

Journal Article · · ACS Applied Materials and Interfaces
 [1];  [2];  [3];  [2];  [3];  [3];  [3];  [2];  [2];  [4];  [4];  [2];  [3];  [2]
  1. Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27599-3290, United States; OSTI
  2. Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27599-3290, United States
  3. Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, United States
  4. Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States
Not provided.
Research Organization:
University of North Carolina, Chapel Hill, NC (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0021173
OSTI ID:
2421783
Journal Information:
ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 1 Vol. 15; ISSN 1944-8244
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (62)

Physics of Semiconductor Devices book January 2007
Synthesis, Characterization, and Reactivity of Ethynyl- and Propynyl-Terminated Si(111) Surfaces journal August 2015
Redox Properties of Mixed Methyl/Vinylferrocenyl Monolayers on Si(111) Surfaces journal December 2013
Metal‐Complex/Semiconductor Hybrid Photocatalysts and Photoelectrodes for CO 2 Reduction Driven by Visible Light journal April 2019
Compilation of Energy Band Gaps in Elemental and Binary Compound Semiconductors and Insulators journal January 1973
Photoelectrochemical devices for solar water splitting – materials and challenges journal January 2017
Illuminating Silicon Surface Hydrosilylation: An Unexpected Plurality of Mechanisms journal September 2013
Synthesis, characterization, photophysical and electrochemical properties of fac-tricarbonyl(4,7-dichloro-1,10-phenanthroline)rhenium(I) complexes journal September 2015
Electrochemical investigations on stability and protonation behavior of pyridine-terminated aromatic self-assembled monolayers journal January 2011
Optimization of Click Chemistry of Ferrocene Derivatives on Acetylene‐Functionalized Silicon(100) Surfaces journal July 2008
X-ray photoelectron study of trans-influence of the ReRe multiple bond journal January 1980
Sonochemical synthesis of nanomaterials journal January 2013
Kinetic Dispersion in Redox-Active Dithiocarbamate Monolayers journal October 2009
>10% solar-to-hydrogen efficiency unassisted water splitting on ALD-protected silicon heterojunction solar cells journal January 2019
Electrochemical Reduction of CO2 Using Group VII Metal Catalysts journal March 2021
Alkylation of Si Surfaces Using a Two-Step Halogenation/Grignard Route journal January 1996
Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts journal January 2018
Infrared Vibrational Spectroscopy of Isotopically Labeled Ethyl-Terminated Si(111) Surfaces Prepared Using a Two-Step Chlorination/Alkylation Procedure journal July 2009
Stability of Chemically Passivated Silicon Electrodes in Aqueous Solutions: Interplay between Bias Voltage and Hydration of the Electrolyte journal February 2016
Photocathode engineering for efficient photoelectrochemical CO2 reduction journal June 2020
Decoupling Kinetics and Thermodynamics of Interfacial Catalysis at a Chemically Modified Black Silicon Semiconductor Photoelectrode journal May 2020
Effect of Molecule–Surface Reaction Mechanism on the Electronic Characteristics and Photovoltaic Performance of Molecularly Modified Si journal June 2013
Molecular Catalysts with Diphosphine Ligands Containing Pendant Amines journal May 2022
Platinum Diimine Bis(acetylide) Complexes:  Synthesis, Characterization, and Luminescence Properties journal February 2000
Heck Coupling of Olefins to Mixed Methyl/Thienyl Monolayers on Si(111) Surfaces journal June 2013
Mild and Efficient Functionalization of Hydrogen-Terminated Si(111) via Sonochemical Activated Hydrosilylation journal May 2011
Re(bipy-tBu)(CO) 3 Cl−improved Catalytic Activity for Reduction of Carbon Dioxide: IR-Spectroelectrochemical and Mechanistic Studies journal October 2010
Silicon/Molecule Interfacial Electronic Modifications journal January 2008
Tuning p-Si(111) Photovoltage via Molecule|Semiconductor Electronic Coupling journal February 2021
Covalent Attachment of Polyoxometalates to Passivated Si(111) Substrates: A Stable and Electronic Defect-Free Si|POM Platform journal June 2021
Atomic Layer Deposited TiO 2 –IrO x Alloys Enable Corrosion Resistant Water Oxidation on Silicon at High Photovoltage journal November 2018
Scanning Tunneling Microscopy of Ethylated Si(111) Surfaces Prepared by a Chlorination/Alkylation Process journal November 2006
Fermi level, work function and vacuum level journal January 2016
Influence of Spatial Redox Distribution on the Electrochemical Behavior of Electroactive Self-Assembled Monolayers journal September 2001
Electrochemical Detection of Nanoscale Phase Separation in Binary Self-Assembled Monolayers journal April 2005
Surface chemical reactions on self-assembled silane based monolayers journal January 2021
Photophysical properties of rhenium(I) tricarbonyl complexes containing alkyl- and aryl-substituted phenanthrolines as ligands journal September 1993
A Noble-Metal-Free Hydrogen Evolution Catalyst Grafted to Visible Light-Absorbing Semiconductors journal January 2013
Sonochemistry journal March 1990
Controlled Silicon Surface Functionalization by Alkene Hydrosilylation journal August 2005
Chemical and electronic characterization of methyl-terminated Si(111) surfaces by high-resolution synchrotron photoelectron spectroscopy journal July 2005
Hybrid Photocathodes for Carbon Dioxide Reduction: Interfaces for Charge Separation and Selective Catalysis journal March 2021
Determination of the Fermi-level pinning position at Si(111) surfaces journal December 1983
Reducing the resistance for the use of electrochemical impedance spectroscopy analysis in materials chemistry journal January 2021
Measurement of the Band Bending and Surface Dipole at Chemically Functionalized Si(111)/Vacuum Interfaces journal August 2013
An XPS study of Si as it occurs in adsorbents, catalysts, and thin films journal April 1983
Electronic Structure of Methoxy-, Bromo-, and Nitrobenzene Grafted onto Si(111) journal July 2006
Titanium Oxide Crystallization and Interface Defect Passivation for High Performance Insulator-Protected Schottky Junction MIS Photoanodes journal May 2016
Functionalization of Oxide-Free Silicon Surfaces with Redox-Active Assemblies journal April 2016
Comparison of the Photoelectrochemical Behavior of H-Terminated and Methyl-Terminated Si(111) Surfaces in Contact with a Series of One-Electron, Outer-Sphere Redox Couples in CH 3 CN journal October 2012
One- and two-electron pathways in the electrocatalytic reduction of CO 2 by fac-Re(bpy)(CO) 3 Cl (bpy = 2,2′-bipyridine) journal January 1985
Electrocatalytic and homogeneous approaches to conversion of CO 2 to liquid fuels journal January 2009
Modifying electronic properties at the silicon–molecule interface using atomic tethers journal December 2010
Applications of Monolayer-Functionalized H-Terminated Silicon Surfaces: A Review journal March 2017
Hybrid Organic/Inorganic Band-Edge Modulation of p -Si(111) Photoelectrodes: Effects of R, Metal Oxide, and Pt on H 2 Generation journal February 2015
Static and dynamic electronic characterization of organic monolayers grafted on a silicon surface journal January 2016
Band Bending in Semiconductors: Chemical and Physical Consequences at Surfaces and Interfaces journal June 2012
Surface Passivation and Positive Band-Edge Shift of p-Si(111) Surfaces Functionalized with Mixed Methyl/Trifluoromethylphenylacetylene Overlayers journal June 2020
Use of electroactive thiols to study the formation and exchange of alkanethiol monolayers on gold journal June 1991
Photoelectrochemical operation of a surface-bound, nickel-phosphine H 2 evolution catalyst on p-Si(111): a molecular semiconductor|catalyst construct journal January 2015
Surface‐Junction Effects on Interfacial Electron Transfer between Bis(terpyridine)iron(II) and Hydrogen‐Terminated Silicon(111) Electrode journal February 2014
Non-Catalytic Benefits of Ni(II) Binding to an Si(111)-PNP Construct for Photoelectrochemical Hydrogen Evolution Reaction: Metal Ion Induced Flat Band Potential Modulation journal March 2020

Similar Records

Design, synthesis, and photophysical properties of Re(I) tricarbonyl 1,10-phenanthroline complexes
Journal Article · 2020 · Journal of Molecular Structure · OSTI ID:2279643

Synthesis and Surface Attachment of Molecular Re(I) Hydride Species with Silatrane Functionalized Bipyridyl Ligands
Journal Article · 2023 · Organometallics · OSTI ID:2421792

The effect of sodium thiosulfate on cytotoxicity of a diimine Re(i) tricarbonyl complex
Journal Article · 2021 · Dalton Transactions · OSTI ID:1834777