Highly Tunable Syngas Product Ratios Enabled by Novel Nanoscale Hybrid Electrolytes Designed for Combined CO2 Capture and Electrochemical Conversion

Feric, Tony G.; Hamilton, Sara T.; Ko, Byung Hee; Lee, Gahyun Annie; Verma, Sumit; Jiao, Feng; Park, Ah‐Hyung Alissa

doi:10.1002/adfm.202210017

Highly Tunable Syngas Product Ratios Enabled by Novel Nanoscale Hybrid Electrolytes Designed for Combined CO₂ Capture and Electrochemical Conversion

Journal Article · Tue Jan 31 00:00:00 EST 2023 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.202210017· OSTI ID:2421276

^[1]; ^[2]; Ko, Byung Hee ^[3]; ^[2]; Verma, Sumit ^[4]; Jiao, Feng ^[3]; ^[2]

Columbia Univ., New York, NY (United States); OSTI
Columbia Univ., New York, NY (United States)
Univ. of Delaware, Newark, DE (United States)
Shell International Exploration and Production Inc., Houston, TX (United States)

Coupling renewable energy with the electrochemical conversion of CO₂ to chemicals and fuels has been proposed as a strategy to achieve a new circular carbon economy and help mitigate the effects of anthropogenic CO₂ emissions. Liquid-like Nanoparticle Organic Hybrid Materials (NOHMs) are composed of polymers tethered to nanoparticles and are previously explored as CO₂ capture materials and electrolyte additives. Here, in this study, two types of aqueous NOHM-based electrolytes are prepared to explore the effect of CO₂ binding energy (i.e., chemisorption versus physisorption) on CO₂ electroreduction over a silver nanoparticle catalyst for syngas production. Poly(ethylenimine) (PEI) and Jeffamine M2070 (HPE) are ionically tethered to SiO₂ nanoparticles to form the amine-containing NOHM-I-PEI and ether-containing NOHM-I-HPE, respectively. At less negative cathode potentials, PEI and NOHM-I-PEI-based electrolytes produce CO at higher rates than 0.1 molal. KHCO₃ due to favorable catalyst-electrolyte interactions. Whereas at more negative potentials, H₂ production is favored because of the carbamate electrochemical inactivity. Conversely, HPE and NOHM-I-HPE-based electrolytes display poor CO₂ reduction performance at less negative potentials. At more negative potentials, their performance approached that of 0.1 molal. KHCO₃, highlighting how the polymer functional groups of NOHMs can be strategically selected to produce value-added products from CO₂ with highly tunable compositions.

View Accepted Manuscript (DOE)

Research Organization:: Case Western Reserve Univ., Cleveland, OH (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019409

OSTI ID:: 2421276

Journal Information:: Advanced Functional Materials, Journal Name: Advanced Functional Materials Journal Issue: 13 Vol. 33; ISSN 1616-301X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (90)

Solvent Impregnated Polymers Loaded with Liquid‐Like Nanoparticle Organic Hybrid Materials for Enhanced Kinetics of Direct Air Capture and Point Source CO ₂ Capture Rim, Guanhe; Feric, Tony G.; Moore, Thomas Advanced Functional Materials, Vol. 31, Issue 21 https://doi.org/10.1002/adfm.202010047	journal	March 2021
Impacts of Bond Type and Grafting Density on the Thermal, Structural, and Transport Behaviors of Nanoparticle Organic Hybrid Materials‐Based Electrolytes Feric, Tony G.; Hamilton, Sara T.; Haque, Md. Ashraful Advanced Functional Materials, Vol. 32, Issue 36 https://doi.org/10.1002/adfm.202203947	journal	June 2022
Tunable Molecular‐Scale Materials for Catalyzing the Low‐Overpotential Electrochemical Conversion of CO₂ Rosen, Brian A.; Hod, Idan Advanced Materials, Vol. 30, Issue 41 https://doi.org/10.1002/adma.201706238	journal	April 2018
Promises of Main Group Metal–Based Nanostructured Materials for Electrochemical CO ₂ Reduction to Formate Han, Na; Ding, Pan; He, Le Advanced Energy Materials, Vol. 10, Issue 11 https://doi.org/10.1002/aenm.201902338	journal	November 2019
Electrolyte Effects on the Electrochemical Reduction of CO ₂ Moura de Salles Pupo, Marilia; Kortlever, Ruud ChemPhysChem, Vol. 20, Issue 22 https://doi.org/10.1002/cphc.201900680	journal	November 2019
Electrochemical Reduction of Carbon Dioxide in a Monoethanolamine Capture Medium Chen, Lu; Li, Fengwang; Zhang, Ying ChemSusChem, Vol. 10, Issue 20 https://doi.org/10.1002/cssc.201701075	journal	September 2017
A General and Facile Approach for the Electrochemical Reduction of Carbon Dioxide Inspired by Deep Eutectic Solvents Vasilyev, Dmitry V.; Rudnev, Alexander V.; Broekmann, Peter ChemSusChem, Vol. 12, Issue 8 https://doi.org/10.1002/cssc.201900579	journal	April 2019
Catalyst–Electrolyte Interactions in Aqueous Reline Solutions for Highly Selective Electrochemical CO ₂ Reduction Garg, Sahil; Li, Mengran; Rufford, Thomas E. ChemSusChem, Vol. 13, Issue 2 https://doi.org/10.1002/cssc.201902433	journal	November 2019
Extended Investigation of Electrochemical CO₂ Reduction in Ethanolamine Solutions by SECM Filotás, Daniel; Nagy, Tibor; Nagy, Livia Electroanalysis, Vol. 30, Issue 4 https://doi.org/10.1002/elan.201700693	journal	December 2017
Nonaqueous amine-based absorbents for energy efficient CO2 capture Guo, Hui; Li, Chenxu; Shi, Xiaoqin Applied Energy, Vol. 239 https://doi.org/10.1016/j.apenergy.2019.02.019	journal	April 2019
Efficient electroreduction of CO 2 on bulk silver electrode in aqueous solution via the inhibition of hydrogen evolution Quan, Fengjiao; Xiong, Mubing; Jia, Falong Applied Surface Science, Vol. 399 https://doi.org/10.1016/j.apsusc.2016.12.069	journal	March 2017
Controlling the selectivity of CO2 electroreduction on copper: The effect of the electrolyte concentration and the importance of the local pH Varela, Ana Sofia; Kroschel, Matthias; Reier, Tobias Catalysis Today, Vol. 260 https://doi.org/10.1016/j.cattod.2015.06.009	journal	February 2016
Effect of additives in aqueous electrolytes on CO2 electroreduction Sharifi Golru, Samaneh; Biddinger, Elizabeth J. Chemical Engineering Journal, Vol. 428 https://doi.org/10.1016/j.cej.2021.131303	journal	January 2022
Self-suspended polymer grafted nanoparticles Srivastava, Samanvaya; Choudhury, Snehashis; Agrawal, Akanksha Current Opinion in Chemical Engineering, Vol. 16 https://doi.org/10.1016/j.coche.2017.04.007	journal	May 2017
Electrochemical conversion of carbon dioxide to high value chemicals using gas-diffusion electrodes Malkhandi, Souradip; Yeo, Boon Siang Current Opinion in Chemical Engineering, Vol. 26 https://doi.org/10.1016/j.coche.2019.09.008	journal	December 2019
Effect of solution pH on CO: formate formation rates during electrochemical reduction of aqueous CO2 at Sn cathodes Bumroongsakulsawat, P.; Kelsall, G. H. Electrochimica Acta, Vol. 141 https://doi.org/10.1016/j.electacta.2014.07.057	journal	September 2014
Solvents and Supporting Electrolytes in the Electrocatalytic Reduction of CO2 König, Maximilian; Vaes, Jan; Klemm, Elias iScience, Vol. 19 https://doi.org/10.1016/j.isci.2019.07.014	journal	September 2019
Effect of water on the physical properties and carbon dioxide capture capacities of liquid-like Nanoparticle Organic Hybrid Materials and their corresponding polymers Petit, Camille; Bhatnagar, Sonali; Park, Ah-Hyung Alissa Journal of Colloid and Interface Science, Vol. 407 https://doi.org/10.1016/j.jcis.2013.05.065	journal	October 2013
Electrolytic cell design for electrochemical CO2 reduction Liang, Shuyu; Altaf, Naveed; Huang, Liang Journal of CO2 Utilization, Vol. 35 https://doi.org/10.1016/j.jcou.2019.09.007	journal	January 2020
The Electrolyte Frontier: A Manifesto Amanchukwu, Chibueze V. Joule, Vol. 4, Issue 2 https://doi.org/10.1016/j.joule.2019.12.009	journal	February 2020
Tandem and Hybrid Processes for Carbon Dioxide Utilization Overa, Sean; Feric, Tony G.; Park, Ah-Hyung Alissa Joule, Vol. 5, Issue 1 https://doi.org/10.1016/j.joule.2020.12.004	journal	January 2021
Electrochemical CO2 reduction: Electrocatalyst, reaction mechanism, and process engineering Lu, Qi; Jiao, Feng Nano Energy, Vol. 29 https://doi.org/10.1016/j.nanoen.2016.04.009	journal	November 2016
Challenges and solution technologies for the integration of variable renewable energy sources—a review Sinsel, Simon R.; Riemke, Rhea L.; Hoffmann, Volker H. Renewable Energy, Vol. 145 https://doi.org/10.1016/j.renene.2019.06.147	journal	January 2020
Electrochemical CO2 reduction to CO facilitated by MDEA-based deep eutectic solvent in aqueous solution Ahmad, Naveed; Wang, Xiaoxiao; Sun, Peixu Renewable Energy, Vol. 177 https://doi.org/10.1016/j.renene.2021.05.106	journal	November 2021
Hybrid Hairy Nanoparticle Electrolytes Stabilizing Lithium Metal Batteries Choudhury, Snehashis; Agrawal, Akanksha; Wei, Shuya Chemistry of Materials, Vol. 28, Issue 7 https://doi.org/10.1021/acs.chemmater.6b00029	journal	March 2016
Insights into the Enhanced Oxidative Thermal Stability of Nanoparticle Organic Hybrid Materials Developed for Carbon Capture and Energy Storage Feric, Tony G.; Hamilton, Sara T.; Park, Ah-Hyung Alissa Energy & Fuels, Vol. 35, Issue 23 https://doi.org/10.1021/acs.energyfuels.1c03243	journal	November 2021
Mechanisms of CO ₂ Capture into Monoethanolamine Solution with Different CO ₂ Loading during the Absorption/Desorption Processes Lv, Bihong; Guo, Bingsong; Zhou, Zuoming Environmental Science & Technology, Vol. 49, Issue 17 https://doi.org/10.1021/acs.est.5b02356	journal	August 2015
Kinetics, Thermodynamics, and Mechanism of a Novel Biphasic Solvent for CO₂ Capture from Flue Gas Zhang, Shihan; Shen, Yao; Shao, Peijing Environmental Science & Technology, Vol. 52, Issue 6 https://doi.org/10.1021/acs.est.7b05936	journal	February 2018
Ionic Liquids-Promoted Electrocatalytic Reduction of Carbon Dioxide Cui, Yuandong; He, Bin; Liu, Xiaomin Industrial & Engineering Chemistry Research, Vol. 59, Issue 46 https://doi.org/10.1021/acs.iecr.0c04037	journal	November 2020
Integrating CO₂ Capture with Electrochemical Conversion Using Amine-Based Capture Solvents as Electrolytes Pérez-Gallent, Elena; Vankani, Chirag; Sánchez-Martínez, Carlos Industrial & Engineering Chemistry Research, Vol. 60, Issue 11 https://doi.org/10.1021/acs.iecr.0c05848	journal	March 2021
CO₂ Capture Using Aqueous Potassium Carbonate Promoted by Ethylaminoethanol: A Kinetic Study Bhosale, Rahul R.; Kumar, Anand; AlMomani, Fares Industrial & Engineering Chemistry Research, Vol. 55, Issue 18 https://doi.org/10.1021/acs.iecr.5b04398	journal	April 2016
Fundamental Understanding of CO ₂ Capture and Regeneration in Aqueous Amines from First-Principles Studies: Recent Progress and Remaining Challenges Stowe, Haley M.; Hwang, Gyeong S. Industrial & Engineering Chemistry Research, Vol. 56, Issue 24 https://doi.org/10.1021/acs.iecr.7b00213	journal	June 2017
NMR Relaxometry and Diffusometry Analysis of Dynamics in Ionic Liquids and Ionogels for Use in Lithium-Ion Batteries Jayakody, Nishani Kanchana; Fraenza, Carla C.; Greenbaum, Steven G. The Journal of Physical Chemistry B, Vol. 124, Issue 31 https://doi.org/10.1021/acs.jpcb.0c02755	journal	July 2020
Solvation in Ionic Liquids with Polymer-Grafted Nanoparticles Liu, Siqi; Walton, Mia; Tarakina, Nadezda V. The Journal of Physical Chemistry B, Vol. 124, Issue 23 https://doi.org/10.1021/acs.jpcb.0c02813	journal	May 2020
From Salt in Solution to Solely Ions: Solvation of Methyl Viologen in Deep Eutectic Solvents and Ionic Liquids Klein, Jeffrey M.; Squire, Henry; Dean, William The Journal of Physical Chemistry B, Vol. 124, Issue 29 https://doi.org/10.1021/acs.jpcb.0c03296	journal	June 2020
Liquid Structure and Transport Properties of the Deep Eutectic Solvent Ethaline Zhang, Yong; Poe, Derrick; Heroux, Luke The Journal of Physical Chemistry B, Vol. 124, Issue 25 https://doi.org/10.1021/acs.jpcb.0c04058	journal	May 2020
Dynamic Mixing Behaviors of Ionically Tethered Polymer Canopy of Nanoscale Hybrid Materials in Fluids of Varying Physical and Chemical Properties Feric, Tony G.; Hamilton, Sara T.; Cantillo, Nelly M. The Journal of Physical Chemistry B, Vol. 125, Issue 32 https://doi.org/10.1021/acs.jpcb.1c00935	journal	August 2021
Structure and Dispersion of Free and Grafted Polymer in Nanoparticle Organic Hybrid Materials-Based Solutions by Small-Angle Neutron Scattering Haque, Md. Ashraful; Feric, Tony G.; Hamilton, Sara T. The Journal of Physical Chemistry C, Vol. 125, Issue 9 https://doi.org/10.1021/acs.jpcc.0c10790	journal	March 2021
Cations of Ionic Liquid Electrolytes Can Act as a Promoter for CO₂ Electrocatalysis through Reactive Intermediates and Electrostatic Stabilization Ratschmeier, Björn; Braunschweig, Björn The Journal of Physical Chemistry C, Vol. 125, Issue 30 https://doi.org/10.1021/acs.jpcc.1c02898	journal	July 2021
Catalyst Preoxidation and EDTA Electrolyte Additive Remedy Activity and Selectivity Declines During Electrochemical CO ₂ Reduction Jovanov, Zarko P.; Ferreira de Araujo, Jorge; Li, Shuang The Journal of Physical Chemistry C, Vol. 123, Issue 4 https://doi.org/10.1021/acs.jpcc.8b08794	journal	January 2019
Electroanalytical Investigation of the Electrode–Electrolyte Interface of Quaternary Ammonium Ionic Liquids: Impact of Alkyl Chain Length and Ether Functionality Klein, Jeffrey M.; Squire, Henry; Gurkan, Burcu The Journal of Physical Chemistry C, Vol. 124, Issue 10 https://doi.org/10.1021/acs.jpcc.9b08016	journal	December 2019
Spectroscopic Investigation of Entropic Canopy–Canopy Interactions of Nanoparticle Organic Hybrid Materials Choi, Soyoung; Moon, Seokyoon; Park, Youngjune Langmuir, Vol. 36, Issue 32 https://doi.org/10.1021/acs.langmuir.0c01784	journal	July 2020
Localized and Collective Dynamics in Liquid-like Polyethylenimine-Based Nanoparticle Organic Hybrid Materials Mapesa, Emmanuel Urandu; Cantillo, Nelly M.; Hamilton, Sara T. Macromolecules, Vol. 54, Issue 5 https://doi.org/10.1021/acs.macromol.0c02370	journal	February 2021
Spectroscopic Investigation of Thermochemical Depolymerization of Lignin Model Compounds in the Presence of Novel Liquidlike Nanoparticle Organic Hybrid Solvents for Efficient Biomass Valorization Moon, Seokyoon; Lee, Yunseok; Choi, Soyoung Organic Process Research & Development, Vol. 22, Issue 12 https://doi.org/10.1021/acs.oprd.8b00282	journal	October 2018
Mechanistic Study of Controlled Zinc Electrodeposition Behaviors Facilitated by Nanoscale Electrolyte Additives at the Electrode Interface Hamilton, Sara T.; Feric, Tony G.; Gładysiak, Andrzej ACS Applied Materials & Interfaces, Vol. 14, Issue 19 https://doi.org/10.1021/acsami.1c23781	journal	May 2022
Electrochemical Reduction of CO ₂ into Tunable Syngas Production by Regulating the Crystal Facets of Earth-Abundant Zn Catalyst Qin, Binhao; Li, Yuhang; Fu, Hongquan ACS Applied Materials & Interfaces, Vol. 10, Issue 24 https://doi.org/10.1021/acsami.8b04809	journal	May 2018
Confinement of Ionic Liquids at Single-Ni-Sites Boost Electroreduction of CO ₂ in Aqueous Electrolytes Ren, Wenhao; Tan, Xin; Chen, Xianjue ACS Catalysis, Vol. 10, Issue 22 https://doi.org/10.1021/acscatal.0c03873	journal	October 2020
Directing the Outcome of CO ₂ Reduction at Bismuth Cathodes Using Varied Ionic Liquid Promoters Atifi, Abderrahman; Boyce, David W.; DiMeglio, John L. ACS Catalysis, Vol. 8, Issue 4 https://doi.org/10.1021/acscatal.7b03433	journal	March 2018
Insight into the Microenvironments of the Metal–Ionic Liquid Interface during Electrochemical CO ₂ Reduction Lim, Hyung-Kyu; Kwon, Youngkook; Kim, Han Seul ACS Catalysis, Vol. 8, Issue 3 https://doi.org/10.1021/acscatal.7b03777	journal	January 2018
Influence of Atomic Surface Structure on the Activity of Ag for the Electrochemical Reduction of CO ₂ to CO Clark, Ezra L.; Ringe, Stefan; Tang, Michael ACS Catalysis, Vol. 9, Issue 5 https://doi.org/10.1021/acscatal.9b00260	journal	March 2019
Energy-Efficient CO₂ Capture Using Nonaqueous Absorbents of Secondary Alkanolamines with a 2-Butoxyethanol Cosolvent Ping, Tiantian; Dong, Yu; Shen, Shufeng ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 49 https://doi.org/10.1021/acssuschemeng.0c06345	journal	November 2020
Enhanced Electrocatalytic Activity of Primary Amines for CO₂ Reduction Using Copper Electrodes in Aqueous Solution Abdinejad, Maryam; Mirza, Zainab; Zhang, Xiao-an ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 4 https://doi.org/10.1021/acssuschemeng.9b06837	journal	January 2020
Achieving Multiple and Tunable Ratios of Syngas to Meet Various Downstream Industrial Processes Cui, Song; Yu, Chang; Tan, Xinyi ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 8 https://doi.org/10.1021/acssuschemeng.9b07255	journal	February 2020
Effect of SO ₂ on CO ₂ Capture Using Liquid-like Nanoparticle Organic Hybrid Materials Lin, Kun-Yi Andrew; Petit, Camille; Park, Ah-Hyung Alissa Energy & Fuels, Vol. 27, Issue 8 https://doi.org/10.1021/ef400374q	journal	June 2013
Effects of Bonding Types and Functional Groups on CO ₂ Capture using Novel Multiphase Systems of Liquid-like Nanoparticle Organic Hybrid Materials Lin, Kun-Yi Andrew; Park, Ah-Hyung Alissa Environmental Science & Technology, Vol. 45, Issue 15 https://doi.org/10.1021/es200146g	journal	August 2011
Ab Initio Study of the Reaction of Carbamate Formation from CO ₂ and Alkanolamines da Silva, Eirik F.; Svendsen, Hallvard F. Industrial & Engineering Chemistry Research, Vol. 43, Issue 13 https://doi.org/10.1021/ie030619k	journal	June 2004
Hydrolysis of Electrolyte Cations Enhances the Electrochemical Reduction of CO ₂ over Ag and Cu Singh, Meenesh R.; Kwon, Youngkook; Lum, Yanwei Journal of the American Chemical Society, Vol. 138, Issue 39 https://doi.org/10.1021/jacs.6b07612	journal	September 2016
The Central Role of Bicarbonate in the Electrochemical Reduction of Carbon Dioxide on Gold Dunwell, Marco; Lu, Qi; Heyes, Jeffrey M. Journal of the American Chemical Society, Vol. 139, Issue 10 https://doi.org/10.1021/jacs.6b13287	journal	March 2017
Nanoscale Hybrid Electrolytes with Viscosity Controlled Using Ionic Stimulus for Electrochemical Energy Conversion and Storage Hamilton, Sara T.; Feric, Tony G.; Bhattacharyya, Sahana JACS Au, Vol. 2, Issue 3 https://doi.org/10.1021/jacsau.1c00410	journal	March 2022
CO ₂ Capture Capacity and Swelling Measurements of Liquid-like Nanoparticle Organic Hybrid Materials via Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy Park, Youngjune; Shin, Dolly; Jang, Young Nam Journal of Chemical & Engineering Data, Vol. 57, Issue 1 https://doi.org/10.1021/je200623b	journal	October 2011
Spectroscopic Investigation of the Canopy Configurations in Nanoparticle Organic Hybrid Materials of Various Grafting Densities during CO ₂ Capture Petit, Camille; Park, Youngjune; Lin, Kun-Yi Andrew The Journal of Physical Chemistry C, Vol. 116, Issue 1 https://doi.org/10.1021/jp210391c	journal	December 2011
In Situ Spectroscopic Examination of a Low Overpotential Pathway for Carbon Dioxide Conversion to Carbon Monoxide Rosen, Brian A.; Haan, John L.; Mukherjee, Prabuddha The Journal of Physical Chemistry C, Vol. 116, Issue 29, p. 15307-15312 https://doi.org/10.1021/jp210542v	journal	July 2012
Prospects of CO₂ Utilization via Direct Heterogeneous Electrochemical Reduction Whipple, Devin T.; Kenis, Paul J. A. The Journal of Physical Chemistry Letters, Vol. 1, Issue 24, p. 3451-3458 https://doi.org/10.1021/jz1012627	journal	December 2010
Design and Characterization of Liquidlike POSS-Based Hybrid Nanomaterials Synthesized via Ionic Bonding and Their Interactions with CO ₂ Petit, Camille; Lin, Kun-Yi Andrew; Park, Ah-Hyung Alissa Langmuir, Vol. 29, Issue 39 https://doi.org/10.1021/la4007923	journal	September 2013
Switching the Reaction Course of Electrochemical CO ₂ Reduction with Ionic Liquids Sun, Liyuan; Ramesha, Ganganahalli K.; Kamat, Prashant V. Langmuir, Vol. 30, Issue 21 https://doi.org/10.1021/la5009076	journal	May 2014
The impact of nitrogen oxides on electrochemical carbon dioxide reduction Ko, Byung Hee; Hasa, Bjorn; Shin, Haeun Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-19731-8	journal	November 2020
Economics of converting renewable power to hydrogen Glenk, Gunther; Reichelstein, Stefan Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-019-0326-1	journal	February 2019
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels Birdja, Yuvraj Y.; Pérez-Gallent, Elena; Figueiredo, Marta C. Nature Energy, Vol. 4, Issue 9 https://doi.org/10.1038/s41560-019-0450-y	journal	September 2019
Electrochemical upgrade of CO2 from amine capture solution Lee, Geonhui; Li, Yuguang C.; Kim, Ji-Yong Nature Energy, Vol. 6, Issue 1 https://doi.org/10.1038/s41560-020-00735-z	journal	December 2020
Designing materials for electrochemical carbon dioxide recycling Ross, Michael B.; De Luna, Phil; Li, Yifan Nature Catalysis, Vol. 2, Issue 8 https://doi.org/10.1038/s41929-019-0306-7	journal	July 2019
Coupling electrochemical CO2 conversion with CO2 capture Sullivan, Ian; Goryachev, Andrey; Digdaya, Ibadillah A. Nature Catalysis, Vol. 4, Issue 11 https://doi.org/10.1038/s41929-021-00699-7	journal	November 2021
Thermal stability, swelling behavior and CO ₂ absorption properties of Nanoscale Ionic Materials (NIMs) Andrew Lin, Kun-Yi; Park, Youngjune; Petit, Camille RSC Adv., Vol. 4, Issue 110 https://doi.org/10.1039/C4RA10722E	journal	January 2014
Selective CO ₂ reduction on a polycrystalline Ag electrode enhanced by anodization treatment Zhou, Li Qin; Ling, Chen; Jones, Michael Chemical Communications, Vol. 51, Issue 100 https://doi.org/10.1039/C5CC06752A	journal	January 2015
Effects of electrolyte, catalyst, and membrane composition and operating conditions on the performance of solar-driven electrochemical reduction of carbon dioxide Singh, Meenesh R.; Clark, Ezra L.; Bell, Alexis T. Physical Chemistry Chemical Physics, Vol. 17, Issue 29 https://doi.org/10.1039/C5CP03283K	journal	January 2015
The effect of electrolyte composition on the electroreduction of CO ₂ to CO on Ag based gas diffusion electrodes Verma, Sumit; Lu, Xun; Ma, Sichao Physical Chemistry Chemical Physics, Vol. 18, Issue 10 https://doi.org/10.1039/C5CP05665A	journal	January 2016
A highly conductive, non-flammable polymer–nanoparticle hybrid electrolyte Agrawal, Akanksha; Choudhury, Snehashis; Archer, Lynden A. RSC Advances, Vol. 5, Issue 27 https://doi.org/10.1039/C5RA01031D	journal	January 2015
Review of liquid nano-absorbents for enhanced CO ₂ capture Yu, Wei; Wang, Tao; Park, Ah-Hyung Alissa Nanoscale, Vol. 11, Issue 37 https://doi.org/10.1039/C9NR05089B	journal	January 2019
Nanoporous hybrid electrolytes Schaefer, Jennifer L.; Moganty, Surya S.; Yanga, Dennis A. Journal of Materials Chemistry, Vol. 21, Issue 27 https://doi.org/10.1039/c0jm04171h	journal	January 2011
Investigation of CO2 capture mechanisms of liquid-like nanoparticle organic hybrid materials via structural characterization Park, Youngjune; Decatur, John; Lin, Kun-Yi Andrew Physical Chemistry Chemical Physics, Vol. 13, Issue 40 https://doi.org/10.1039/c1cp22631b	journal	January 2011
Effect of canopy structures and their steric interactions on CO2 sorption behavior of liquid-like nanoparticle organic hybrid materials Park, Youngjune; Petit, Camille; Han, Patrick RSC Advances, Vol. 4, Issue 17 https://doi.org/10.1039/c3ra46801a	journal	January 2014
Ionic Liquid-Mediated Selective Conversion of CO₂ to CO at Low Overpotentials Rosen, B. A.; Salehi-Khojin, A.; Thorson, M. R. Science, Vol. 334, Issue 6056, p. 643-644 https://doi.org/10.1126/science.1209786	journal	September 2011
Nanostructured transition metal dichalcogenide electrocatalysts for CO ₂ reduction in ionic liquid Asadi, Mohammad; Kim, Kibum; Liu, Cong Science, Vol. 353, Issue 6298 https://doi.org/10.1126/science.aaf4767	journal	July 2016
Design of an Electrochemical Cell Making Syngas (CO + H₂) from CO₂ and H₂O Reduction at Room Temperature Delacourt, Charles; Ridgway, Paul L.; Kerr, John B. Journal of The Electrochemical Society, Vol. 155, Issue 1, p. B42-B49 https://doi.org/10.1149/1.2801871	journal	January 2008
Electrochemical Reduction of Carbamates and Carbamic Acids: Implications for Combined Carbon Capture and Electrochemical CO₂ Recycling Bhattacharya, Moumita; Sebghati, Sepehr; Vercella, Yvensha Madeika Journal of The Electrochemical Society, Vol. 167, Issue 8 https://doi.org/10.1149/1945-7111/ab8ed0	journal	January 2020
Electrochemical Behavior of Copper Ion Complexed with Nanoparticle Organic Hybrid Materials Cantillo, Nelly M.; Bruce, Maria; Hamilton, Sara T. Journal of The Electrochemical Society, Vol. 167, Issue 11 https://doi.org/10.1149/1945-7111/aba158	journal	July 2020
Stability Analysis of Electrodeposition across a Structured Electrolyte with Immobilized Anions Tikekar, Mukul D.; Archer, Lynden A.; Koch, Donald L. Journal of The Electrochemical Society, Vol. 161, Issue 6 https://doi.org/10.1149/2.085405jes	journal	January 2014
Recent Advances in Anhydrous Solvents for CO2 Capture: Ionic Liquids, Switchable Solvents, and Nanoparticle Organic Hybrid Materials Park, Youngjune; Lin, Kun-Yi Andrew; Park, Ah-Hyung Alissa Frontiers in Energy Research, Vol. 3 https://doi.org/10.3389/fenrg.2015.00042	journal	October 2015
Carbon Capture From Flue Gas and the Atmosphere: A Perspective Wang, Xiaoxing; Song, Chunshan Frontiers in Energy Research, Vol. 8 https://doi.org/10.3389/fenrg.2020.560849	journal	December 2020
The Mechanism of Room-Temperature Ionic-Liquid-Based Electrochemical CO2 Reduction: A Review Lim, Hyung-Kyu; Kim, Hyungjun Molecules, Vol. 22, Issue 4 https://doi.org/10.3390/molecules22040536	journal	March 2017
Review on Innovative Catalytic Reforming of Natural Gas to Syngas Ghoneim, Salwa A.; El-Salamony, Radwa A.; El-Temtamy, Seham A. World Journal of Engineering and Technology, Vol. 04, Issue 01 https://doi.org/10.4236/wjet.2016.41011	journal	January 2016

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