Spin diffusion in the Phosphorus-31 NMR relaxation in a layered crystalline α-Sn(IV) phosphate contaminated by paramagnetic impurities

Bakhmutov, Vladimir I.; Elliott, Douglas W.; Bhuvanesh, Nattamai; Zhou, Hong-Cai

doi:10.1016/j.ssnmr.2023.101875

Spin diffusion in the Phosphorus-31 NMR relaxation in a layered crystalline α-Sn(IV) phosphate contaminated by paramagnetic impurities

Journal Article · Mon Jun 05 00:00:00 EDT 2023 · Solid State Nuclear Magnetic Resonance

DOI:https://doi.org/10.1016/j.ssnmr.2023.101875· OSTI ID:2420660

^[1]; Elliott, Douglas W. ^[2]; Bhuvanesh, Nattamai ^[2]; Zhou, Hong-Cai ^[2]

Texas A & M Univ., College Station, TX (United States); OSTI
Texas A & M Univ., College Station, TX (United States)

The study of a layered crystalline Sn(IV) phosphate by solid-state NMR has demonstrated that the ³¹P T₁ relaxation of phosphate groups, dependent on spinning rate is completely controlled by the limited spin diffusion to paramagnetic ions found by EPR. The spin-diffusion constant, D(SD), was estimated as 2.04 10^–14 cm²s^–1. Finally, the conclusion was supported by the ³¹P T₁ time measurements in zirconium phosphate 1–1, also showing paramagnetic ions and in diamagnetic compound (NH₄)₂HPO₄.

View Accepted Manuscript (DOE)

Research Organization:: Texas A & M Univ., College Station, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0017864

OSTI ID:: 2420660

Alternate ID(s):: OSTI ID: 1999874

Journal Information:: Solid State Nuclear Magnetic Resonance, Journal Name: Solid State Nuclear Magnetic Resonance Vol. 126; ISSN 0926-2040

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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