Investigations of room temperature multiferroic and magneto-electric properties of (1-Φ) PZTFT-Φ CZFMO particulate composites

Bhoi, Krishnamayee; Pradhan, Dhiren K.; Chandrakanta, K.; Simhachalam, Narendra Babu; Singh, A. K.; Vishwakarma, P. N.; Kumar, A.; Rack, Philip D.; Pradhan, Dillip K.

doi:10.1063/5.0120665

Investigations of room temperature multiferroic and magneto-electric properties of (1-Φ) PZTFT-Φ CZFMO particulate composites

Journal Article · Thu Jan 12 00:00:00 EST 2023 · Journal of Applied Physics

DOI:https://doi.org/10.1063/5.0120665· OSTI ID:2419622

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National Institute of Technology, Rourkela (India)
Univ. of Tennessee, Knoxville, TN (United States)
Osmania University, Hyderabad (India)
CSIR National Physical Laboratory, New Delhi (India)

Multiferroic composites consisting of a single-phase multiferroic [0.6(PbZr_0.53Ti_0.47O₃)-0.4(PbFe_0.5Ta_0.5)O₃] as a matrix and a magnetostrictive phase (Co_0.6Zn_0.4Fe_1.7Mn_0.3O₄) dispersed in the matrix are fabricated via hybrid synthesis technique. The structure and surface morphology studies using x-ray diffraction and field emission scanning electron microscopy techniques indicate the formation of 3-0 type particulate composites. Coexistence of soft-magnetic behavior and ferroelectric characteristics are confirmed for composites from magnetization vs magnetic field (M–H) and polarization vs electric field (P–E) measurements, respectively. Magneto-dielectric (MD) measurement shows significant changes in the dielectric properties with the application of a magnetic field, indicating the existence of strong MD behavior. The biquadratic nature of magneto-electric (ME) coupling is described by the Landau free energy equation arising from the strain transfer at the interfaces between the constituent phases. The direct magneto-electric voltage coefficient measurement also confirms very strong coupling between ferroelectricity and magnetism and supports the strain-mediated magneto-electric effect in composites. The Φ = 0.3 composite exhibits the maximum ME coefficient of 20.72 mV/cm Oe with M_S = 24.62 emu/g, H_C = 59.66 Oe, and piezoelectric coefficient value d₃₃ = 19 pC/N. In conclusion, the strong magneto-electric effect along with low dielectric loss at room temperature in these composites suggests their suitability for multifunctional magneto-electric device applications such as magnetic sensors, etc.

View Accepted Manuscript (DOE)

Research Organization:: Louisiana State Univ., Baton Rouge, LA (United States)

Sponsoring Organization:: USDOE; UGC DAE, CSR

Grant/Contract Number:: SC0002136

OSTI ID:: 2419622

Journal Information:: Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 2 Vol. 133; ISSN 0021-8979; ISSN 1089-7550

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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