Precise Control of Dissipative Self-assembly by Light and Electricity

Chen, Chunfeng; Guan, Zhibin

doi:10.1002/chem.202300347

Precise Control of Dissipative Self-assembly by Light and Electricity

Journal Article · Fri Feb 03 00:00:00 EST 2023 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.202300347· OSTI ID:2419023

Chen, Chunfeng ^[1]; ^[2]

Univ. of California, Irvine, CA (United States); OSTI
Univ. of California, Irvine, CA (United States)

Nature-inspired synthetic dissipative self-assemblies have attracted much attention recently. However, it remains a major challenge to achieve precise control over dissipative supramolecular assembly structures and functions of self-contained systems. Here we combine light and electricity as two clean, and spatiotemporally addressable fuels to provide precise control over the morphology for dissipative self-assembly of a perylene bisimide glycine (PBIg) building block in a self-contained solution. In this design, electrochemical oxidation provides the positive fuel to activate PBIg self-assembly while photoreduction supplies the negative fuel to deactivate the system for disassembly. Further, through programming the two counteracting fuels, we demonstrated the control of PBIg self-assembly into a variety of assembly morphologies in a self-contained system. In addition, by exerting light and electrical dual fuels simultaneously, we could create an active homeostasis exhibiting dynamic instability, leading to morphological change to asymmetric assemblies with curvatures. Such precise control over self-assembly of self-contained systems may find future applications in programming complex active materials as well as formulating pharmaceutical reagents with desired morphologies.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Irvine, CA (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-04ER46162

OSTI ID:: 2419023

Alternate ID(s):: OSTI ID: 1973291

Journal Information:: Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Journal Issue: 27 Vol. 29; ISSN 0947-6539

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Precise Control of Dissipative Self-assembly by Light and Electricity

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