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Viability of Cathodic Protection for Preventing Corrosion of Stainless Steel 316H in Molten LiF-NaF-KF

Journal Article · · Corrosion
DOI:https://doi.org/10.5006/4265· OSTI ID:2418318

Molten fluoride salts are candidate heat transfer fluids in a number of applications such as generation IV molten salt nuclear reactors and concentrated solar power plants. However, a chief concern in the design of these systems is the corrosion of structural materials that come in contact with these molten salts. Redox control methods such as the purification of salt, the addition of active elements, and applied electrochemical potential can be efficient methods for preventing the corrosion of structural materials in molten fluoride salts. Applied electrochemical potential as a redox control method for application in molten fluoride salts has rarely been explored. This study seeks to understand the viability of impressed current cathodic protection (CP) at various currents as a redox control method to prevent corrosion of stainless steel 316H in molten LiF-NaF-KF (FLiNaK) salt. Results show that application of CP can be an effective method to prevent corrosion of SS316H in molten FLiNaK salt, but the applied current will have to be optimized to prevent undesirable side effects such as reduction of salt constituents, salt deposition on electrodes, etc.

Research Organization:
Georgia Institute of Technology, Atlanta, GA (United States)
Sponsoring Organization:
USDOE Office of Nuclear Energy (NE)
DOE Contract Number:
NE0008749
OSTI ID:
2418318
Journal Information:
Corrosion, Journal Name: Corrosion Journal Issue: 7 Vol. 79; ISSN 0010-9312
Publisher:
NACE International
Country of Publication:
United States
Language:
English

References (9)

Interaction of beryllium with 316H stainless steel in molten Li2BeF4 (FLiBe) journal July 2022
Cathodic Protection in Molten Fluoride Salts at 1200 F journal July 1966
Redox potential control in molten salt systems for corrosion mitigation journal November 2018
Modeling the Effect of Cathodic Protection on Superalloys Inside High Temperature Molten Salt Systems journal January 2017
Effect of Li metal addition on corrosion control of Hastelloy N and stainless steel 316H in molten LiF-NaF-KF journal November 2021
Effect of oxide impurities on the corrosion behavior of structural materials in molten LiF-NaF-KF journal September 2022
Potentiodynamic Polarization of Pure Metals and Alloys in Molten LiF-NaF-KF (FLiNaK) Using the K/K+ Dynamic Reference Electrode journal July 2022
Effect of excess Mg to control corrosion in molten MgCl2 and KCl eutectic salt mixture journal January 2022
Cathodic protection of type 310S stainless steel in a chloride–bromide mixed molten salt at 923 K journal August 2019

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