Magnetic properties of vanadium(III) {mu}-oxo clusters
Journal Article
·
· Russian Journal of Coordination Chemistry
OSTI ID:240964
- Institute of Rare Element and Mineral Chemistry and Technology, Murnansk (Russian Federation)
Magnetic properties of the binuclear vanadium(III) {mu}-oxo complexes that have shortened V-O bonds are theoretically analyzed in terms of the MO LCAO method with due regard for configuration interaction. It is established that these complexes exhibit a wide variety of magnetic properties from strong ferromagnetism to strong antiferromagnetism, depending on the geometry of the [V{sub 2}({mu}-O)L{sub 10}] fragment. The factors favorable for one type or another of magnetic behavior are revealed. Theoretical results are shown to agree well with the known experimental data.
- OSTI ID:
- 240964
- Journal Information:
- Russian Journal of Coordination Chemistry, Journal Name: Russian Journal of Coordination Chemistry Journal Issue: 11 Vol. 21; ISSN RJCCEY
- Country of Publication:
- United States
- Language:
- English
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