Reactive capture and electrochemical conversion of CO 2 with ionic liquids and deep eutectic solvents

Dongare, Saudagar; Zeeshan, Muhammad; Aydogdu, Ahmet Safa; Dikki, Ruth; Kurtoğlu-Öztulum, Samira F.; Coskun, Oguz Kagan; Muñoz, Miguel; Banerjee, Avishek; Gautam, Manu; Ross, R. Dominic; Stanley, Jared S.; Brower, Rowan S.; Muchharla, Baleeswaraiah; Sacci, Robert L.; Velázquez, Jesús M.; Kumar, Bijandra; Yang, Jenny Y.; Hahn, Christopher; Keskin, Seda; Morales-Guio, Carlos G.; Uzun, Alper; Spurgeon, Joshua M.; Gurkan, Burcu

doi:10.1039/D4CS00390J

Reactive capture and electrochemical conversion of CO ₂ with ionic liquids and deep eutectic solvents

Journal Article · Tue Aug 27 00:00:00 EDT 2024 · Chemical Society Reviews

DOI:https://doi.org/10.1039/D4CS00390J· OSTI ID:2438116

^[1]; ^[1]; Aydogdu, Ahmet Safa ^[2]; Dikki, Ruth ^[1]; ^[3]; Coskun, Oguz Kagan ^[1]; Muñoz, Miguel ^[1]; ^[4]; Gautam, Manu ^[5]; ^[6]; ^[7]; Brower, Rowan S. ^[8]; ^[9]; ^[10]; ^[8]; Kumar, Bijandra ^[9]; ^[7]; Hahn, Christopher ^[6]; ^[2]; ^[4] more »

Chemical and Biomolecular Engineering, Case Western Reserve University, Cleveland, OH, 44106, USA
Department of Chemical and Biological Engineering, Koç University, Rumelifeneri Yolu, Sariyer, 34450 Istanbul, Turkey, Koç University TÜPRAŞ Energy Center (KUTEM), Koç University, Rumelifeneri Yolu, Sariyer, 34450 Istanbul, Turkey
Department of Chemical and Biological Engineering, Koç University, Rumelifeneri Yolu, Sariyer, 34450 Istanbul, Turkey, Koç University TÜPRAŞ Energy Center (KUTEM), Koç University, Rumelifeneri Yolu, Sariyer, 34450 Istanbul, Turkey, Department of Materials Science and Technology, Faculty of Science, Turkish-German University, Sahinkaya Cad., Beykoz, 34820 Istanbul, Turkey
Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, Los Angeles, CA 90095, USA
Conn Center for Renewable Energy Research, University of Louisville, Louisville, KY 40292, USA
Materials Science Division, Lawrence Livermore National Laboratory, Livermore, CA, 94550, USA
Department of Chemistry, University of California, Irvine, Irvine, CA 92697, USA
Department of Chemistry, University of California, Davis, Davis, CA 95616, USA
Department of Mathematics, Computer Science, & Engineering Technology, Elizabeth City State University, 1704 Weeksville Road, Elizabeth City, NC 27909, USA
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830, USA
Department of Chemical and Biological Engineering, Koç University, Rumelifeneri Yolu, Sariyer, 34450 Istanbul, Turkey, Koç University TÜPRAŞ Energy Center (KUTEM), Koç University, Rumelifeneri Yolu, Sariyer, 34450 Istanbul, Turkey, Koç University Surface Science and Technology Center (KUYTAM), Koç University, Rumelifeneri Yolu, Sariyer, 34450 Istanbul, Turkey

Ionic liquids (ILs) and deep eutectic solvents (DESs) have tremendous potential for reactive capture of CO ₂ , due to their highly properties, including a wide electrochemical stability window, low volatility, and high CO ₂ solubility.

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Research Organization:: Case Western Reserve University, Cleveland, OH (United States); Elizabeth City State University, NC (United States); Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: AC05-00OR22725; AC52-07NA27344; NA0004007; NA0004112; SC0019409; SC0022214; SC0023427

OSTI ID:: 2438116

Alternate ID(s):: OSTI ID: 2404385
OSTI ID: 2407058
OSTI ID: 2441033
OSTI ID: 2516794
OSTI ID: 2549350

Report Number(s):: LLNL--JRNL-2002785

Journal Information:: Chemical Society Reviews, Journal Name: Chemical Society Reviews Journal Issue: 17 Vol. 53; ISSN 0306-0012; ISSN CSRVBR

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Suppressing Co-Ion Generation via Cationic Proton Donors to Amplify Driving Forces for Electrochemical CO₂ Reduction Guo, Wenxiao; Liu, Beichen; Gebbie, Matthew A. The Journal of Physical Chemistry C, Vol. 127, Issue 29 https://doi.org/10.1021/acs.jpcc.3c04004	journal	July 2023
Porous Solids Impregnated with Task-Specific Ionic Liquids as Composite Sorbents Ruckart, K. Neil; O’Brien, Richard A.; Woodard, Seth M. The Journal of Physical Chemistry C, Vol. 119, Issue 35 https://doi.org/10.1021/acs.jpcc.5b04646	journal	August 2015
Theoretical Study of EMIM ⁺ Adsorption on Silver Electrode Surfaces Urushihara, Makoto; Chan, Karen; Shi, Chuan The Journal of Physical Chemistry C, Vol. 119, Issue 34 https://doi.org/10.1021/acs.jpcc.5b07268	journal	August 2015
Is the Imidazolium Cation a Unique Promoter for Electrocatalytic Reduction of Carbon Dioxide? Zhao, Shu-Feng; Horne, Mike; Bond, Alan M. The Journal of Physical Chemistry C, Vol. 120, Issue 42 https://doi.org/10.1021/acs.jpcc.6b08182	journal	October 2016
Carbon Dioxide Reduction in Room-Temperature Ionic Liquids: The Effect of the Choice of Electrode Material, Cation, and Anion Tanner, Eden E. L.; Batchelor-McAuley, Christopher; Compton, Richard G. The Journal of Physical Chemistry C, Vol. 120, Issue 46 https://doi.org/10.1021/acs.jpcc.6b10564	journal	November 2016
Improving Gas Separation Performance of ZIF-8 by [BMIM][BF ₄ ] Incorporation: Interactions and Their Consequences on Performance Koyuturk, Burak; Altintas, Cigdem; Kinik, F. Pelin The Journal of Physical Chemistry C, Vol. 121, Issue 19 https://doi.org/10.1021/acs.jpcc.7b00848	journal	May 2017
Electroanalytical Investigation of the Electrode–Electrolyte Interface of Quaternary Ammonium Ionic Liquids: Impact of Alkyl Chain Length and Ether Functionality Klein, Jeffrey M.; Squire, Henry; Gurkan, Burcu The Journal of Physical Chemistry C, Vol. 124, Issue 10 https://doi.org/10.1021/acs.jpcc.9b08016	journal	December 2019
In Situ Raman Monitoring of Potential-Dependent Adlayer Structures on the Au(111)/Ionic Liquid Interface Fu, Jia-Ying; Li, Xiao-Chong; Yu, Zhou Langmuir, Vol. 38, Issue 19 https://doi.org/10.1021/acs.langmuir.2c00703	journal	May 2022
Porous Polymer Supported Amino Functionalized Ionic Liquid for Effective CO₂ Capture Wu, Jianmeng; Yang, Zeying; Xie, Jiaqi Langmuir, Vol. 39, Issue 7 https://doi.org/10.1021/acs.langmuir.2c03217	journal	February 2023
Key Experimental Considerations When Evaluating Functional Ionic Liquids for Combined Capture and Electrochemical Conversion of CO₂ Dongare, Saudagar; Coskun, Oguz Kagan; Cagli, Eda Langmuir, Vol. 40, Issue 18 https://doi.org/10.1021/acs.langmuir.3c03828	journal	March 2024
Thermal Stability Limits of Imidazolium Ionic Liquids Immobilized on Metal-Oxides Babucci, Melike; Akçay, Aslı; Balci, Volkan Langmuir, Vol. 31, Issue 33 https://doi.org/10.1021/acs.langmuir.5b02519	journal	August 2015
Tuning the Gas Separation Performance of CuBTC by Ionic Liquid Incorporation Sezginel, Kutay B.; Keskin, Seda; Uzun, Alper Langmuir, Vol. 32, Issue 4 https://doi.org/10.1021/acs.langmuir.5b04123	journal	January 2016
Understanding the Influence of [EMIM]Cl on the Suppression of the Hydrogen Evolution Reaction on Transition Metal Electrodes Feaster, Jeremy T.; Jongerius, Anna L.; Liu, Xinyan Langmuir, Vol. 33, Issue 37 https://doi.org/10.1021/acs.langmuir.7b01170	journal	July 2017
Barriers of Electrochemical CO ₂ Reduction on Transition Metals Shi, Chuan; Chan, Karen; Yoo, Jong Suk Organic Process Research & Development, Vol. 20, Issue 8 https://doi.org/10.1021/acs.oprd.6b00103	journal	July 2016
CO ₂ Hydrogenation and Formic Acid Dehydrogenation Using Ir Catalysts with Amide-Based Ligands Kanega, Ryoichi; Ertem, Mehmed Z.; Onishi, Naoya Organometallics, Vol. 39, Issue 9 https://doi.org/10.1021/acs.organomet.9b00809	journal	February 2020
Principal Descriptors of Ionic Liquid Co-catalysts for the Electrochemical Reduction of CO₂ Vasilyev, Dmitry V.; Shyshkanov, Serhii; Shirzadi, Erfan ACS Applied Energy Materials, Vol. 3, Issue 5 https://doi.org/10.1021/acsaem.0c00330	journal	April 2020
Selective Electrooxidation of Glycerol to Formic Acid over Carbon Supported Ni_1–xM_x (M = Bi, Pd, and Au) Nanocatalysts and Coelectrolysis of CO₂ Houache, Mohamed S. E.; Safari, Reza; Nwabara, Uzoma O. ACS Applied Energy Materials, Vol. 3, Issue 9 https://doi.org/10.1021/acsaem.0c01282	journal	August 2020
Composite of MIL-101(Cr) with a Pyrrolidinium-Based Ionic Liquid Providing High CO₂ Selectivity Habib, Nitasha; Durak, Ozce; Gulbalkan, Hasan Can ACS Applied Engineering Materials, Vol. 1, Issue 6 https://doi.org/10.1021/acsaenm.3c00010	journal	May 2023
Capsules of Reactive Ionic Liquids for Selective Capture of Carbon Dioxide at Low Concentrations Lee, Yun-Yang; Edgehouse, Katelynn; Klemm, Aidan ACS Applied Materials & Interfaces, Vol. 12, Issue 16 https://doi.org/10.1021/acsami.0c01622	journal	April 2020
CO₂ Electroreduction on Silver Foams Modified by Ionic Liquids with Different Cation Side Chain Length Parada, Walter A.; Vasilyev, Dmitry V.; Mayrhofer, Karl J. J. ACS Applied Materials & Interfaces, Vol. 14, Issue 12 https://doi.org/10.1021/acsami.1c24386	journal	March 2022
Amino-Functionalized Ionic-Liquid-Grafted Covalent Organic Frameworks for High-Efficiency CO₂Capture and Conversion Yin, Meilin; Wang, Lipeng; Tang, Shaokun ACS Applied Materials & Interfaces, Vol. 14, Issue 50 https://doi.org/10.1021/acsami.2c18226	journal	December 2022
Designing Supported Ionic Liquids (ILs) within Inorganic Nanosheets for CO ₂ Capture Applications Zhou, Yingjie; Liu, Jingjing; Xiao, Min ACS Applied Materials & Interfaces, Vol. 8, Issue 8 https://doi.org/10.1021/acsami.5b11249	journal	February 2016
[BMIM][PF ₆ ] Incorporation Doubles CO ₂ Selectivity of ZIF-8: Elucidation of Interactions and Their Consequences on Performance Kinik, F. Pelin; Altintas, Cigdem; Balci, Volkan ACS Applied Materials & Interfaces, Vol. 8, Issue 45 https://doi.org/10.1021/acsami.6b11087	journal	November 2016
New Class of Type III Porous Liquids: A Promising Platform for Rational Adjustment of Gas Sorption Behavior Shan, Weida; Fulvio, Pasquale F.; Kong, Liyun ACS Applied Materials & Interfaces, Vol. 10, Issue 1 https://doi.org/10.1021/acsami.7b15873	journal	December 2017
Facile Approach to Graft Ionic Liquid into MOF for Improving the Efficiency of CO ₂ Chemical Fixation Sun, Yuxiu; Huang, Hongliang; Vardhan, Harsh ACS Applied Materials & Interfaces, Vol. 10, Issue 32 https://doi.org/10.1021/acsami.8b08914	journal	July 2018
Trends in Solid Adsorbent Materials Development for CO ₂ Capture Pardakhti, Maryam; Jafari, Tahereh; Tobin, Zachary ACS Applied Materials & Interfaces, Vol. 11, Issue 38 https://doi.org/10.1021/acsami.9b08487	journal	June 2019
Effect of Surface Characteristics of Graphene Aerogels and Hydrophilicity of Ionic Liquids on the CO₂/CH₄ Separation Performance of Ionic Liquid/Reduced Graphene Aerogel Composites Caglayan, Hatice Pelin; Unal, Ugur; Keskin, Seda ACS Applied Nano Materials, Vol. 6, Issue 3 https://doi.org/10.1021/acsanm.2c05476	journal	February 2023
Ionic Liquid-Impregnated Metal–Organic Frameworks for CO₂/CH₄ Separation Ferreira, Tiago J.; Ribeiro, Rui P. P. L.; Mota, José P. B. ACS Applied Nano Materials, Vol. 2, Issue 12 https://doi.org/10.1021/acsanm.9b01936	journal	November 2019
The Role of Organic Promoters in the Electroreduction of Carbon Dioxide Vasilyev, Dmitry V.; Dyson, Paul J. ACS Catalysis, Vol. 11, Issue 3 https://doi.org/10.1021/acscatal.0c04283	journal	January 2021
Carbon-Based Materials for Electrochemical Reduction of CO ₂ to C ₂₊ Oxygenates: Recent Progress and Remaining Challenges Zhao, Kun; Quan, Xie ACS Catalysis, Vol. 11, Issue 4 https://doi.org/10.1021/acscatal.0c04714	journal	February 2021
Dramatic HER Suppression on Ag Electrodes via Molecular Films for Highly Selective CO ₂ to CO Reduction Thevenon, Arnaud; Rosas-Hernández, Alonso; Fontani Herreros, Alex M. ACS Catalysis, Vol. 11, Issue 8 https://doi.org/10.1021/acscatal.1c00338	journal	March 2021
Interfacial Electrolyte Effects on Electrocatalytic CO₂ Reduction Deng, Bangwei; Huang, Ming; Zhao, Xiaoli ACS Catalysis, Vol. 12, Issue 1 https://doi.org/10.1021/acscatal.1c03501	journal	December 2021
Tuning Ionic Screening To Accelerate Electrochemical CO₂ Reduction in Ionic Liquid Electrolytes Liu, Beichen; Guo, Wenxiao; Gebbie, Matthew A. ACS Catalysis, Vol. 12, Issue 15 https://doi.org/10.1021/acscatal.2c02154	journal	July 2022
Reactive Capture of CO₂: Opportunities and Challenges Siegel, Rachel E.; Pattanayak, Santanu; Berben, Louise A. ACS Catalysis, Vol. 13, Issue 1 https://doi.org/10.1021/acscatal.2c05019	journal	December 2022
A Bifunctional Ionic Liquid for Capture and Electrochemical Conversion of CO₂ to CO over Silver Dongare, Saudagar; Coskun, Oguz Kagan; Cagli, Eda ACS Catalysis, Vol. 13, Issue 12 https://doi.org/10.1021/acscatal.3c01538	journal	May 2023
Uncovering the Active Species in Amine-Mediated CO₂ Reduction to CO on Ag Leverick, Graham; Bernhardt, Elizabeth M.; Ismail, Aisyah Ilyani ACS Catalysis, Vol. 13, Issue 18 https://doi.org/10.1021/acscatal.3c02500	journal	September 2023
Subnanometer Cu Clusters on Porous Ag Enhancing Ethanol Production in Electrochemical CO₂ Reduction Park, Jiwon; Jeong, Chaehwa; Na, Moony ACS Catalysis, Vol. 14, Issue 5 https://doi.org/10.1021/acscatal.3c03469	journal	February 2024
Thermodynamic Aspects of Electrocatalytic CO ₂ Reduction in Acetonitrile and with an Ionic Liquid as Solvent or Electrolyte Matsubara, Yasuo; Grills, David C.; Kuwahara, Yutaka ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b00656	journal	October 2015
Tetraarylphosphonium Salt-Catalyzed Carbon Dioxide Fixation at Atmospheric Pressure for the Synthesis of Cyclic Carbonates Toda, Yasunori; Komiyama, Yutaka; Kikuchi, Ayaka ACS Catalysis, Vol. 6, Issue 10 https://doi.org/10.1021/acscatal.6b02265	journal	September 2016
Electric Field Effects in Electrochemical CO ₂ Reduction Chen, Leanne D.; Urushihara, Makoto; Chan, Karen ACS Catalysis, Vol. 6, Issue 10 https://doi.org/10.1021/acscatal.6b02299	journal	September 2016
Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes Feaster, Jeremy T.; Shi, Chuan; Cave, Etosha R. ACS Catalysis, Vol. 7, Issue 7 https://doi.org/10.1021/acscatal.7b00687	journal	June 2017
Tuning the Selectivity of Single-Site Supported Metal Catalysts with Ionic Liquids Babucci, Melike; Fang, Chia-Yu; Hoffman, Adam S. ACS Catalysis, Vol. 7, Issue 10 https://doi.org/10.1021/acscatal.7b02429	journal	September 2017
Directing the Outcome of CO ₂ Reduction at Bismuth Cathodes Using Varied Ionic Liquid Promoters Atifi, Abderrahman; Boyce, David W.; DiMeglio, John L. ACS Catalysis, Vol. 8, Issue 4 https://doi.org/10.1021/acscatal.7b03433	journal	March 2018
Insight into the Microenvironments of the Metal–Ionic Liquid Interface during Electrochemical CO ₂ Reduction Lim, Hyung-Kyu; Kwon, Youngkook; Kim, Han Seul ACS Catalysis, Vol. 8, Issue 3 https://doi.org/10.1021/acscatal.7b03777	journal	January 2018
Selective Carbon Dioxide Hydrogenation Driven by Ferromagnetic RuFe Nanoparticles in Ionic Liquids Qadir, Muhammad I.; Weilhard, Andreas; Fernandes, Jesum A. ACS Catalysis, Vol. 8, Issue 2 https://doi.org/10.1021/acscatal.7b03804	journal	January 2018
Challenges and Prospects in Solar Water Splitting and CO ₂ Reduction with Inorganic and Hybrid Nanostructures Stolarczyk, Jacek K.; Bhattacharyya, Santanu; Polavarapu, Lakshminarayana ACS Catalysis, Vol. 8, Issue 4 https://doi.org/10.1021/acscatal.8b00791	journal	March 2018
In Situ Monitoring Using ATR-SEIRAS of the Electrocatalytic Reduction of CO ₂ on Au in an Ionic Liquid/Water Mixture Papasizza, Marco; Cuesta, Angel ACS Catalysis, Vol. 8, Issue 7 https://doi.org/10.1021/acscatal.8b00977	journal	May 2018
Understanding Surface-Mediated Electrochemical Reactions: CO ₂ Reduction and Beyond Dunwell, Marco; Luc, Wesley; Yan, Yushan ACS Catalysis, Vol. 8, Issue 9 https://doi.org/10.1021/acscatal.8b02181	journal	July 2018
Mechanistic Insights on CO₂ Reduction Reactions at Platinum/[BMIM][BF₄] Interfaces from In Operando Spectroscopy Kemna, Andre; García Rey, Natalia; Braunschweig, Björn ACS Catalysis, Vol. 9, Issue 7 https://doi.org/10.1021/acscatal.9b01033	journal	June 2019
Using a 3D Porous Flow-Through Electrode Geometry for High-Rate Electrochemical Reduction of CO ₂ to CO in Ionic Liquid Vedharathinam, Vedasri; Qi, Zhen; Horwood, Corie ACS Catalysis, Vol. 9, Issue 12 https://doi.org/10.1021/acscatal.9b03201	journal	October 2019
Dual Salt Cation-Swing Process for Electrochemical CO₂ Separation Kuo, Fang-Yu; Jerng, Sung Eun; Gallant, Betar M. ACS Central Science, Vol. 9, Issue 9 https://doi.org/10.1021/acscentsci.3c00692	journal	August 2023
Electrodes Designed for Converting Bicarbonate into CO Lees, Eric W.; Goldman, Maxwell; Fink, Arthur G. ACS Energy Letters, Vol. 5, Issue 7 https://doi.org/10.1021/acsenergylett.0c00898	journal	June 2020
CO ₂ Electroreduction to Formate at a Partial Current Density of 930 mA cm ^–2 with InP Colloidal Quantum Dot Derived Catalysts Grigioni, Ivan; Sagar, Laxmi Kishore; Li, Yuguang C. ACS Energy Letters, Vol. 6, Issue 1 https://doi.org/10.1021/acsenergylett.0c02165	journal	December 2020
Ethylene Electrosynthesis: A Comparative Techno-economic Analysis of Alkaline vs Membrane Electrode Assembly vs CO ₂ –CO–C ₂ H ₄ Tandems Sisler, Jared; Khan, Shaihroz; Ip, Alexander H. ACS Energy Letters, Vol. 6, Issue 3 https://doi.org/10.1021/acsenergylett.0c02633	journal	February 2021
What It Takes for Imidazolium Cations to Promote Electrochemical Reduction of CO₂ Neyrizi, Sobhan; Kiewiet, Joep; Hempenius, Mark A. ACS Energy Letters, Vol. 7, Issue 10 https://doi.org/10.1021/acsenergylett.2c01372	journal	September 2022
Ammonia-Mediated CO₂ Capture and Direct Electroreduction to Formate Liu, Hengzhou; Chen, Yifu; Lee, Jungkuk ACS Energy Letters, Vol. 7, Issue 12 https://doi.org/10.1021/acsenergylett.2c02247	journal	November 2022
Hydrodynamics Change Tafel Slopes in Electrochemical CO₂ Reduction on Copper Watkins, Nicholas B.; Schiffer, Zachary J.; Lai, Yungchieh ACS Energy Letters, Vol. 8, Issue 5 https://doi.org/10.1021/acsenergylett.3c00442	journal	April 2023
Electroreduction of CO₂: Advances in the Continuous Production of Formic Acid and Formate Fernández-Caso, Kevin; Díaz-Sainz, Guillermo; Alvarez-Guerra, Manuel ACS Energy Letters, Vol. 8, Issue 4 https://doi.org/10.1021/acsenergylett.3c00489	journal	March 2023
Integration of CO₂ Capture and Electrochemical Conversion Xia, Qing; Zhang, Kouer; Zheng, Tingting ACS Energy Letters, Vol. 8, Issue 6 https://doi.org/10.1021/acsenergylett.3c00738	journal	June 2023
Tuning Surface Reactivity and Electric Field Strength via Intermetallic Alloying Clark, Ezra L.; Nielsen, Rasmus; Sørensen, Jakob Ejler ACS Energy Letters, Vol. 8, Issue 10 https://doi.org/10.1021/acsenergylett.3c01639	journal	September 2023
Detrimental Effects of Monoethanolamine and Other Amine-Based Capture Agents on the Electrochemical Reduction of CO₂ Safipour, John; Weber, Adam Z.; Bell, Alexis T. ACS Energy Letters, Vol. 8, Issue 12 https://doi.org/10.1021/acsenergylett.3c01953	journal	November 2023
Electrochemical Capture and Release of Carbon Dioxide Rheinhardt, Joseph H.; Singh, Poonam; Tarakeshwar, Pilarisetty ACS Energy Letters, Vol. 2, Issue 2 https://doi.org/10.1021/acsenergylett.6b00608	journal	January 2017
Achieving Highly Efficient, Selective, and Stable CO ₂ Reduction on Nitrogen-Doped Carbon Nanotubes Wu, Jingjie; Yadav, Ram Manohar; Liu, Mingjie ACS Nano, Vol. 9, Issue 5 https://doi.org/10.1021/acsnano.5b01079	journal	April 2015
Will Any Crap We Put into Graphene Increase Its Electrocatalytic Effect? Wang, Lu; Sofer, Zdenek; Pumera, Martin ACS Nano, Vol. 14, Issue 1 https://doi.org/10.1021/acsnano.9b00184	journal	January 2020
Hydrophobic Functional Deep Eutectic Solvents Used for Efficient and Reversible Capture of CO₂ Gu, Yanxue; Hou, Yucui; Ren, Shuhang ACS Omega, Vol. 5, Issue 12 https://doi.org/10.1021/acsomega.0c00150	journal	March 2020
Improving the Separation of CO₂/CH₄ Using Impregnation of Deep Eutectic Solvents on Porous Carbon Ariyanto, Teguh; Masruroh, Kuni; Pambayun, Gita Yunita Sri ACS Omega, Vol. 6, Issue 29 https://doi.org/10.1021/acsomega.1c02545	journal	July 2021
Experimental Insight into the Thermodynamics of the Dissolution of Electrolytes in Room-Temperature Ionic Liquids: From the Mass Action Law to the Absolute Standard Chemical Potential of a Proton Matsubara, Yasuo; Grills, David C.; Koide, Yoshihiro ACS Omega, Vol. 1, Issue 6 https://doi.org/10.1021/acsomega.6b00129	journal	December 2016
Toward Rational Design of Ionic Liquid/Metal–Organic Framework Composites: Effects of Interionic Interaction Energy Nozari, Vahid; Keskin, Seda; Uzun, Alper ACS Omega, Vol. 2, Issue 10 https://doi.org/10.1021/acsomega.7b01074	journal	October 2017
Insights into the Dielectric-Heating-Enhanced Regeneration of CO₂-Rich Aqueous Amine Solutions Tsubaki, Shuntaro; Furusawa, Kosuke; Yamada, Hidetaka ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 36 https://doi.org/10.1021/acssuschemeng.0c05342	journal	August 2020
Deep Eutectic Solvent Formed by Imidazolium Cyanopyrrolide and Ethylene Glycol for Reactive CO₂ Separations Lee, Yun-Yang; Penley, Drace; Klemm, Aidan ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 3 https://doi.org/10.1021/acssuschemeng.0c07217	journal	January 2021
One-Pot Multiple-Step Integration Strategy for Efficient Fixation of CO₂ into Chain Carbonates by Azolide Anions Poly(ionic liquid)s He, Yuting; Li, Xue; Cai, Wenyi ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 20 https://doi.org/10.1021/acssuschemeng.1c01187	journal	May 2021
Encapsulation of Ru Complexes into Poly(ionic liquid) Enables the Methanation of CO₂ under Mild Conditions Wang, Rui; Du, Yi-Ran; Ding, Guang-Rong ACS Sustainable Chemistry & Engineering, Vol. 10, Issue 16 https://doi.org/10.1021/acssuschemeng.2c00891	journal	April 2022
Comparative Technoeconomic Analysis of Pathways for Electrochemical Reduction of CO₂ with Methanol to Produce Methyl Formate Spurgeon, Joshua M.; Theaker, Nolan; Phipps, Christine A. ACS Sustainable Chemistry & Engineering, Vol. 10, Issue 38 https://doi.org/10.1021/acssuschemeng.2c04362	journal	September 2022
Impact of Hydrogen Bonds on CO₂ Binding in Eutectic Solvents: An Experimental and Computational Study toward Sorbent Design for CO₂ Capture Klemm, Aidan; Vicchio, Stephen P.; Bhattacharjee, Sanchari ACS Sustainable Chemistry & Engineering, Vol. 11, Issue 9 https://doi.org/10.1021/acssuschemeng.2c06767	journal	February 2023
Effect of Hydrogen Bonds on CO₂ Capture by Functionalized Deep Eutectic Solvents Derived from 4-Fluorophenol Wang, Zonghua; Chen, Mingzhe; Lu, Bohao ACS Sustainable Chemistry & Engineering, Vol. 11, Issue 16 https://doi.org/10.1021/acssuschemeng.2c07590	journal	April 2023
Quinone Reduction in Ionic Liquids for Electrochemical CO ₂ Separation Gurkan, Burcu; Simeon, Fritz; Hatton, T. Alan ACS Sustainable Chemistry & Engineering, Vol. 3, Issue 7 https://doi.org/10.1021/acssuschemeng.5b00116	journal	June 2015
Temperature-Controlled Reaction–Separation for Conversion of CO₂ to Carbonates with Functional Ionic Liquids Catalyst Meng, Xianglei; He, Hongyan; Nie, Yi ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 4 https://doi.org/10.1021/acssuschemeng.6b02612	journal	February 2017
Efficient Synthesis of Cyclic Carbonates from Atmospheric CO₂ Using a Positive Charge Delocalized Ionic Liquid Catalyst Zhang, Zhiguo; Fan, Fangjun; Xing, Huabin ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 4 https://doi.org/10.1021/acssuschemeng.7b00513	journal	March 2017
DBU-Based Protic Ionic Liquids for CO ₂ Capture Zhu, Xiao; Song, Mengling; Xu, Yingjie ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 9 https://doi.org/10.1021/acssuschemeng.7b01839	journal	August 2017
CO₂ Capture by Supported Ionic Liquid Phase: Highlighting the Role of the Particle Size Santiago, Ruben; Lemus, Jesus; Hospital-Benito, Daniel ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 15 https://doi.org/10.1021/acssuschemeng.9b02277	journal	June 2019
Effect of Water on CO ₂ Capture by Aprotic Heterocyclic Anion (AHA) Ionic Liquids Avelar Bonilla, Gabriela M.; Morales-Collazo, Oscar; Brennecke, Joan F. ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 19 https://doi.org/10.1021/acssuschemeng.9b04424	journal	September 2019
Enhanced Electrocatalytic Activity of Primary Amines for CO₂ Reduction Using Copper Electrodes in Aqueous Solution Abdinejad, Maryam; Mirza, Zainab; Zhang, Xiao-an ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 4 https://doi.org/10.1021/acssuschemeng.9b06837	journal	January 2020
Superbase Ionic Liquid-Based Deep Eutectic Solvents for Improving CO ₂ Absorption Yan, Hong; Zhao, Lei; Bai, Yinge ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 6 https://doi.org/10.1021/acssuschemeng.9b07128	journal	January 2020
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Reactive capture and electrochemical conversion of CO ₂ with ionic liquids and deep eutectic solvents