Interplanar Ferromagnetism Enhanced Ultrawide Zero Thermal Expansion in Kagome Cubic Intermetallic (Zr,Nb)Fe2

Sun, Yanming; Cao, Yili; Hu, Shixin; Avdeev, Maxim; Wang, Chin-Wei; Khmelevskyi, Sergii; Ren, Yang; Lapidus, Saul H.; Chen, Xin; Li, Qiang; Deng, Jinxia; Miao, Jun; Lin, Kun; Kuang, Xiaojun; Xing, Xianran

doi:10.1021/jacs.3c03160

Interplanar Ferromagnetism Enhanced Ultrawide Zero Thermal Expansion in Kagome Cubic Intermetallic (Zr,Nb)Fe₂

Journal Article · Tue Jul 25 04:00:00 EDT 2023 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.3c03160· OSTI ID:2404919

Sun, Yanming ^[1]; ^[1]; Hu, Shixin ^[2]; ^[3]; Wang, Chin-Wei ^[4]; Khmelevskyi, Sergii ^[5]; ^[6]; ^[7]; Chen, Xin ^[1]; ^[1]; Deng, Jinxia ^[1]; ^[1]; ^[1]; ^[8]; ^[1]

Univ. of Science and Technology, Beijing (China)
Lanzhou Univ. (China)
Australian Nuclear Science and Technology Organisation (ANSTO), Lucas Heights, NSW (Australia); Univ. of Sydney, NSW (Australia)
National Synchrotron Radiation Research Center, Hsinchu (Taiwan)
Vienna Univ. of Technology (Austria)
City Univ. of Hong Kong, Kowloon (Hong Kong)
Argonne National Laboratory (ANL), Argonne, IL (United States)
Guilin University of Technology (China)

A cubic metal exhibiting zero thermal expansion (ZTE) over a wide temperature window demonstrates significant applications in a broad range of advanced technologies but is extremely rare in nature. Here, enabled by high-temperature synthesis, we realize tunable thermal expansion via magnetic doping in the class of kagome cubic (Fd-3m) intermetallic (Zr,Nb)Fe₂. A remarkably isotropic ZTE is achieved with a negligible coefficient of thermal expansion (+0.47 x 10^-6 K^-1) from 4 to 425 K, almost wider than most ZTE in metals available. A combined in situ magnetization, neutron powder diffraction, and hyperfine Mössbauer spectrum analysis reveals that interplanar ferromagnetic ordering contributes to a large magnetic compensation for normal lattice contraction upon cooling. Trace Fe-doping introduces extra magnetic exchange interactions that distinctly enhance the ferromagnetism and magnetic ordering temperature, thus engendering such an ultrawide ZTE. Finally, this work presents a promising ZTE in kagome metallic materials.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Key Research and Development Program of China; National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2404919

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 31 Vol. 145; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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