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Understanding the interplay between pilot fuel mixing and auto-ignition chemistry in hydrogen-enriched environment

Journal Article · · Proceedings of the Combustion Institute
 [1];  [2];  [1]
  1. Sandia National Lab. (SNL-CA), Livermore, CA (United States). Combustion Research Facility
  2. Sandia National Lab. (SNL-CA), Livermore, CA (United States). Combustion Research Facility; Colorado School of Mines, Golden, CO (United States)

The diesel-piloted dual-fuel compression ignition combustion strategy is well-suited to accelerate the decarbonization of transportation by adopting hydrogen as a renewable energy carrier into the existing internal combustion engine with minimal engine modifications. Despite the simplicity of engine modification, many questions remain unanswered regarding the optimal pilot injection strategy for reliable ignition with minimum pilot fuel consumption. The present study uses a single-cylinder heavy-duty optical engine to explore the phenomenology and underlying mechanisms governing the pilot fuel ignition and the subsequent combustion of a premixed hydrogen-air charge. The engine is operated in a dual-fuel mode with hydrogen premixed into the engine intake charge with a direct pilot injection of n-heptane as a diesel pilot fuel surrogate. Optical diagnostics used to visualize in-cylinder combustion phenomena include high-speed IR imaging of the pilot fuel spray evolution as well as high-speed HCHO* and OH* chemiluminescence as indicators of low-temperature and high-temperature heat release, respectively. Three pilot injection strategies are compared to explore the effects of pilot fuel mass, injection pressure, and injection duration on the probability and repeatability of successful ignition. The thermodynamic and imaging data analysis supported by zero-dimensional chemical kinetics simulations revealed a complex interplay between the physical and chemical processes governing the pilot fuel ignition process in a hydrogen containing charge. Hydrogen strongly inhibits the ignition of pilot fuel mixtures and therefore requires longer injection duration to create zones with sufficiently high pilot fuel concentration for successful ignition. Results show that ignition typically tends to rely on stochastic pockets with high pilot fuel concentration, which results in poor repeatability of combustion and frequent misfiring. In conclusion, this work has improved the understanding on how the unique chemical properties of hydrogen pose a challenge for maximization of hydrogen’s energy share in hydrogen dual-fuel engines and highlights a potential mitigation pathway.

Research Organization:
Sandia National Laboratories (SNL-CA), Livermore, CA (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
NA0003525
OSTI ID:
2404609
Report Number(s):
SAND--2024-08951J
Journal Information:
Proceedings of the Combustion Institute, Journal Name: Proceedings of the Combustion Institute Journal Issue: 1-4 Vol. 40; ISSN 1540-7489
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

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Effect of post injections on mixture preparation and unburned hydrocarbon emissions in a heavy-duty diesel engine journal August 2016
Experimental investigations on effect of different compression ratios on enhancement of maximum hydrogen energy share in a compression ignition engine under dual-fuel mode journal July 2015
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An experimental study of a direct injection compression ignition hydrogen engine journal August 2009
Feasibility of compression ignition for hydrogen fueled engine with neat hydrogen-air pre-mixture by using high compression journal January 2013
Hydrogen-diesel dual-fuel direct-injection (H2DDI) combustion under compression-ignition engine conditions journal January 2023
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A comprehensive review of measurements and data analysis of laminar burning velocities for various fuel+air mixtures journal September 2018
Kinetic modeling of gasoline surrogate components and mixtures under engine conditions journal January 2011
Effect of methane on pilot-fuel auto-ignition in dual-fuel engines journal January 2019
Influence of pilot-fuel mixing on the spatio-temporal progression of two-stage autoignition of diesel-sprays in low-reactivity ambient fuel-air mixture journal January 2021
Alternative Fuels for Internal Combustion Engines journal August 2020
Entrainment Waves in Diesel Jets journal April 2009
Effects of Injection Pressure and Ambient Gas Density on Fuel - Ambient Gas Mixing and Combustion Characteristics of D.I. Diesel Spray conference August 2011
Impact of Hydrogen on the Ignition and Combustion Behavior Diesel Sprays in a Dual Fuel, Diesel-Piloted, Premixed Hydrogen Engine conference August 2023
Impact of Mixture Inhomogeneity and Ignition Location on Early Flame Kernel Evolution in a Direct-Injection Hydrogen-Fueled Heavy-Duty Optical Engine conference September 2023

Figures / Tables (6)


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