Whole-Voltage-Range Solid-Solution Reaction in Layered Oxide Cathode of Sodium-Ion Batteries

Ren, Meng; Zhu, Zhuo; Liang, Zhaohui; Huang, Yaohui; Zhang, Tong; Hou, Machuan; Zhang, Kai; Chen, Zonghai; He, Yushi; Ma, Zifeng; Chen, Jun; Li, Fujun

doi:10.1002/smll.202304187

Whole-Voltage-Range Solid-Solution Reaction in Layered Oxide Cathode of Sodium-Ion Batteries

Journal Article · Mon Aug 21 04:00:00 EDT 2023 · Small

DOI:https://doi.org/10.1002/smll.202304187· OSTI ID:2403518

^[1]; Zhu, Zhuo ^[1]; Liang, Zhaohui ^[1]; Huang, Yaohui ^[1]; Zhang, Tong ^[1]; Hou, Machuan ^[1]; Zhang, Kai ^[2]; Chen, Zonghai ^[3]; He, Yushi ^[4]; Ma, Zifeng ^[4]; Chen, Jun ^[2]; ^[2]

Nankai University, Tianjin (China)
Nankai University, Tianjin (China); Haihe Laboratory of Sustainable Chemical Transformations, Tianjin (China)
Argonne National Laboratory (ANL), Argonne, IL (United States)
Shanghai Jiao Tong Univ. (China)

Layered manganese-based oxides (LMOs) are promising cathode materials for sodium-ion batteries (SIBs) due to their versatile structures. However, the Jahn–Teller effect of Mn³⁺ induces severe distortion of MnO₆ octahedra, and the resultant low symmetry is responsible for the gliding of MnO₂ layers and then inferior multiple-phase transitions upon Na⁺ extraction/insertion. Here, hexagonal P2-Na_0.643Li_0.078Mn_0.827Ti_0.095O₂ is synthesized through the incorporation of Li and Ti into the distorted orthorhombic P'2-Na_0.67MnO₂ to function as a phase-transition-free oxide cathode. Further, it is revealed that Li in both the transition-metal and Na layers enhances the covalency of Mn–O bonds and allows degeneracy of Mn 3d e_g orbitals to favor the formation of hexagonal phase, and the high strength of Ti–O bonds reduces the electrostatic interaction between Na and O for suppressed Na⁺/vacancy rearrangements. These collectively lead to a whole-voltage-range solid-solution reaction between 1.8 and 4.3 V with a small volume variation of 1.49%. This rewards its excellent cycling stability (capacity retention of 90% after 500 cycles) and rate capability (89 mAh g^-1 at 2000 mA g^-1).

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); National Natural Science Foundation of China (NSFC); Tianjin Natural Science Foundation

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2403518

Alternate ID(s):: OSTI ID: 2229189

Journal Information:: Small, Journal Name: Small Journal Issue: 49 Vol. 19; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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