Raman spectroscopic study of anhydrous and hydrous REE phosphates, oxides, and hydroxides

Hurtig, Nicole C.; Gysi, Alexander P.; Smith-Schmitz, Sarah E.; Harlov, Daniel

doi:10.1039/d4dt01086h

Raman spectroscopic study of anhydrous and hydrous REE phosphates, oxides, and hydroxides

Journal Article · Wed May 22 00:00:00 EDT 2024 · Dalton Transactions

DOI:https://doi.org/10.1039/d4dt01086h· OSTI ID:2402993

^[1]; ^[2]; Smith-Schmitz, Sarah E. ^[2]; Harlov, Daniel ^[3]

New Mexico Institute of Mining and Technology, Socorro, NM (United States); New Mexico Bureau of Geology/New Mexico Institute of Mining and Technology
New Mexico Institute of Mining and Technology, Socorro, NM (United States)
Deutsches GeoForschungsZentrum GFZ, Potsdam (Germany); China University of Geosciences, Wuhan (China); University of Johannesburg (South Africa)

Rare earth elements (REE) include the lanthanides (La–Lu), Y, and Sc which are critical elements for the green energy transition. The REE show a decrease in ionic radii with increased atomic numbers, which results in a so-called lanthanide contraction systematically affecting crystal structures and mineral properties. Here we present a compilation of reference Raman spectra of ten REE sesquioxides (A-, B- and C-type), five REE hydroxides, eight xenotime-structured REE phosphate endmembers and two solid solutions, seven monazite-structured REE phosphate endmembers and two solid solutions and seven rhabdophane endmembers with up to five Ce_1–xLREE_x rhabdophane solid solutions (LREE = La–Gd). Raman mode assignment is based on a detailed literature review summarizing existing analytical work and theoretical calculations and systematic trends observed in this study by analyzing different REE-bearing solids. Here, the wavenumbers of the main REE-O Raman band systematically increase with decreasing ionic radii forming discrete linear trends within isostructural mineral groups, that can be used to estimate the REE-O mode in other solids with known REE-O coordination numbers. Photoluminescence using 266 nm, 532 nm and 633 nm excitation laser wavelengths for REE-bearing oxides, hydroxides, anhydrous and hydrous phosphates is also presented providing a new framework for identifying REE-phases in phosphate-bearing natural mineral deposits.

View Accepted Manuscript (DOE)

Research Organization:: New Mexico Institute of Mining and Technology, Socorro, NM (United States); New Mexico Bureau of Geology and Mineral Resources, Socorro, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: SC0022269

OSTI ID:: 2402993

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 23 Vol. 53; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (73)

Raman spectra of the rare earth orthophosphates Begun, G. M.; Beall, G. W.; Boatner, L. A. Journal of Raman Spectroscopy, Vol. 11, Issue 4 https://doi.org/10.1002/jrs.1250110411	journal	August 1981
Application of Raman spectroscopy for the identification of phosphate minerals from REE supergene deposit Zhukova, Irina A.; Stepanov, Aleksandr S.; Korsakov, Andrey V. Journal of Raman Spectroscopy, Vol. 53, Issue 3 https://doi.org/10.1002/jrs.6213	journal	July 2021
Observation stimulated Raman scattering in nanocrystalline Sc₂O₃ ceramics Kaminskii, A. A.; Bagaev, S. N.; Ueda, K. Laser Physics Letters, Vol. 2, Issue 1 https://doi.org/10.1002/lapl.200410137	journal	October 2004
Raman spectra of lanthanide sesquioxide single crystals with A-type structure Zarembowitch, J.; Gouteron, J.; Lejus, A. M. Physica Status Solidi (b), Vol. 94, Issue 1 https://doi.org/10.1002/pssb.2220940128	journal	July 1979
Raman Spectra of La2O3Dispersed on γ-Al2O3 Scheithauer, M.; Knözinger, H.; Vannice, M. A. Journal of Catalysis, Vol. 178, Issue 2 https://doi.org/10.1006/jcat.1998.2187	journal	September 1998
Vibrational Spectroscopy of the C-Form of Yttrium Sesquioxide Repelin, Y.; Proust, C.; Husson, E. Journal of Solid State Chemistry, Vol. 118, Issue 1 https://doi.org/10.1006/jssc.1995.1326	journal	August 1995
The Principal Rare Earth Elements Deposits of the United States: A Summary of Domestic Deposits and a Global Perspective Long, Keith R.; Van Gosen, Bradley S.; Foley, Nora K. Non-Renewable Resource Issues https://doi.org/10.1007/978-90-481-8679-2_7	book	January 2012
Synthesis, characterization and photoluminescent properties of rare-earth hydroxides and oxides nanorods by hydrothermal route Liu, Shuyang; Liu, Yongjun; Mu, Qiuying Applied Physics A, Vol. 111, Issue 4 https://doi.org/10.1007/s00339-012-7387-3	journal	November 2012
Factors affecting the Nd3+ (REE3+) luminescence of minerals Lenz, Christoph; Talla, Dominik; Ruschel, Katja Mineralogy and Petrology, Vol. 107, Issue 3 https://doi.org/10.1007/s00710-013-0286-2	journal	May 2013
Multi-stage evolution of xenotime–(Y) from Písek pegmatites, Czech Republic: an electron probe micro-analysis and Raman spectroscopy study Švecová, E.; Čopjaková, R.; Losos, Z. Mineralogy and Petrology, Vol. 110, Issue 6 https://doi.org/10.1007/s00710-016-0442-6	journal	April 2016
Phase structure and vibrational spectra of rare-earth-oxide ceramics of Dy2(1−x)Tm2x O3 Fu, Xiaojian; Xu, Yuanda; Zhou, Ji Journal of Materials Science, Vol. 47, Issue 4 https://doi.org/10.1007/s10853-011-5948-z	journal	October 2011
Characterization of the preparation of Pd/SiO2 and Pd/La2O3 by laser Raman spectroscopy Chan, S. Journal of Catalysis, Vol. 89, Issue 2 https://doi.org/10.1016/0021-9517(84)90319-1	journal	October 1984
Structural trends in the lanthanide trihydroxides Beall, G. W.; Milligan, W. O.; Wolcott, Herbert A. Journal of Inorganic and Nuclear Chemistry, Vol. 39, Issue 1 https://doi.org/10.1016/0022-1902(77)80434-X	journal	January 1977
Bonding anomalies in the rare earth sesquioxides Urban, Marek W.; Cornilsen, Bahne C. Journal of Physics and Chemistry of Solids, Vol. 48, Issue 5 https://doi.org/10.1016/0022-3697(87)90108-9	journal	January 1987
Raman spectra of lanthanide sesquioxide single crystals: Correlation between A and B-type structures Gouteron, J.; Michel, D.; Lejus, A. M. Journal of Solid State Chemistry, Vol. 38, Issue 3 https://doi.org/10.1016/0022-4596(81)90058-X	journal	July 1981
Vibrational spectra of oxides with the C-type rare earth oxide structure White, William B.; Keramidas, Vassilis G. Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 28, Issue 3 https://doi.org/10.1016/0584-8539(72)80237-X	journal	March 1972
Vibrational spectra of crystals with the A-type rare earth oxide structure—I. La2O3 and Nd2O3 Boldish, Steven I.; White, William B. Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 35, Issue 11 https://doi.org/10.1016/0584-8539(79)80204-4	journal	January 1979
Evidence of lanthanum–chromium mixed oxides formed in CrO /La2O3 model catalysts Hoang, D. L.; Dittmar, A.; Schneider, M. Thermochimica Acta, Vol. 400, Issue 1-2 https://doi.org/10.1016/S0040-6031(02)00491-4	journal	April 2003
Optimization of spectroscopic properties of Yb3+-doped refractory sesquioxides: cubic and monoclinic Gd2O3 Laversenne, L.; Guyot, Y.; Goutaudier, C. Optical Materials, Vol. 16, Issue 4 https://doi.org/10.1016/S0925-3467(00)00095-1	journal	May 2001
A Raman spectroscopic study of rare earth mixed oxides Panitz, Jan-Christoph; Mayor, Jean-Claude; Grob, Beda Journal of Alloys and Compounds, Vol. 303-304 https://doi.org/10.1016/S0925-8388(00)00606-X	journal	May 2000
Pressure effect on optical properties and structure stability of LaPO4:Eu3+ hollow spheres Zhao, Zhi; Zuo, Jian; Ding, Zejun Journal of Rare Earths, Vol. 28 https://doi.org/10.1016/S1002-0721(10)60343-2	journal	December 2010
Raman characterization and photoluminescence properties of La1-Tb PO4·nH2O and La1-Tb PO4 phosphor nanorods prepared by microwave-assisted hydrothermal synthesis Colomer, M. T.; Bartolomé, J.; Ortiz, A. L. Ceramics International, Vol. 43, Issue 14 https://doi.org/10.1016/j.ceramint.2017.05.110	journal	October 2017
Laser-induced REE3+ photoluminescence of selected accessory minerals — An “advantageous artefact” in Raman spectroscopy Lenz, Christoph; Nasdala, Lutz; Talla, Dominik Chemical Geology, Vol. 415 https://doi.org/10.1016/j.chemgeo.2015.09.001	journal	November 2015
Global demand for rare earth resources and strategies for green mining Dutta, Tanushree; Kim, Ki-Hyun; Uchimiya, Minori Environmental Research, Vol. 150 https://doi.org/10.1016/j.envres.2016.05.052	journal	October 2016
Raman characterisation of powder of cubic RE2O3 (RE=Nd, Gd, Dy, Tm, and Lu), Sc2O3 and Y2O3 Ubaldini, Alberto; Carnasciali, Maria Maddalena Journal of Alloys and Compounds, Vol. 454, Issue 1-2 https://doi.org/10.1016/j.jallcom.2006.12.067	journal	April 2008
A simple method to prepare Ln(OH)3 (Ln=La, Sm, Tb, Eu, and Gd) nanorods using CTAB micelle solution and their room temperature photoluminescence properties Mu, Qiuying; Wang, Yude Journal of Alloys and Compounds, Vol. 509, Issue 5 https://doi.org/10.1016/j.jallcom.2010.10.141	journal	February 2011
Non-resonant energy transfer from Eu3+ to Yb3+ in C-type and B-type (Eu1-Yb )2O3 nanocrystals Candela, M. T.; Aguado, F.; Diego-Rucabado, A. Journal of Alloys and Compounds, Vol. 921 https://doi.org/10.1016/j.jallcom.2022.166043	journal	November 2022
Photoluminescence and Raman study of the high-pressure behavior of monoclinic (Eu1-Yb )2O3 solid solution Candela, M. T.; Aguado, F.; González, J. A. Journal of Alloys and Compounds, Vol. 967 https://doi.org/10.1016/j.jallcom.2023.171621	journal	December 2023
Crystal chemistry of the monazite structure Clavier, Nicolas; Podor, Renaud; Dacheux, Nicolas Journal of the European Ceramic Society, Vol. 31, Issue 6, p. 941-976 https://doi.org/10.1016/j.jeurceramsoc.2010.12.019	journal	June 2011
Actinide solubility-controlling phases during the dissolution of phosphate ceramics Du Fou de Kerdaniel, E.; Clavier, N.; Dacheux, N. Journal of Nuclear Materials, Vol. 362, Issue 2-3 https://doi.org/10.1016/j.jnucmat.2007.01.132	journal	May 2007
Probing structural homogeneity of La 1-x Gd x PO 4 monazite-type solid solutions by combined spectroscopic and computational studies Huittinen, N.; Arinicheva, Y.; Kowalski, P. M. Journal of Nuclear Materials, Vol. 486 https://doi.org/10.1016/j.jnucmat.2017.01.024	journal	April 2017
Rare earth phosphate powders RePO4·nH2O (Re=La, Ce or Y) II. Thermal behavior Lucas, S.; Champion, E.; Bernache-Assollant, D. Journal of Solid State Chemistry, Vol. 177, Issue 4-5 https://doi.org/10.1016/j.jssc.2003.11.004	journal	April 2004
Raman, XRD and microscopic investigations on CeO2–Lu2O3 and CeO2–Sc2O3 systems: A sub-solidus phase evolution study Grover, V.; Banerji, Ankita; Sengupta, P. Journal of Solid State Chemistry, Vol. 181, Issue 8 https://doi.org/10.1016/j.jssc.2008.04.001	journal	August 2008
Structural, vibrational, and thermochemical properties of the monazite-type solid solution La1–Pr PO4 Hirsch, A.; Kegler, P.; Alencar, I. Journal of Solid State Chemistry, Vol. 245 https://doi.org/10.1016/j.jssc.2016.09.032	journal	January 2017
Vibrational spectra of monazite-type rare-earth orthophosphates Silva, E. N.; Ayala, A. P.; Guedes, I. Optical Materials, Vol. 29, Issue 2-3 https://doi.org/10.1016/j.optmat.2005.09.001	journal	November 2006
Raman and infrared spectroscopy of monazite-type ceramics used for nuclear waste conditioning Heuser, J.; Bukaemskiy, A. A.; Neumeier, S. Progress in Nuclear Energy, Vol. 72 https://doi.org/10.1016/j.pnucene.2013.09.003	journal	April 2014
Monazite, rhabdophane, xenotime & churchite: Vibrational spectroscopy of gadolinium phosphate polymorphs Clavier, N.; Mesbah, A.; Szenknect, S. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 205 https://doi.org/10.1016/j.saa.2018.07.016	journal	December 2018
The structure of B-type Sm2O3. A powder neutron diffraction study using enriched 154Sm Kennedy, Brendan J.; Avdeev, Max Solid State Sciences, Vol. 13, Issue 9 https://doi.org/10.1016/j.solidstatesciences.2011.06.020	journal	September 2011
Study of monazite under high pressure Huang, Tony; Lee, Jiann-Shing; Kung, Jennifer Solid State Communications, Vol. 150, Issue 37-38, p. 1845-1850 https://doi.org/10.1016/j.ssc.2010.06.042	journal	October 2010
The Raman OH stretching bands of liquid water Sun, Qiang Vibrational Spectroscopy, Vol. 51, Issue 2 https://doi.org/10.1016/j.vibspec.2009.05.002	journal	November 2009
Crystal Chemistry and Thermodynamics of HREE (Er, Yb) Mixing in a Xenotime Solid Solution Strzelecki, Andrew C.; Reece, Margaret; Zhao, Xiaodong ACS Earth and Space Chemistry, Vol. 6, Issue 5 https://doi.org/10.1021/acsearthspacechem.2c00052	journal	May 2022
Role of Surface Oxygen Vacancies and Lanthanide Contraction Phenomenon of Ln(OH) ₃ (Ln = La, Pr, and Nd) in Sulfide-Mediated Photoelectrochemical Water Splitting Sanivarapu, Suresh Reddy; Lawrence, John Berchmans; Sreedhar, Gosipathala ACS Omega, Vol. 3, Issue 6 https://doi.org/10.1021/acsomega.8b00429	journal	June 2018
Monoclinic Form of the Rhabdophane Compounds: REEPO ₄ ·0.667H ₂ O Mesbah, Adel; Clavier, Nicolas; Elkaim, Erik Crystal Growth & Design, Vol. 14, Issue 10 https://doi.org/10.1021/cg500707b	journal	September 2014
High-Pressure Structural Transitions of Sc ₂ O ₃ by X-ray Diffraction, Raman Spectra, and Ab Initio Calculations Liu, Dan; Lei, Weiwei; Li, Yinwei Inorganic Chemistry, Vol. 48, Issue 17 https://doi.org/10.1021/ic900889v	journal	September 2009
Raman Spectroscopy of Minerals Griffith, W. P. Nature, Vol. 224, Issue 5216 https://doi.org/10.1038/224264a0	journal	October 1969
Occurrence of the potent mutagens 2- nitrobenzanthrone and 3-nitrobenzanthrone in fine airborne particles Santos, Aldenor G.; da Rocha, Gisele O.; de Andrade, Jailson B. Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-018-37186-2	journal	January 2019
Facile synthesis of electrostatically anchored Nd(OH)₃ nanorods onto graphene nanosheets as a high capacitance electrode material for supercapacitors Arunachalam, Subasri; Kirubasankar, Balakrishnan; Murugadoss, Vignesh New Journal of Chemistry, Vol. 42, Issue 4 https://doi.org/10.1039/C7NJ04335J	journal	January 2018
Crystal Structures of a Series of Rare Earth Phosphates Mooney, Rose C. L. The Journal of Chemical Physics, Vol. 16, Issue 10 https://doi.org/10.1063/1.1746668	journal	October 1948
Raman spectra of R ₂ O ₃ ( R —rare earth) sesquioxides with C-type bixbyite crystal structure: A comparative study Abrashev, M. V.; Todorov, N. D.; Geshev, J. Journal of Applied Physics, Vol. 116, Issue 10 https://doi.org/10.1063/1.4894775	journal	September 2014
Photoluminescence and Raman spectroscopy studies of Eu³⁺-doped rutile TiO₂nanocrystals at high pressures Zeng, Q. G.; Ding, Z. J.; Lei, B. F. High Pressure Research, Vol. 32, Issue 3 https://doi.org/10.1080/08957959.2012.710235	journal	September 2012
The vibrational spectrum of zircon (zrsio ₄ ) Dawson, P.; Hargreave, M. M.; Wilkinson, G. R. Journal of Physics C: Solid State Physics, Vol. 4, Issue 2 https://doi.org/10.1088/0022-3719/4/2/014	journal	February 1971
The vibrational spectra and structures of rare earth oxides in the A modification Denning, J. H.; Ross, S. D. Journal of Physics C: Solid State Physics, Vol. 5, Issue 11 https://doi.org/10.1088/0022-3719/5/11/008	journal	June 1972
Intensities and asymmetries of electronic Raman scattering inErPO4andTmPO4 Becker, P. C.; Edelstein, N.; Williams, G. M. Physical Review B, Vol. 31, Issue 12 https://doi.org/10.1103/PhysRevB.31.8102	journal	June 1985
Vibrational dynamics of YPO 4 and ScPO 4 single crystals: An integrated study by polarized Raman spectroscopy and first-principles calculations Giarola, M.; Sanson, A.; Rahman, A. Physical Review B, Vol. 83, Issue 22 https://doi.org/10.1103/PhysRevB.83.224302	journal	June 2011
Raman spectroscopy and lattice dynamical calculations of Sc 2 O 3 single crystals Todorov, N. D.; Abrashev, M. V.; Marinova, V. Physical Review B, Vol. 87, Issue 10 https://doi.org/10.1103/PhysRevB.87.104301	journal	March 2013
Fityk : a general-purpose peak fitting program Wojdyr, Marcin Journal of Applied Crystallography, Vol. 43, Issue 5 https://doi.org/10.1107/S0021889810030499	journal	September 2010
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
In situ Raman spectroscopy of pressure‐induced phase transformations in polycrystalline Tb PO ₄ , Dy PO ₄ , and Gd _x Dy _{(1− x )} PO ₄ Musselman, Matthew A.; Wilkinson, Taylor M.; Haberl, Bianca Journal of the American Ceramic Society, Vol. 101, Issue 6 https://doi.org/10.1111/jace.15374	journal	January 2018
Investigation of Nd³⁺ incorporation in Ce‐rhabdophane: Insight from structural flexibility and occupation mechanism Liu, Hang; Zhao, Xiaofeng; Teng, Yuancheng Journal of the American Ceramic Society, Vol. 105, Issue 7 https://doi.org/10.1111/jace.18438	journal	March 2022
Raman and Fluorescence Spectroscopy of CeO ₂ , Er ₂ O ₃ , Nd ₂ O ₃ , Tm ₂ O ₃ , Yb ₂ O ₃ , La ₂ O ₃ , and Tb ₄ O ₇ Cui, Jianlan; Hope, Gregory A. Journal of Spectroscopy, Vol. 2015 https://doi.org/10.1155/2015/940172	journal	January 2015
Phonon and Electronic Raman Spectra of Cubic Rare-Earth Oxides and Isomorphous Yttrium Oxide* Schaack, G.; Koningstein, J. A. Journal of the Optical Society of America, Vol. 60, Issue 8 https://doi.org/10.1364/JOSA.60.001110	journal	August 1970
Raman and Resonance Raman Spectroscopy of Selected Rare-Earth Sesquioxides Tucker, L. A.; Carney, F. J.; McMillan, P. Applied Spectroscopy, Vol. 38, Issue 6 https://doi.org/10.1366/0003702844554657	journal	November 1984
Database of Standard Raman Spectra of Minerals and Related Inorganic Crystals Wang, Alian; Han, Jingyi; Guo, Lihe Applied Spectroscopy, Vol. 48, Issue 8 https://doi.org/10.1366/0003702944029640	journal	August 1994
The crystal structure of cubic C-type samarium sesquioxide, Sm2O3 Kohlmann, Holger Zeitschrift für Naturforschung B, Vol. 74, Issue 5 https://doi.org/10.1515/znb-2019-0042	journal	May 2019
Standard Thermodynamic Properties and Heat Capacity Equations for Rare Earth Element Hydroxides Diakonov, I. I.; Tagirov, B. R.; Ragnarsdottir, K. V. ract, Vol. 81, Issue 2 https://doi.org/10.1524/ract.1998.81.2.107	journal	June 1998
Crystal chemistry of the monazite and xenotime structures Ni, Yunxiang; Hughes, John M.; Mariano, Anthony N. American Mineralogist, Vol. 80, Issue 1-2 https://doi.org/10.2138/am-1995-1-203	journal	February 1995
Synthesis of REE and Y phosphates by Pb-free flux methods and their utilization as standards for electron microprobe analysis and in design of monazite chemical U-Th-Pb dating protocol Cherniak, D. J.; Pyle, J.; Rakovan, John American Mineralogist, Vol. 89, Issue 10 https://doi.org/10.2138/am-2004-1023	journal	October 2004
Raman investigation of H2O molecule and hydroxyl groups in the channels of hemimorphite Kolesov, B. American Mineralogist, Vol. 91, Issue 8-9 https://doi.org/10.2138/am.2006.2179	journal	August 2006
Versatile Monazite: Resolving geological records and solving challenges in materials science: Monazite as a promising long-term radioactive waste matrix: Benefits of high-structural flexibility and chemical durability Dacheux, N.; Clavier, N.; Podor, R. American Mineralogist, Vol. 98, Issue 5-6 https://doi.org/10.2138/am.2013.4307	journal	May 2013
A Spectroscopic Investigation of Eu3+ Incorporation in LnPO4 (Ln = Tb, Gd1-xLux, X = 0.3, 0.5, 0.7, 1) Ceramics Lösch, Henry; Hirsch, Antje; Holthausen, Jacqueline Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00094	journal	February 2019
Evidence for Lattice Strain and Non-ideal Behavior in the (La1−xEux)PO4 Solid Solution from X-ray Diffraction and Vibrational Spectroscopy Geisler, Thorsten; Popa, Karin; Konings, Rudy J. M. Frontiers in Earth Science, Vol. 4 https://doi.org/10.3389/feart.2016.00064	journal	June 2016
Micro-Raman—A Tool for the Heavy Mineral Analysis of Gold Placer-Type Deposits (Pianu Valley, Romania) Maftei, Andreea Elena; Buzatu, Andrei; Damian, Gheorghe Minerals, Vol. 10, Issue 11 https://doi.org/10.3390/min10110988	journal	November 2020
Global Potential of Rare Earth Resources and Rare Earth Demand from Clean Technologies Zhou, Baolu; Li, Zhongxue; Chen, Congcong Minerals, Vol. 7, Issue 11 https://doi.org/10.3390/min7110203	journal	October 2017

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58 GEOSCIENCES
Raman spectroscopy
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oxides
phosphates
rare earth elements
solid solutions

Raman spectroscopic study of anhydrous and hydrous REE phosphates, oxides, and hydroxides

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