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The Conundrum of “Pair Sites” in Langmuir–Hinshelwood Reaction Kinetics in Heterogeneous Catalysis

Journal Article · · ACS Catalysis
 [1];  [2]
  1. Renewable Resources and Enabling Sciences Center, National Renewable Energy Laboratory, 15013 Denver West Parkway, Golden, Colorado 80401, United States
  2. Operando Molecular Spectroscopy and Catalysis Laboratory, Department of Chemical and Biomolecular Engineering, Lehigh University, Bethlehem, Pennsylvania 18015, United States

Not Available

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
2396056
Alternate ID(s):
OSTI ID: 2395924
OSTI ID: 2402999
Journal Information:
ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 13 Vol. 14; ISSN 2155-5435
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (97)

Atom Tunneling in Chemistry journal March 2016
Mechanism by which Tungsten Oxide Promotes the Activity of Supported V 2 O 5 /TiO 2 Catalysts for NO X Abatement: Structural Effects Revealed by 51 V MAS NMR Spectroscopy journal September 2019
New Mechanistic and Reaction Pathway Insights for Oxidative Coupling of Methane (OCM) over Supported Na 2 WO 4 /SiO 2 Catalysts journal August 2021
Isotope Studies in Oxidation of Propane over Vanadium Oxide journal August 2017
A Spectroscopic Study of Supported‐Phosphate‐Catalysts (SPCs): Evidence of Surface‐mediated Hydrogen‐Transfer journal February 2021
Hydrogen Tunneling in Stoichiometric and Catalytic Reactions involving Transition Metals journal November 2023
The Effect of Loading of Vanadia on Silica in the Oxidation of Butane journal November 1993
Reactivity of Supported Vanadium Oxide Catalysts: The Partial Oxidation of Methanol journal April 1994
Fundamental Studies of Butane Oxidation over Model-Supported Vanadium Oxide Catalysts: Molecular Structure-Reactivity Relationships journal August 1997
Isotopic Tracer and Kinetic Studies of Oxidative Dehydrogenation Pathways on Vanadium Oxide Catalysts journal September 1999
Ethane and n-Butane Oxidation over Supported Vanadium Oxide Catalysts: An in Situ UV–Visible Diffuse Reflectance Spectroscopic Investigation journal December 1999
Kinetic Isotopic Effects in Oxidative Dehydrogenation of Propane on Vanadium Oxide Catalysts journal May 2000
The Relationship between the Electronic and Redox Properties of Dispersed Metal Oxides and Their Turnover Rates in Oxidative Dehydrogenation Reactions journal July 2002
Kinetics of Catalytic Reactions book January 2005
Selective reduction of NO by NH3 over vanadia-based commercial catalyst: Parametric sensitivity and kinetic modelling journal June 1996
Study of the interaction of 1-butene with V2O5 and mixed vanadium and phosphorus oxides by means of temperature-programmed desorption journal May 1982
Heterogeneous Catalysis book January 1975
Evolution of V2O5-TiO2 catalysts in the course of the catalytic reaction journal August 1987
n-Butane selective oxidation on vanadium-based oxides : Dependence on catalyst microstructure journal August 1986
The incorporated dispersion of vanadium oxide and its influence on the textural properties of tetragonal ZrO2 journal October 1998
The origin of the support effect in supported metal oxide catalysts: in situ infrared and kinetic studies during methanol oxidation journal March 1999
Oxidation of sulfur dioxide over supported vanadia catalysts: molecular structure – reactivity relationships and reaction kinetics journal June 1999
Preparation of selective catalytic reduction catalysts via milling and thermal spreading journal November 1997
Oxidative dehydrogenation of propane over vanadium and niobium oxides supported catalysts journal August 1999
Mass and heat transfer effects on the oxidative dehydrogenation of propane (ODP) over a low loaded VOx/Al2O3 catalyst journal April 2007
The generality of surface vanadium oxide phases in mixed oxide catalysts journal January 2011
Redox behaviour of vanadium during hydrogen–oxygen exposure of the V2O5-WO3/TiO2 SCR catalyst at 250°C journal September 2011
Migration and oxidation of vanadium atom and dimer supported on anatase TiO2(1 0 1) surface journal November 2021
Kinetic parameter estimation for supported vanadium oxide catalysts for propane ODH reaction: Effect of loading and support journal December 2006
Selective oxidation of propylene to acrolein over supported V2O5/Nb2O5 catalysts: An in situ Raman, IR, TPSR and kinetic study journal December 2006
Micropore diffusivities of NO and NH3 in Cu-ZSM-5 and their effect on NH3-SCR journal July 2019
Progress in catalysis by mixed oxides: From confusion to catalysis science journal November 2023
Surface chemistry of hydroxyapatite for sustainable n-butanol production from bio-ethanol journal September 2021
Optimizing the surface distribution of acid sites for cooperative catalysis in condensation reactions promoted by water journal October 2021
Molecular water provides a channel for communication between Brønsted acid sites in solid catalysts journal October 2021
Interplay between remote single-atom active sites triggers speedy catalytic oxidation journal November 2022
Communication between active sites regulates heterogeneous catalysis journal November 2022
Nanostructural and chemical characterization of supported metal oxide catalysts by aberration corrected analytical electron microscopy journal February 2012
Propylene production via propane oxidative dehydrogenation over VOx/γ-Al2O3 catalyst journal July 2014
Propane oxidative dehydrogenation on VO /ZrO2 catalysts journal May 2004
Oxidative dehydrogenation of propane over V/MCM-41 catalysts: comparison of O2 and N2O as oxidants journal August 2005
CH3OH oxidation over well-defined supported V2O5/Al2O3 catalysts: Influence of vanadium oxide loading and surface vanadium–oxygen functionalities journal April 2008
The kinetics of selective oxidation of propene on bismuth vanadium molybdenum oxide catalysts journal December 2013
Proton shuttling flattens the energy landscape of nitrite catalytic reduction journal September 2022
Unveiling the origin of enhanced catalytic performance of CePO4/Pt for selective hydrogenation of nitroarenes journal February 2024
Water–active site interactions in zeolites and their relevance in catalysis journal June 2021
n-Butane Oxidation to Maleic Anhydride: Reaction Mechanism and Kinetics Over VPO Catalyst journal April 2024
Oxygen Exchange on Vanadium Pentoxide journal February 2022
Monolayer Detection of Supported Fe and Co Oxides on Ceria To Establish Structure–Activity Relationships for Reduction of NO by CO journal April 2017
Adsorbate-Induced Strong Metal–Support Interactions: Implications for Catalyst Design journal January 2023
Inverse Oxide/Metal Catalysts in Fundamental Studies and Practical Applications: A Perspective of Recent Developments journal June 2016
Elucidating the Effects of Mn Promotion on SiO 2 -Supported Na-Promoted Tungsten Oxide Catalysts for Oxidative Coupling of Methane (OCM) journal July 2021
The Mechanism and Pathway of Selective Partial Oxidation of n-Butane to Maleic Anhydride Studied on Titanium Phosphate Catalysts journal November 2023
Enhanced Two-Dimensional Dispersion of Group V Metal Oxides on Silica journal September 2015
Catalyst Activation and Kinetics for Propylene Metathesis by Supported WOx/SiO2 Catalysts journal December 2016
Reaction Pathways and Kinetics for Selective Catalytic Reduction (SCR) of Acidic NO x Emissions from Power Plants with NH 3 journal November 2017
A Perspective on the Selective Catalytic Reduction (SCR) of NO with NH 3 by Supported V 2 O 5 –WO 3 /TiO 2 Catalysts journal May 2018
Design Strategies for the Molecular Level Synthesis of Supported Catalysts journal August 2011
Mechanistic aspects of maleic anhydride synthesis from C4 hydrocarbons over phosphorus vanadium oxide journal January 1988
Catalysis Science of Methanol Oxidation over Iron Vanadate Catalysts: Nature of the Catalytic Active Sites journal December 2010
Critical Literature Review of the Kinetics for the Oxidative Dehydrogenation of Propane over Well-Defined Supported Vanadium Oxide Catalysts journal September 2014
Surface ReO x Sites on Al 2 O 3 and Their Molecular Structure–Reactivity Relationships for Olefin Metathesis journal January 2015
Experimental criterion for the absence of artifacts in the measurement of rates of heterogeneous catalytic reactions journal November 1982
Kinetic Modeling of the Heterogeneously Catalyzed Oxidation of Propene to Acrolein in a Catalytic Wall Reactor journal October 2003
General Principles journal May 1943
Large tunneling effects in the migration of chemisorbed hydrogen on a metal journal July 1985
Size-Dependent Catalytic Activity of Supported Vanadium Oxide Species: Oxidative Dehydrogenation of Propane journal May 2014
Tunneling in C−H Oxidation Reactions by an Oxoiron(IV) Porphyrin Radical Cation: Direct Measurements of Very Large H/D Kinetic Isotope Effects journal May 2008
Selective Catalytic Reduction over Cu/SSZ-13: Linking Homo- and Heterogeneous Catalysis journal March 2017
Redox Dynamics of Active VOx Sites Promoted by TiOx during Oxidative Dehydrogenation of Ethanol Detected by Operando Quick XAS journal March 2022
A Density Functional Theory Study of the Oxidation of Methanol to Formaldehyde over Vanadia Supported on Silica, Titania, and Zirconia journal August 2002
Comparative Study of Bulk and Supported V−Mo−Te−Nb−O Mixed Metal Oxide Catalysts for Oxidative Dehydrogenation of Propane to Propylene journal June 2003
Quantitative Determination of the Speciation of Surface Vanadium Oxides and Their Catalytic Activity journal May 2006
Oxidative Dehydrogenation of Propane by Monomeric Vanadium Oxide Sites on Silica Support journal March 2007
Strong Kinetic Isotope Effect in the Dissociative Chemisorption of H 2 on a PdO(101) Thin Film journal May 2010
Thermal Spreading As an Alternative for the Wet Impregnation Method: Advantages and Downsides in the Preparation of MoO3/SiO2−Al2O3 Metathesis Catalysts journal October 2010
A Tunnel Model for Activated Hydrogen Dissociation on Metal Surfaces journal April 2013
Diffusion Path and Conduction Mechanism of Protons in Hydroxyapatite journal February 2014
An Operando Raman, IR, and TPSR Spectroscopic Investigation of the Selective Oxidation of Propylene to Acrolein over a Model Supported Vanadium Oxide Monolayer Catalyst journal July 2008
Reaction-Induced Spreading of Metal Oxides onto Surfaces of Oxide Supports during Alcohol Oxidation:  Phenomenon, Nature, and Mechanisms journal February 1999
Identification of active Zr–WOx clusters on a ZrO2 support for solid acid catalysts journal November 2009
Visualizing atomic-scale redox dynamics in vanadium oxide-based catalysts journal August 2017
Engineering catalyst supports to stabilize PdOx two-dimensional rafts for water-tolerant methane oxidation journal October 2021
Catalysis book May 1993
The role of hydroxyl channel in defining selected physicochemical peculiarities exhibited by hydroxyapatite journal January 2015
Monolayer supported CuO x /Co 3 O 4 as an active and selective low temperature NO x decomposition catalyst journal January 2019
Synthesis and molecular structure of model silica-supported tungsten oxide catalysts for oxidative coupling of methane (OCM) journal January 2020
Water structures on acidic zeolites and their roles in catalysis journal January 2024
Topology of silica supported vanadium–titanium oxide catalysts for oxidative dehydrogenation of propane journal January 2012
Catalysis science of supported vanadium oxide catalysts journal January 2013
Elementary steps of the catalytic NOx reduction with NH3: Cluster studies on adsorbate diffusion and dehydrogenation at vanadium oxide substrate journal May 2013
Identification of the "Active Sites" of a Surface-Catalyzed Reaction journal September 1996
The Kinetic Significance of V5+ in n-Butane Oxidation Catalyzed by Vanadium Phosphates journal January 1997
Dynamic multinuclear sites formed by mobilized copper ions in NO x selective catalytic reduction journal August 2017
Introduction to the Principles of Heterogeneous Catalysis journal January 1967
The role of surfaces in the reactivity of solids journal January 1984
Kinetics of Heterogeneous Catalytic Reactions book January 1984

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