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Refining Microstructures in Additively Manufactured Al/Cu Gradients Through TiB2 Inclusions

Journal Article · · JOM. Journal of the Minerals, Metals & Materials Society
Here, the additive manufacture of compositionally graded Al/Cu parts by laser engineered net shaping (LENS) is demonstrated. The use of a blue light build laser enabled deposition on a Cu substrate. The thermal gradient and rapid solidification inherent to selective laser melting enabled mass transport of Cu up to 4 mm from a Cu substrate through a pure Al deposition, providing a means of producing gradients with finer step sizes than the printed layer thicknesses. Divorcing gradient continuity from layer or particle size makes LENS a potentially enabling technology for the manufacture of graded density impactors for ramp compression experiments. Printing graded structures with pure Al, however, was prevented by the growth of Al2Cu3 dendrites and acicular grains amid a matrix of Al2Cu. A combination of adding TiB2 grain refining powder and actively varying print layer composition suppressed the dendritic growth mode and produced an equiaxed microstructure in a compositionally graded part. Material phase was characterized for crystal structure and nanoindentation hardness to enable a discussion of phase evolution in the rapidly solidifying melt pool of a LENS print.
Research Organization:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
NA0003525
OSTI ID:
2394706
Report Number(s):
SAND--2024-08350J
Journal Information:
JOM. Journal of the Minerals, Metals & Materials Society, Journal Name: JOM. Journal of the Minerals, Metals & Materials Society Vol. 76; ISSN 1047-4838
Publisher:
SpringerCopyright Statement
Country of Publication:
United States
Language:
English

References (98)

A Review on Functionally Graded Materials and Structures via Additive Manufacturing: From Multi‐Scale Design to Versatile Functional Properties journal April 2020
Fabrication of graded density impactor via underwater shock wave and quasi-isentropic compression testing at two-stage gas gun facility journal August 2014
Intermetallic phase formation in diffusion-bonded Cu/Al laminates journal December 2010
Cellular/Dendritic Transition and Microstructure Evolution during Transient Directional Solidification of Pb-Sb Alloys journal May 2008
Grain refinement of aluminum alloys: Part I. the nucleant and solute paradigms—a review of the literature journal June 1999
A Study on Electrical and Electrochemical Characteristics of Friction Stir Welded Lithium-Ion Battery Tabs for Electric Vehicles journal October 2019
Metal Additive Manufacturing: A Review journal April 2014
Prospects of In-Situ α-Al2O3 as an Inoculant in Aluminum: A Feasibility Study journal August 2017
A model for the growth of Guinier-Preston zones-the vacancy pump journal June 1965
The evaluation of data obtained with diffusion couples of binary single-phase and multiphase systems journal February 1969
Rapid dendrite growth in undercooled alloys journal April 1987
Vacancy concentrations in metals journal February 1978
Steady state columnar and equiaxed growth of dendrites and eutectic journal July 1984
Cooling and heating rate dependence of precipitation in an Al—Cu alloy journal August 1992
Enhanced mechanical properties of laser treated Al-Cu alloys: A microstructural analysis journal July 1995
Growth rate of intermetallic compounds in Al/Cu bimetal produced by cold roll welding process journal April 2001
Formation of α-Widmanstätten structure: effects of grain size and cooling rate on the Widmanstätten morphologies and on the mechanical properties in Ti6Al4V alloy journal November 2001
Microstructural and hardness investigation of an aluminum–copper alloy processed by laser surface melting journal March 2003
Modelling of inoculation of metallic melts: application to grain refinement of aluminium by Al–Ti–B journal June 2000
A model of grain refinement incorporating alloy constitution and potency of heterogeneous nucleant particles journal June 2001
Microstructure and nanoindentation hardness of Al/Al3Sc multilayers journal June 2003
Fabrication of functionally graded TiC/Ti composites by Laser Engineered Net Shaping journal May 2003
In situ observations of dendritic fragmentation due to local solute-enrichment during directional solidification of an aluminum alloy journal August 2007
Revisiting the role of peritectics in grain refinement of Al alloys journal January 2013
Fine-structured aluminium products with controllable texture by selective laser melting of pre-alloyed AlSi10Mg powder journal March 2013
Laser powder-bed fusion additive manufacturing: Physics of complex melt flow and formation mechanisms of pores, spatter, and denudation zones journal April 2016
Promoting the columnar to equiaxed transition and grain refinement of titanium alloys during additive manufacturing journal April 2019
Grain refinement mechanisms in additively manufactured nano-functionalized aluminum journal November 2020
High-throughput additive manufacturing and characterization of refractory high entropy alloys journal June 2020
Design for Additive Manufacturing: Trends, opportunities, considerations, and constraints journal January 2016
Contribution made by double-sized TiC particles addition to the ductility–strength synergy in wire and arc additively manufactured Al–Cu alloys journal January 2024
Effect of La2O3 on corrosion resistance of laser clad ferrite-based alloy coatings journal February 2006
Feedstock powder processing research needs for additive manufacturing development journal February 2018
Plastic homogeneity in nanoscale heterostructured binary and multicomponent metallic eutectics: An overview journal February 2023
Effects of intermetallic compound on the electrical and mechanical properties of friction welded Cu/Al bimetallic joints during annealing journal March 2005
Effect of in situ γ-Al2O3 particles on the microstructure of hypereutectic Al–20%Si alloy journal November 2013
Grain morphology evolution behavior of titanium alloy components during laser melting deposition additive manufacturing journal May 2015
Microstructural characterisation of high-entropy alloy AlCoCrFeNi fabricated by laser engineered net shaping journal November 2015
Which wets TiB2 inoculant particles: Al or Al3Ti? journal April 2016
Microstructure and mechanical properties of Al-Cu alloys fabricated by selective laser melting of powder mixtures journal February 2018
Achieving strength-ductility balance in a laser powder bed fusion fabricated TiB2/Al–Cu-Mg-Ag alloy journal June 2023
Grain morphology control and texture characterization of laser solid formed Ti6Al2Sn2Zr3Mo1.5Cr2Nb titanium alloy journal December 2016
Solidification Microstructure of Laser Additive Manufactured Ti6Al2Zr2Sn3Mo1.5Cr2Nb Titanium Alloy journal April 2016
Microstructure and properties of a laser fabricated burn-resistant Ti alloy journal April 2004
A critical assessment of the effect of indentation spacing on the measurement of hardness and modulus using instrumented indentation testing journal February 2019
Metal additive manufacturing in aerospace: A review journal November 2021
Fabrication and characterization of graded impedance impactors for gas gun experiments from hot-pressed magnesium and polyethylene powders journal April 2008
Effects of process variables and size-scale on solidification microstructure in beam-based fabrication of bulky 3D structures journal July 2009
Selective laser melting of high strength Al–Cu–Mg alloys: Processing, microstructure and mechanical properties journal February 2016
Comparative study of commercially pure titanium produced by laser engineered net shaping, selective laser melting and casting processes journal September 2017
Additive manufacturing of functionally graded materials: A review journal September 2019
Probing effects of solute trapping on the mechanical properties of α-Al in rapidly solidified hypoeutectic Al-10at.%Cu after surface laser melting journal January 2024
Additive manufacturing of metallic lattice structures: Unconstrained design, accurate fabrication, fascinated performances, and challenges journal October 2021
On microstructure and work hardening behavior of laser powder bed fused Al-Cu-Mg-Ag-TiB2 and AlSi10Mg alloys journal June 2023
Direct observations of nucleant TiB2 particles in cast aluminum by synchrotron radiation multiscale tomography journal May 2020
Laser surface alloying on aluminum and its alloys: A review journal January 2018
Fabrication and Characterization of High Strength Al-Cu Alloys Processed Using Laser Beam Melting in Metal Powder Bed journal January 2014
Effects of Hot Isostatic Pressing on Copper Parts Fabricated via Binder Jetting journal January 2017
Formation of ultra-fine copper grains in copper-clad aluminum wire journal September 2010
Compositionally graded joints between magnetically dissimilar alloys achieved through directed energy deposition journal September 2021
Modeling of nanoindentation of bulk and thin film by finite element method journal January 2005
Keyhole fluctuation and pore formation mechanisms during laser powder bed fusion additive manufacturing journal March 2022
Equation-of-state measurements for aluminum, copper, and tantalum in the pressure range 80–440 GPa (0.8–4.4 Mbar) journal January 2003
Production of Vacancies by Laser Bombardment journal September 1971
Diffusion of Copper in Nickel and Aluminum journal December 1965
Application of tape-cast graded impedance impactors for light-gas gun experiments journal July 2007
A self‐consistent technique for estimating the dynamic yield strength of a shock‐loaded material journal July 1978
Experimental results of tantalum material strength at high pressure and high strain rate
  • Park, Hye-Sook; Barton, Nathan; Belof, Jonathan L.
  • SHOCK COMPRESSION OF CONDENSED MATTER - 2011: Proceedings of the Conference of the American Physical Society Topical Group on Shock Compression of Condensed Matter, AIP Conference Proceedings https://doi.org/10.1063/1.3686536
conference January 2012
Atomic diffusion behavior in Cu-Al explosive welding process journal January 2013
Extracting strength from high pressure ramp-release experiments journal December 2013
Flow strength of tantalum under ramp compression to 250 GPa journal January 2014
Application of Al-Cu-W-Ta graded density impactors in dynamic ramp compression experiments journal April 2019
Optical properties of liquid metals at high temperatures journal December 1969
Grain refinement of alloys by inoculation of melts
  • Greer, A. L.
  • Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 361, Issue 1804 https://doi.org/10.1098/rsta.2002.1147
journal January 2003
Optical Constants of the Noble Metals journal December 1972
Estimates of Ta strength at ultrahigh pressures and strain rates using thin-film graded-density impactors journal June 2019
Grain-Size-Independent Plastic Flow at Ultrahigh Pressures and Strain Rates journal February 2015
Free-Form Design of Electrical Machine Rotor Cores for Production Using Additive Manufacturing journal March 2019
Additive Manufacturing Review: Early Past to Current Practice journal September 2020
Epitaxy and Microstructure Evolution in Metal Additive Manufacturing journal July 2016
A review on integration of lightweight gradient lattice structures in additive manufacturing parts journal June 2020
Grain refinement by Al–Ti–B alloys in aluminium melts: a study of the mechanisms of poisoning by zirconium journal October 1999
Overview of modelling and simulation of metal powder bed fusion process at Lawrence Livermore National Laboratory journal November 2014
A review on powder bed fusion technology of metal additive manufacturing book May 2017
Structure and Hardness of the Sputtered Al-Cu Thin Films System journal January 2004
Solid-State Diffusion Welding of Commercial Aluminum Alloy with Pure Copper journal June 2022
An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments journal June 1992
Tape Casting Technique for Fabrication of Graded-Density Impactors for Tailored Dynamic Compression journal January 2006
Compositionally graded metals: A new frontier of additive manufacturing journal August 2014
Using the Laser Engineered Net Shaping (LENS{trademark}) process to produce complex components from a CAD solid model report August 1997
On the Self-Diffusion Coefficients of Aluminum in Copper(Rich)-Aluminum Solid Solutions journal January 1970
Interdiffusion in the Al–Cu System journal January 1971
A Review on Additive Manufacturing of Pure Copper journal June 2021
In Situ Investigation of Microstructural Evolution and Intermetallic Compounds Formation at Liquid Al/Solid Cu Interface by Synchrotron X-ray Radiography journal August 2022
Roll Bonding Properties of Al/Cu Bimetallic Laminates Fabricated by the Roll Bonding Technique journal June 2017
Microstructure and Properties of Aluminum-Copper Composites Prepared by Hot-Pressure Sintering journal June 2014
Technologies and Trends to Improve Power Electronic Packaging journal January 2011
A Review of Additive Manufacturing journal January 2012

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