Chiral-structured heterointerfaces enable durable perovskite solar cells

Duan, Tianwei; You, Shuai; Chen, Min; Yu, Wenjian; Li, Yanyan; Guo, Peijun; Berry, Joseph J.; Luther, Joseph M.; Zhu, Kai; Zhou, Yuanyuan

doi:10.1126/science.ado5172

Chiral-structured heterointerfaces enable durable perovskite solar cells

Journal Article · Thu May 23 00:00:00 EDT 2024 · Science

DOI:https://doi.org/10.1126/science.ado5172· OSTI ID:2394634

^[1]; You, Shuai ^[2]; Chen, Min ^[2]; ^[1]; ^[3]; ^[3]; ^[4]; ^[4]; ^[2]; ^[5]

Hong Kong Baptist Univ. (China)
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Yale Univ., New Haven, CT (United States)
National Renewable Energy Laboratory (NREL), Golden, CO (United States); Univ. of Colorado, Boulder, CO (United States)
Hong Kong University of Science and Technology (HKUST) (Hong Kong)

Mechanical failure and chemical degradation of device heterointerfaces can strongly influence the long-term stability of perovskite solar cells (PSCs) under thermal cycling and damp heat conditions. Here, we report chirality-mediated interfaces based on R-/S-methylbenzyl-ammonium between the perovskite absorber and electron-transport layer to create an elastic yet strong heterointerface with increased mechanical reliability. This interface harnesses enantiomer-controlled entropy to enhance tolerance to thermal cycling–induced fatigue and material degradation, and a heterochiral arrangement of organic cations leads to closer packing of benzene rings, which enhances chemical stability and charge transfer. The encapsulated PSCs showed retentions of 92% of power-conversion efficiency under a thermal cycling test (-40°C to 85°C; 200 cycles over 1200 hours) and 92% under a damp heat test (85% relative humidity; 85°C; 600 hours).

View Accepted Manuscript (DOE)

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office; National Science Foundation (NSF)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 2394634

Report Number(s):: NREL/JA--5900-90016; MainId:91794; UUID:bad6beab-b22b-4422-90fe-41a61d140f18; MainAdminId:72980

Journal Information:: Science, Journal Name: Science Journal Issue: 6698 Vol. 384; ISSN 0036-8075

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

References (46)

Charge‐Carrier Trapping and Radiative Recombination in Metal Halide Perovskite Semiconductors Trimpl, Michael J.; Wright, Adam D.; Schutt, Kelly Advanced Functional Materials, Vol. 30, Issue 42 https://doi.org/10.1002/adfm.202004312	journal	August 2020
Interfacial Residual Stress Relaxation in Perovskite Solar Cells with Improved Stability Wang, Hao; Zhu, Cheng; Liu, Lang Advanced Materials, Vol. 31, Issue 48 https://doi.org/10.1002/adma.201904408	journal	October 2019
Inhibited Crack Development by Compressive Strain in Perovskite Solar Cells with Improved Mechanical Stability Yuan, Guizhou; Xie, Wenqiang; Song, Qizhen Advanced Materials, Vol. 35, Issue 17 https://doi.org/10.1002/adma.202211257	journal	March 2023
Tuning Phase Purity in Chiral 2D Perovskites Scalon, Lucas; Brunner, Julius; Guaita, Maria Gabriella Detone Advanced Optical Materials, Vol. 12, Issue 2 https://doi.org/10.1002/adom.202300776	journal	July 2023
Effect of Cation Composition on the Mechanical Stability of Perovskite Solar Cells Rolston, Nicholas; Printz, Adam D.; Tracy, Jared M. Advanced Energy Materials, Vol. 8, Issue 9 https://doi.org/10.1002/aenm.201702116	journal	December 2017
Structure and Performance Evolution of Perovskite Solar Cells under Extreme Temperatures Li, Guixiang; Su, Zhenhuang; Li, Meng Advanced Energy Materials, Vol. 12, Issue 48 https://doi.org/10.1002/aenm.202202887	journal	October 2022
Engineering with keratin: A functional material and a source of bioinspiration Lazarus, Benjamin S.; Chadha, Charul; Velasco-Hogan, Audrey iScience, Vol. 24, Issue 8 https://doi.org/10.1016/j.isci.2021.102798	journal	August 2021
3D/2D passivation as a secret to success for polycrystalline thin-film solar cells McGott, Deborah L.; Muzzillo, Christopher P.; Perkins, Craig L. Joule, Vol. 5, Issue 5 https://doi.org/10.1016/j.joule.2021.03.015	journal	May 2021
Mechanical design and multifunctional applications of chiral mechanical metamaterials: A review Wu, Wenwang; Hu, Wenxia; Qian, Guian Materials & Design, Vol. 180 https://doi.org/10.1016/j.matdes.2019.107950	journal	October 2019
Influence of phase transition on stability of perovskite solar cells under thermal cycling conditions He, Jiang; Li, Tianhui; Liu, Xueping Solar Energy, Vol. 188 https://doi.org/10.1016/j.solener.2019.06.025	journal	August 2019
From Homochiral Assembly to Heterochiral Assembly: A Leap in Charge Transport Properties of Binaphthol-Based Axially Chiral Materials Chen, Ming; Jiao, Xuechen; Li, Jing Langmuir, Vol. 35, Issue 18 https://doi.org/10.1021/acs.langmuir.9b00463	journal	April 2019
Emergent Properties of an Organic Semiconductor Driven by its Molecular Chirality Yang, Ying; Rice, Beth; Shi, Xingyuan ACS Nano, Vol. 11, Issue 8 https://doi.org/10.1021/acsnano.7b03540	journal	July 2017
Tracking Photoexcited Carriers in Hybrid Perovskite Semiconductors: Trap-Dominated Spatial Heterogeneity and Diffusion deQuilettes, Dane W.; Jariwala, Sarthak; Burke, Sven ACS Nano, Vol. 11, Issue 11 https://doi.org/10.1021/acsnano.7b06242	journal	September 2017
Molecular Structure of Nucleic Acids: A Structure for Deoxyribose Nucleic Acid Watson, J. D.; Crick, F. H. C. Nature, Vol. 171, Issue 4356 https://doi.org/10.1038/171737a0	journal	April 1953
Organic-to-inorganic structural chirality transfer in a 2D hybrid perovskite and impact on Rashba-Dresselhaus spin-orbit coupling Jana, Manoj K.; Song, Ruyi; Liu, Haoliang Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-18485-7	journal	September 2020
Advances and challenges in understanding the microscopic structure–property–performance relationship in perovskite solar cells Zhou, Yuanyuan; Herz, Laura M.; Jen, Alex K-Y. Nature Energy, Vol. 7, Issue 9 https://doi.org/10.1038/s41560-022-01096-5	journal	September 2022
Challenges and opportunities for the mechanical reliability of metal halide perovskites and photovoltaics Dai, Zhenghong; Padture, Nitin P. Nature Energy, Vol. 8, Issue 12 https://doi.org/10.1038/s41560-023-01378-6	journal	November 2023
Chiral-perovskite optoelectronics Long, Guankui; Sabatini, Randy; Saidaminov, Makhsud I. Nature Reviews Materials, Vol. 5, Issue 6 https://doi.org/10.1038/s41578-020-0181-5	journal	March 2020
Materials for chiral light control Crassous, Jeanne; Fuchter, Matthew J.; Freedman, Danna E. Nature Reviews Materials https://doi.org/10.1038/s41578-023-00543-3	journal	March 2023
Developing fibrillated cellulose as a sustainable technological material Li, Tian; Chen, Chaoji; Brozena, Alexandra H. Nature, Vol. 590, Issue 7844 https://doi.org/10.1038/s41586-020-03167-7	journal	February 2021
Surface reaction for efficient and stable inverted perovskite solar cells Jiang, Qi; Tong, Jinhui; Xian, Yeming Nature, Vol. 611, Issue 7935 https://doi.org/10.1038/s41586-022-05268-x	journal	September 2022
Controlled growth of perovskite layers with volatile alkylammonium chlorides Park, Jaewang; Kim, Jongbeom; Yun, Hyun-Sung Nature, Vol. 616, Issue 7958 https://doi.org/10.1038/s41586-023-05825-y	journal	February 2023
All-perovskite tandem solar cells with 3D/3D bilayer perovskite heterojunction Lin, Renxing; Wang, Yurui; Lu, Qianwen Nature, Vol. 620, Issue 7976 https://doi.org/10.1038/s41586-023-06278-z	journal	June 2023
Enhanced optoelectronic coupling for perovskite/silicon tandem solar cells Aydin, Erkan; Ugur, Esma; Yildirim, Bumin K. Nature, Vol. 623, Issue 7988 https://doi.org/10.1038/s41586-023-06667-4	journal	September 2023
Deformation mechanism of innovative 3D chiral metamaterials Wu, Wenwang; Qi, Dexing; Liao, Haitao Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-30737-7	journal	August 2018
Synthesis and crystal structures of inorganic–organic hybrids incorporating an aromatic amine with a chiral functional group Billing, David G.; Lemmerer, Andreas CrystEngComm, Vol. 8, Issue 9 https://doi.org/10.1039/B606987H	journal	January 2006
Encapsulating perovskite solar cells to withstand damp heat and thermal cycling Cheacharoen, Rongrong; Boyd, Caleb C.; Burkhard, George F. Sustainable Energy & Fuels, Vol. 2, Issue 11 https://doi.org/10.1039/C8SE00250A	journal	January 2018
Revealing the role of thiocyanate anion in layered hybrid halide perovskite (CH3NH3)2Pb(SCN)2I2 Tang, Gang; Yang, Chao; Stroppa, Alessandro The Journal of Chemical Physics, Vol. 146, Issue 22 https://doi.org/10.1063/1.4984615	journal	June 2017
Bis(1-phenylethylammonium) tetraiodoplumbate(II) Billing, David G. Acta Crystallographica Section E Structure Reports Online, Vol. 58, Issue 11 https://doi.org/10.1107/S1600536802019025	journal	October 2002
Butterfly gyroid nanostructures as a time-frozen glimpse of intracellular membrane development Wilts, Bodo D.; Apeleo Zubiri, Benjamin; Klatt, Michael A. Science Advances, Vol. 3, Issue 4 https://doi.org/10.1126/sciadv.1603119	journal	April 2017
Mechanically active materials in three-dimensional mesostructures Ning, Xin; Yu, Xinge; Wang, Heling Science Advances, Vol. 4, Issue 9 https://doi.org/10.1126/sciadv.aat8313	journal	September 2018
Structural Origin of Circularly Polarized Iridescence in Jeweled Beetles Sharma, Vivek; Crne, Matija; Park, Jung Ok Science, Vol. 325, Issue 5939 https://doi.org/10.1126/science.1172051	journal	July 2009
Near-atomic cryo-EM structure of the helical measles virus nucleocapsid Gutsche, I.; Desfosses, A.; Effantin, G. Science, Vol. 348, Issue 6235 https://doi.org/10.1126/science.aaa5137	journal	April 2015
Impact of microstructure on local carrier lifetime in perovskite solar cells de Quilettes, D. W.; Vorpahl, S. M.; Stranks, S. D. Science, Vol. 348, Issue 6235 https://doi.org/10.1126/science.aaa5333	journal	April 2015
Promises and challenges of perovskite solar cells Correa-Baena, Juan-Pablo; Saliba, Michael; Buonassisi, Tonio Science, Vol. 358, Issue 6364 https://doi.org/10.1126/science.aam6323	journal	November 2017
Three-dimensional mechanical metamaterials with a twist Frenzel, Tobias; Kadic, Muamer; Wegener, Martin Science, Vol. 358, Issue 6366 https://doi.org/10.1126/science.aao4640	journal	November 2017
A figure of merit for flexibility Peng, Jun; Snyder, G. Jeffrey Science, Vol. 366, Issue 6466 https://doi.org/10.1126/science.aaz5704	journal	November 2019
Chiral-induced spin selectivity enables a room-temperature spin light-emitting diode Kim, Young-Hoon; Zhai, Yaxin; Lu, Haipeng Science, Vol. 371, Issue 6534 https://doi.org/10.1126/science.abf5291	journal	March 2021
Interfacial toughening with self-assembled monolayers enhances perovskite solar cell reliability Dai, Zhenghong; Yadavalli, Srinivas K.; Chen, Min Science, Vol. 372, Issue 6542 https://doi.org/10.1126/science.abf5602	journal	May 2021
Highly efficient p-i-n perovskite solar cells that endure temperature variations Li, Guixiang; Su, Zhenhuang; Canil, Laura Science, Vol. 379, Issue 6630 https://doi.org/10.1126/science.add7331	journal	January 2023
Stabilized hole-selective layer for high-performance inverted p-i-n perovskite solar cells Li, Zhen; Sun, Xianglang; Zheng, Xiaopeng Science, Vol. 382, Issue 6668 https://doi.org/10.1126/science.ade9637	journal	October 2023
Unveiling facet-dependent degradation and facet engineering for stable perovskite solar cells Ma, Chunqing; Eickemeyer, Felix T.; Lee, Sun-Ho Science, Vol. 379, Issue 6628 https://doi.org/10.1126/science.adf3349	journal	January 2023
Interface engineering for high-performance, triple-halide perovskite–silicon tandem solar cells Mariotti, Silvia; Köhnen, Eike; Scheler, Florian Science, Vol. 381, Issue 6653 https://doi.org/10.1126/science.adf5872	journal	July 2023
Minimizing buried interfacial defects for efficient inverted perovskite solar cells Zhang, Shuo; Ye, Fangyuan; Wang, Xiaoyu Science, Vol. 380, Issue 6643 https://doi.org/10.1126/science.adg3755	journal	April 2023
Homogenized NiO _x nanoparticles for improved hole transport in inverted perovskite solar cells Yu, Shiqi; Xiong, Zhuang; Zhou, Haitao Science, Vol. 382, Issue 6677 https://doi.org/10.1126/science.adj8858	journal	December 2023
Bimolecularly passivated interface enables efficient and stable inverted perovskite solar cells Liu, Cheng; Yang, Yi; Chen, Hao Science, Vol. 382, Issue 6672 https://doi.org/10.1126/science.adk1633	journal	November 2023

Similar Records

Stability-limiting heterointerfaces of perovskite photovoltaics

Journal Article · Tue Mar 15 00:00:00 EDT 2022 · Nature (London) · OSTI ID:1864592

On the Durability of Tin‐Containing Perovskite Solar Cells

Journal Article · Tue Nov 14 23:00:00 EST 2023 · Advanced Science · OSTI ID:2212826

Related Subjects

14 SOLAR ENERGY
chiral
perovskite
solar cells
stability

Chiral-structured heterointerfaces enable durable perovskite solar cells

Citation Formats

References (46)

Similar Records

Related Subjects