Confined Ionic Environments Tailoring the Reactivity of Molecules in the Micropores of BEA-Type Zeolite

Kim, Sungmin; Chen, Feng; Camaioni, Donald M.; Derewinski, Miroslaw A.; Gutiérrez, Oliver Y.; Liu, Yue; Lercher, Johannes A.

doi:10.1021/jacs.4c03405

Confined Ionic Environments Tailoring the Reactivity of Molecules in the Micropores of BEA-Type Zeolite

Journal Article · Tue Jun 18 00:00:00 EDT 2024 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.4c03405· OSTI ID:2375560

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Institute for Integrated Catalysis and Physical Science Division, Pacific Northwest National Laboratory, Richland, Washington 99354, United States
Department of Chemistry and Catalysis Research Institute, TU München, Lichtenbergstrasse 4, Garching 85748, Germany
Institute for Integrated Catalysis and Physical Science Division, Pacific Northwest National Laboratory, Richland, Washington 99354, United States, Department of Chemistry and Catalysis Research Institute, TU München, Lichtenbergstrasse 4, Garching 85748, Germany

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI ID:: 2375560

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 26 Vol. 146; ISSN 0002-7863

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (31)

Mechanistic insights into aqueous phase propanol dehydration in H-ZSM-5 zeolite Mei, Donghai; Lercher, Johannes A. AIChE Journal, Vol. 63, Issue 1 https://doi.org/10.1002/aic.15517	journal	October 2016
Directing the Rate‐Enhancement for Hydronium Ion Catalyzed Dehydration via Organization of Alkanols in Nanoscopic Confinements Shetty, Manish; Wang, Huamin; Chen, Feng Angewandte Chemie, Vol. 133, Issue 5 https://doi.org/10.1002/ange.202009835	journal	November 2020
Upgrading Pyrolysis Oil over Ni/HZSM-5 by Cascade Reactions Zhao, Chen; Lercher, Johannes A. Angewandte Chemie International Edition, Vol. 51, Issue 24 https://doi.org/10.1002/anie.201108306	journal	January 2012
Solvent Effects in Acid-Catalyzed Biomass Conversion Reactions Mellmer, Max A.; Sener, Canan; Gallo, Jean Marcel R. Angewandte Chemie International Edition, Vol. 53, Issue 44 https://doi.org/10.1002/anie.201408359	journal	September 2014
Influence of Hydronium Ions in Zeolites on Sorption Eckstein, Sebastian; Hintermeier, Peter H.; Zhao, Ruixue Angewandte Chemie International Edition, Vol. 58, Issue 11 https://doi.org/10.1002/anie.201812184	journal	March 2019
Influence of Intracrystalline Ionic Strength in MFI Zeolites on Aqueous Phase Dehydration of Methylcyclohexanols Milaković, Lara; Hintermeier, Peter H.; Liu, Yue Angewandte Chemie International Edition, Vol. 60, Issue 47 https://doi.org/10.1002/anie.202107947	journal	September 2021
Heats of adsorption for ammonia and pyridine in H-ZSM-5: evidence for identical Brønsted-acid sites Parrillo, D. J.; Lee, C.; Gorte, R. J. Applied Catalysis A: General, Vol. 110, Issue 1 https://doi.org/10.1016/0926-860X(94)80106-1	journal	March 1994
Applications of Zeolites in Sustainable Chemistry Li, Yi; Li, Lin; Yu, Jihong Chem, Vol. 3, Issue 6 https://doi.org/10.1016/j.chempr.2017.10.009	journal	December 2017
Impact of the local environment of Brønsted acid sites in ZSM-5 on the catalytic activity in n-pentane cracking Schallmoser, S.; Ikuno, T.; Wagenhofer, M. F. Journal of Catalysis, Vol. 316 https://doi.org/10.1016/j.jcat.2014.05.004	journal	July 2014
Catalytic diversity conferred by confinement of protons within porous aluminosilicates in Prins condensation reactions Wang, Shuai; Iglesia, Enrique Journal of Catalysis, Vol. 352 https://doi.org/10.1016/j.jcat.2017.06.012	journal	August 2017
Isomerization and β-scission reactions of alkanes on bifunctional metal-acid catalysts: Consequences of confinement and diffusional constraints on reactivity and selectivity Noh, Gina; Shi, Zhichen; Zones, Stacey I. Journal of Catalysis, Vol. 368 https://doi.org/10.1016/j.jcat.2018.03.033	journal	December 2018
Towards understanding and predicting the hydronium ion catalyzed dehydration of cyclic-primary, secondary and tertiary alcohols Milakovic, Lara; Hintermeier, Peter H.; Liu, Qiang Journal of Catalysis, Vol. 390 https://doi.org/10.1016/j.jcat.2020.08.009	journal	October 2020
Impact of the Environment of BEA-Type Zeolites for Sorption of Water and Cyclohexanol Kim, Sungmin; Jaegers, Nicholas R.; Hu, Wenda The Journal of Physical Chemistry C, Vol. 127, Issue 48 https://doi.org/10.1021/acs.jpcc.3c05405	journal	November 2023
Methanol to Olefins (MTO): From Fundamentals to Commercialization Tian, Peng; Wei, Yingxu; Ye, Mao ACS Catalysis, Vol. 5, Issue 3 https://doi.org/10.1021/acscatal.5b00007	journal	February 2015
Toward More Complete Descriptors of Reactivity in Catalysis by Solid Acids Deshlahra, Prashant; Iglesia, Enrique ACS Catalysis, Vol. 6, Issue 8 https://doi.org/10.1021/acscatal.6b01402	journal	July 2016
Control of the Reaction Mechanism of Alkylaromatics Transalkylation by Means of Molecular Confinement Effects Associated to Zeolite Channel Architecture Margarit, Vicente J.; Osman, Mogahid; Al-Khattaf, Sulaiman ACS Catalysis, Vol. 9, Issue 7 https://doi.org/10.1021/acscatal.9b00763	journal	May 2019
Inorganic Solid Acids and Their Use in Acid-Catalyzed Hydrocarbon Reactions Corma, A. Chemical Reviews, Vol. 95, Issue 3 https://doi.org/10.1021/cr00035a006	journal	May 1995
Hydrophobic Zeolites for Biofuel Upgrading Reactions at the Liquid–Liquid Interface in Water/Oil Emulsions Zapata, Paula A.; Faria, Jimmy; Ruiz, M. Pilar Journal of the American Chemical Society, Vol. 134, Issue 20 https://doi.org/10.1021/ja3015082	journal	May 2012
Catalytic Consequences of Spatial Constraints and Acid Site Location for Monomolecular Alkane Activation on Zeolites Gounder, Rajamani; Iglesia, Enrique Journal of the American Chemical Society, Vol. 131, Issue 5 https://doi.org/10.1021/ja808292c	journal	February 2009
Genesis and Stability of Hydronium Ions in Zeolite Channels Wang, Meng; Jaegers, Nicholas R.; Lee, Mal-Soon Journal of the American Chemical Society, Vol. 141, Issue 8 https://doi.org/10.1021/jacs.8b07969	journal	January 2019
Cooperative Effects between Hydrophilic Pores and Solvents: Catalytic Consequences of Hydrogen Bonding on Alkene Epoxidation in Zeolites Bregante, Daniel T.; Johnson, Alayna M.; Patel, Ami Y. Journal of the American Chemical Society, Vol. 141, Issue 18 https://doi.org/10.1021/jacs.8b12861	journal	January 2019
FTIR Adsorption Studies of H ₂ O and CH ₃ OH in the Isostructural H-SSZ-13 and H-SAPO-34: Formation of H-Bonded Adducts and Protonated Clusters Bordiga, Silvia; Regli, Laura; Lamberti, Carlo The Journal of Physical Chemistry B, Vol. 109, Issue 16 https://doi.org/10.1021/jp044324b	journal	April 2005
Implications of Transition State Confinement within Small Voids for Acid Catalysis Jones, Andrew J.; Zones, Stacey I.; Iglesia, Enrique The Journal of Physical Chemistry C, Vol. 118, Issue 31 https://doi.org/10.1021/jp5050095	journal	July 2014
The active site of acidic aluminosilicate catalysts Haag, W. O.; Lago, R. M.; Weisz, P. B. Nature, Vol. 309, Issue 5969 https://doi.org/10.1038/309589a0	journal	June 1984
Enhancing the catalytic activity of hydronium ions through constrained environments Liu, Yuanshuai; Vjunov, Aleksei; Shi, Hui Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14113	journal	March 2017
Tailoring nanoscopic confines to maximize catalytic activity of hydronium ions Shi, Hui; Eckstein, Sebastian; Vjunov, Aleksei Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15442	journal	May 2017
Confinement effects and acid strength in zeolites Grifoni, Emanuele; Piccini, GiovanniMaria; Lercher, Johannes A. Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-22936-0	journal	May 2021
Recent advances of pore system construction in zeolite-catalyzed chemical industry processes Shi, Jing; Wang, Yangdong; Yang, Weimin Chemical Society Reviews, Vol. 44, Issue 24 https://doi.org/10.1039/C5CS00626K	journal	January 2015
Sustainable production of acrolein: investigation of solid acid–base catalysts for gas-phase dehydration of glycerol Chai, Song-Hai; Wang, Hao-Peng; Liang, Yu Green Chemistry, Vol. 9, Issue 10 https://doi.org/10.1039/b702200j	journal	January 2007
Kinetics of furfural production by dehydration of xylose in a biphasic reactor with microwave heating Weingarten, Ronen; Cho, Joungmo; Conner, Jr., Wm. Curtis Green Chemistry, Vol. 12, Issue 8 https://doi.org/10.1039/c003459b	journal	January 2010
Role of the ionic environment in enhancing the activity of reacting molecules in zeolite pores Pfriem, Niklas; Hintermeier, Peter H.; Eckstein, Sebastian Science, Vol. 372, Issue 6545 https://doi.org/10.1126/science.abh3418	journal	May 2021

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