Triggering C-N Coupling on Metal Oxide Nanocomposite for the Electrochemical Reduction of CO2 and NOx⁻ to Formamide

Ramadhany, Putri; Trần‐Phú, Thành; Yuwono, Jodie A.; Ma, Zhipeng; Han, Chen; Nguyen, Thi Kim Anh; Leverett, Josh; Kumar, Priyank; Hocking, Rosalie K.; Tricoli, Antonio; Simonov, Alexandr N.; Amal, Rose; Daiyan, Rahman

doi:10.1002/aenm.202401786

Triggering C-N Coupling on Metal Oxide Nanocomposite for the Electrochemical Reduction of CO₂ and NO_x⁻ to Formamide

Journal Article · Thu May 23 00:00:00 EDT 2024 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.202401786· OSTI ID:2371675

Ramadhany, Putri ^[1]; Trần‐Phú, Thành ^[2]; Yuwono, Jodie A. ^[3]; Ma, Zhipeng ^[1]; Han, Chen ^[1]; Nguyen, Thi Kim Anh ^[4]; Leverett, Josh ^[1]; Kumar, Priyank ^[1]; Hocking, Rosalie K. ^[5]; Tricoli, Antonio ^[4]; Simonov, Alexandr N. ^[6]; Amal, Rose ^[1]; ^[1]

Univ. of New South Wales, Sydney, NSW (Australia)
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Univ. of Adelaide, SA (Australia)
Univ. of Sydney, NSW (Australia)
Swinburne University of Technology, Melbourne, VIC (Australia)
Monash Univ., Melbourne, VIC (Australia)

The co-electroreduction of CO₂ and NO_x^⁻ (NO₃^⁻/NO₂^⁻) to generate formamide (HCONH₂) offers an opportunity for downstream chemical and polymer manufacturing decarbonization; however, significant challenges lie in the C-N coupling and the associated low product selectivity. Herein, p-block metal oxides are incorporated in copper oxides to provide more accessible active sites for reactant adsorption and activation, tuning the reaction selectivity toward the formamide production. Through in situ Raman and synchrotron-based infrared spectroscopy measurements, C-N bond formation is demonstrated in real-time with the CuO_x/BiO_x catalyst, where the C-N bond is detected via a *CHO and *NH₂ intermediates formation, in agreement with the density functional theory calculations. When tested in a flow electrolyzer, a formamide yield rate of 134 ± 11 mmol h^-1 g_cat^-1 is reported, the first report of co-electroreduction of CO₂ and NO_x^⁻ to formamide beyond conventional H-cell measurements. These new insights on the C-N coupling mechanisms and scale-up capability provide directions for further development of electrocatalysts for the formamide production.

View Accepted Manuscript (DOE)

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE; Australian Research Council (ARC)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 2371675

Report Number(s):: NREL/JA--5900-90163; MainId:91941; UUID:ddae5065-25e4-4a96-b36d-4bbee1426d40; MainAdminId:72789

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 32 Vol. 14; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
electrocatalytic C-N coupling
formamide
metal oxides
nanocomposite