Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Design and Validation of a High-Throughput Reductive Catalytic Fractionation Method

Journal Article · · JACS Au
 [1];  [2];  [2];  [2];  [2];  [3];  [4];  [2];  [5];  [5];  [6];  [4];  [1]
  1. Renewable Resources and Enabling Sciences Center, National Renewable Energy Laboratory, Golden, Colorado 80401, United States, Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80303, United States, Center for Bioenergy Innovation, Oak Ridge, Tennessee 37830, United States
  2. Renewable Resources and Enabling Sciences Center, National Renewable Energy Laboratory, Golden, Colorado 80401, United States, Center for Bioenergy Innovation, Oak Ridge, Tennessee 37830, United States
  3. Department of Organic Chemistry, Stockholm University, Stockholm SE-106 91, Sweden
  4. Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States
  5. Center for Bioenergy Innovation, Oak Ridge, Tennessee 37830, United States, Institute of Plant Breeding, Genetics and Genomics, University of Georgia, Athens, Georgia 30602, United States, Department of Crop and Soil Sciences, University of Georgia, Athens, Georgia 30602, United States, Department of Plant Biology, University of Georgia, Athens, Georgia 30602, United States
  6. Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80303, United States
Not Available
Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Bioenergy Technologies Office (BETO); USDOE Office of Science (SC), Biological and Environmental Research (BER)
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
2370585
Alternate ID(s):
OSTI ID: 2376843
OSTI ID: 2394599
Journal Information:
JACS Au, Journal Name: JACS Au; ISSN 2691-3704
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (76)

Catalytic Biorefining of Plant Biomass to Non-Pyrolytic Lignin Bio-Oil and Carbohydrates through Hydrogen Transfer Reactions journal June 2014
Economic impact of yield and composition variation in bioenergy crops: Populus trichocarpa journal October 2020
A thioacidolysis method tailored for higher-throughput quantitative analysis of lignin monomers journal September 2016
Engineering of a high-throughput screening system to identify cellulosic biomass, pretreatments, and enzyme formulations that enhance sugar release journal February 2010
Mild Heterogeneous Palladium-Catalyzed Cleavage of β-O-4′-Ether Linkages of Lignin Model Compounds and Native Lignin in Air journal November 2013
Hydrogen-free catalytic fractionation of woody biomass journal November 2016
Lignin Valorization by Cobalt‐Catalyzed Fractionation of Lignocellulose to Yield Monophenolic Compounds journal December 2018
Mesoscale Reaction–Diffusion Phenomena Governing Lignin‐First Biomass Fractionation journal May 2020
Catalytic Hydrogenolysis of Lignin: The Influence of Minor Units and Saccharides journal September 2021
Lignin‐First Depolymerization of Lignocellulose into Monophenols over Carbon Nanotube‐Supported Ruthenium: Impact of Lignin Sources journal May 2022
High-Throughput Screening Techniques for Biomass Conversion journal October 2009
A High-Throughput Platform for Screening Milligram Quantities of Plant Biomass for Lignocellulose Digestibility journal January 2010
Thermodynamic properties of organic oxygen compounds XXXVII. Vapour pressures of methanol, ethanol, pentan-1-ol, and octan-1-ol from the normal boiling temperature to the critical temperature journal February 1975
Evaluation of high throughput screening methods in picking up differences between cultivars of lignocellulosic biomass for ethanol production journal July 2014
Single-step conversion of wood lignin into phenolic amines journal October 2023
Population-level approaches reveal novel aspects of lignin biosynthesis, content, composition and structure journal April 2019
Integrated techno-economic assessment of a biorefinery process: The high-end valorization of the lignocellulosic fraction in wood streams journal September 2020
Flowthrough Reductive Catalytic Fractionation of Biomass journal November 2017
Scalable Fabrication of Perovskite Solar Cells to Meet Climate Targets journal November 2018
Multi-pass flow-through reductive catalytic fractionation journal August 2022
Lignin-first biorefining of Nordic poplar to produce cellulose fibers could displace cotton production on agricultural lands journal August 2022
Continuous hydrodeoxygenation of lignin to jet-range aromatic hydrocarbons journal October 2022
Toward Machine Learning-Enhanced High-Throughput Experimentation journal February 2021
Machine Learning Applied to Zeolite Synthesis: The Missing Link for Realizing High-Throughput Discovery journal September 2019
Bright Side of Lignin Depolymerization: Toward New Platform Chemicals journal January 2018
The Evolution of High-Throughput Experimentation in Pharmaceutical Development and Perspectives on the Future journal May 2019
Catalytic Hydrogenolysis of Lignins into Phenolic Compounds over Carbon Nanotube Supported Molybdenum Oxide journal October 2017
Practical High-Throughput Experimentation for Chemists journal May 2017
Aldehyde-Assisted Fractionation Enhances Lignin Valorization in Endocarp Waste Biomass journal November 2020
The Future Biorefinery: The Impact of Upscaling the Reductive Catalytic Fractionation of Lignocellulose Biomass on the Quality of the Lignin Oil, Carbohydrate Products, and Pulp journal March 2023
Interdependence of Solvent and Catalyst Selection on Low Pressure Hydrogen-Free Reductive Catalytic Fractionation journal March 2023
Lignin Hydrogenolysis: Phenolic Monomers from Lignin and Associated Phenolates across Plant Clades journal June 2023
Economic and Sustainability Impacts of Yield and Composition Variation in Bioenergy Crops: Switchgrass (Panicum virgatum L.) journal January 2024
Enhancing Aromatic Production from Reductive Lignin Disassembly: in Situ O-Methylation of Phenolic Intermediates journal September 2016
Synergetic Effects of Alcohol/Water Mixing on the Catalytic Reductive Fractionation of Poplar Wood journal October 2016
Kinetic Studies of Lignin Solvolysis and Reduction by Reductive Catalytic Fractionation Decoupled in Flow-Through Reactors journal April 2018
Catalytic Conversion of Lignin in Woody Biomass into Phenolic Monomers in Methanol/Water Mixtures without External Hydrogen journal July 2019
Hydrogenolysis of Organosolv Lignin in Ethanol/Isopropanol Media without Added Transition-Metal Catalyst journal December 2019
Deposition of Lignin Droplets Produced During Dilute Acid Pretreatment of Maize Stems Retards Enzymatic Hydrolysis of Cellulose journal December 2007
Lignocellulose Conversion via Catalytic Transformations Yields Methoxyterephthalic Acid Directly from Sawdust journal April 2023
Self-Hydrogen Supplied Catalytic Fractionation of Raw Biomass into Lignin-Derived Phenolic Monomers and Cellulose-Rich Pulps journal June 2023
Whole plant cell wall characterization using solution-state 2D NMR journal August 2012
Differences in S/G ratio in natural poplar variants do not predict catalytic depolymerization monomer yields journal May 2019
Fully lignocellulose-based PET analogues for the circular economy journal June 2022
Rational highly dispersed ruthenium for reductive catalytic fractionation of lignocellulose journal August 2022
Stabilization strategies in biomass depolymerization using chemical functionalization journal May 2020
Fractionation of lignocellulosic biomass to produce uncondensed aldehyde-stabilized lignin journal February 2019
Complete lignocellulose conversion with integrated catalyst recycling yielding valuable aromatics and fuels journal January 2018
Tuning the lignin oil OH-content with Ru and Pd catalysts during lignin hydrogenolysis on birch wood journal January 2015
Lignin depolymerization over Ni/C catalyst in methanol, a continuation: effect of substrate and catalyst loading journal January 2015
Influence of bio-based solvents on the catalytic reductive fractionation of birch wood journal January 2015
Chemicals from lignin: an interplay of lignocellulose fractionation, depolymerisation, and upgrading journal January 2018
Effect of methanol in controlling defunctionalization of the propyl side chain of phenolics from catalytic upstream biorefining journal January 2017
Integrating lignin valorization and bio-ethanol production: on the role of Ni-Al 2 O 3 catalyst pellets during lignin-first fractionation journal January 2017
Lignin depolymerization to monophenolic compounds in a flow-through system journal January 2017
Catalytic lignocellulose biorefining in n -butanol/water: a one-pot approach toward phenolics, polyols, and cellulose journal January 2018
Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor journal January 2019
Establishing lignin structure-upgradeability relationships using quantitative 1 H– 13 C heteronuclear single quantum coherence nuclear magnetic resonance (HSQC-NMR) spectroscopy journal January 2019
Guidelines for performing lignin-first biorefining journal January 2021
Highly selective reductive catalytic fractionation at atmospheric pressure without hydrogen journal January 2021
Reductive catalytic fractionation of pine wood: elucidating and quantifying the molecular structures in the lignin oil journal January 2020
Techno-economic analysis and life cycle assessment of a biorefinery utilizing reductive catalytic fractionation journal January 2021
Flow-through solvolysis enables production of native-like lignin from biomass journal January 2021
OrganoSoxhlet: circular fractionation to produce pulp for textiles using CO 2 as acid source journal January 2021
Identification and quantification of lignin monomers and oligomers from reductive catalytic fractionation of pine wood with GC × GC – FID/MS journal January 2022
Feedstock-agnostic reductive catalytic fractionation in alcohol and alcohol–water mixtures journal January 2023
Catalyst choice impacts aromatic monomer yields and selectivity in hydrogen-free reductive catalytic fractionation journal January 2022
Flow-through reductive catalytic fractionation of beech wood sawdust journal January 2023
Stepping away from purified solvents in reductive catalytic fractionation: a step forward towards a disruptive wood biorefinery process journal January 2023
681. Thermodynamic properties of organic oxygen compounds. Part IX. The critical properties and vapour pressures, above five atmospheres, of six aliphatic alcohols journal January 1963
Ambient-pressure lignin valorization to high-performance polymers by intensified reductive catalytic deconstruction journal January 2022
A sustainable wood biorefinery for low–carbon footprint chemicals production journal February 2020
A rapid thioacidolysis method for biomass lignin composition and tricin analysis journal January 2021
Comparison of hydrogenolysis with thioacidolysis for lignin structural analysis journal February 2014
High Throughput Screening Technologies in Biomass Characterization journal November 2018
Abundance of Major Cell Wall Components in Natural Variants and Pedigrees of Populus trichocarpa journal February 2022