High mass loading potassium ion stabilized manganese dioxide nanowire forests for rechargeable Zn batteries

Chen, Qiang; Li, Jiantao; Liao, Cong; Liang, Wenlong; Lou, Xuan; Liu, Ziang; Zhang, Jianli; Tang, Yiping; Mai, Liqiang; Zhou, Liang; Amine, Khalil

doi:10.1016/j.nanoen.2024.109607

High mass loading potassium ion stabilized manganese dioxide nanowire forests for rechargeable Zn batteries

Journal Article · Fri Apr 19 00:00:00 UTC 2024 · Nano Energy

DOI:https://doi.org/10.1016/j.nanoen.2024.109607· OSTI ID:2370375

Chen, Qiang ^[1]; Li, Jiantao ^[2]; Liao, Cong ^[3]; Liang, Wenlong ^[4]; Lou, Xuan ^[4]; Liu, Ziang ^[3]; Zhang, Jianli ^[4]; Tang, Yiping ^[4]; Mai, Liqiang ^[3]; Zhou, Liang ^[3]; Amine, Khalil ^[2]

Wuhan Univ. of Technology (China); Zhejiang Univ. of Technology, Hangzhou (China)
Argonne National Laboratory (ANL), Argonne, IL (United States)
Wuhan Univ. of Technology (China)
Zhejiang Univ. of Technology, Hangzhou (China)

Manganese dioxide (MnO₂) represents an ideal cathode material for rechargeable aqueous Zn batteries due to its high theoretical capacity (308 mAh g^-1), suitable potential (1.4 V vs. Zn²⁺/Zn), natural abundance, and negligible toxicity. However, the capacity and rate capability of MnO₂ deteriorate significantly in thick electrodes owing to its low electrical and ionic conductivities. Herein, we report the design of high mass loading potassium ion stabilized α-MnO₂ (K_0.133MnO₂) nanowire forests on carbon cloth through a seed-assisted hydrothermal method for Zn batteries. Further, the vertically aligned K_0.133MnO₂ nanowire forests with uninterrupted charge transport afford a high area capacity of 3.54 mAh cm^-2 and a capacity retention of 79.2% over 1000 cycles in aqueous electrolyte. Moreover, the high area capacity and cyclability can be readily transferred to quasi-solid-state devices.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); Natural Science Foundation of Zhejiang Province; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Wind Energy Technologies Office

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2370375

Alternate ID(s):: OSTI ID: 2369685

Journal Information:: Nano Energy, Journal Name: Nano Energy Vol. 126; ISSN 2211-2855

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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