MoS2 Nanoplatelets on Hybrid Core-Shell (HyCoS) AuPd NPs for Hybrid SERS Platform for Detection of R6G

Lin, Shusen; Mandavkar, Rutuja; Burse, Shalmali; Habib, Md Ahasan; Khalid, Tasmia; Joni, Mehedi Hasan; Chung, Young-Uk; Kunwar, Sundar; Lee, Jihoon

doi:10.3390/nano13040769

MoS₂ Nanoplatelets on Hybrid Core-Shell (HyCoS) AuPd NPs for Hybrid SERS Platform for Detection of R6G

Journal Article · Sat Feb 18 04:00:00 EST 2023 · Nanomaterials

DOI:https://doi.org/10.3390/nano13040769· OSTI ID:2367519

^[1]; Mandavkar, Rutuja ^[1]; Burse, Shalmali ^[1]; ^[1]; Khalid, Tasmia ^[1]; Joni, Mehedi Hasan ^[1]; ^[1]; ^[2]; ^[1]

Kwangwoon Univ., Seoul (Korea, Republic of)
Kwangwoon Univ., Seoul (Korea, Republic of); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

In this work, a novel hybrid SERS platform incorporating hybrid core-shell (HyCoS) AuPd nanoparticles (NPs) and MoS₂ nanoplatelets has been successfully demonstrated for strong surface-enhanced Raman spectroscopy (SERS) enhancement of Rhodamine 6G (R6G). A significantly improved SERS signal of R6G is observed on the hybrid SERS platform by adapting both electromagnetic mechanism (EM) and chemical mechanism (CM) in a single platform. The EM enhancement originates from the unique plasmonic HyCoS AuPd NP template fabricated by the modified droplet epitaxy, which exhibits strong plasmon excitation of hotspots at the nanogaps of metallic NPs and abundant generation of electric fields by localized surface plasmon resonance (LSPR). Superior LSPR results from the coupling of distinctive AuPd core-shell NP and high-density background Au NPs. The CM enhancement is associated with the charge transfer from the MoS₂ nanoplatelets to the R6G. The direct contact via mixing approach with optimal mixing ratio can effectively facilitate the charges transfer to the HOMO and LUMO of R6G, leading to the orders of Raman signal amplification. The enhancement factor (EF) for the proposed hybrid platform reaches ~10¹⁰ for R6G on the hybrid SERS platform.

View Accepted Manuscript (DOE)

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE National Nuclear Security Administration (NNSA); National Research Foundation of Korea (NRF)

Grant/Contract Number:: 89233218CNA000001

OSTI ID:: 2367519

Report Number(s):: LA-UR--24-23962

Journal Information:: Nanomaterials, Journal Name: Nanomaterials Journal Issue: 4 Vol. 13; ISSN 2079-4991

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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MoS2 Nanoplatelets on Hybrid Core-Shell (HyCoS) AuPd NPs for Hybrid SERS Platform for Detection of R6G

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MoS₂ Nanoplatelets on Hybrid Core-Shell (HyCoS) AuPd NPs for Hybrid SERS Platform for Detection of R6G