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Effect of different grain boundary diffusion alloys on magnetic properties of Dy-free sintered NdFeB magnet

Journal Article · · IEEE Transactions on Magnetics

Dy-free sintered magnets were fabricated by blending Neo powder with different grain boundary diffusion alloy powders. Cu, CeAl and CeAlCu have a negative effect on H cj of magnets, while PrAlCu and AlCuGa have a positive effect. The PrAlCu-added magnet achieves the best magnetic properties among all magnets with the additions of different diffusion alloys. With increasing PrAlCu from 0-10 wt.%, H cj of the magnets gradually increases from the original 14.5 kOe to 19.2 kOe. The magnet with 7.5 wt.% PrAlCu obtains a H cj of 18 kOe and (BH) max of 39.1 MGOe. It is found that Pr and Cu in PrAlCu alloy is mainly distributed at grain boundary and triple junctions, leading to a reduced coupling among grains, thus an enhanced H cj. Here, the grain boundary engineering by adding an appropriate alloy is an effective method to improve H cj of Dy-free NdFeB magnets.

Research Organization:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Organization:
USDOE Office of Science (SC); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)
Grant/Contract Number:
AC02-07CH11358
OSTI ID:
2367346
Report Number(s):
IS-J--11,333
Journal Information:
IEEE Transactions on Magnetics, Journal Name: IEEE Transactions on Magnetics Journal Issue: 9 Vol. 60; ISSN 0018-9464
Publisher:
Institute of Electrical and Electronics Engineers. Magnetics GroupCopyright Statement
Country of Publication:
United States
Language:
English

References (15)

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Development of Dy-Free Nd–Fe–B-Based Sintered Magnet Through Grain Boundary Engineering Using Pr–Cu Alloys journal November 2023
Evaluation of the Microstructural Contribution to the Coercivity of Fine-Grained Nd–Fe–B Sintered Magnets journal January 2012

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