Characterizing PM2.5 Emissions and Temporal Evolution of Organic Composition from Incense Burning in a California Residence

Ofodile, Jennifer; Alves, Michael R.; Liang, Yutong; Franklin, Emily B.; Lunderberg, David M.; Ivey, Cesunica E.; Singer, Brett C.; Nazaroff, William W.; Goldstein, Allen H.

doi:10.1021/acs.est.3c08904

Characterizing PM_2.5 Emissions and Temporal Evolution of Organic Composition from Incense Burning in a California Residence

Journal Article · Mon Mar 04 00:00:00 EST 2024 · Environmental Science and Technology

DOI:https://doi.org/10.1021/acs.est.3c08904· OSTI ID:2352678

^[1]; ^[1]; ^[1]; Franklin, Emily B. ^[1]; Lunderberg, David M. ^[1]; Ivey, Cesunica E. ^[1]; Singer, Brett C. ^[2]; ^[1]; ^[1]

Univ. of California, Berkeley, CA (United States)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

The chemical composition of incense-generated organic aerosol in residential indoor air has received limited attention in Western literature. In this study, we conducted incense burning experiments in a single-family California residence during vacancy. Here, we report the chemical composition of organic fine particulate matter (PM_2.5), associated emission factors (EFs), and gas-particle phase partitioning for indoor semivolatile organic compounds (SVOCs). Speciated organic PM_2.5 measurements were made using two-dimensional gas chromatography coupled with high-resolution time-of-flight mass spectrometry (GC×GC-HR-ToF-MS) and semivolatile thermal desorption aerosol gas chromatography (SV-TAG). Organic PM_2.5 EFs ranged from 7 to 31 mg g^–1 for burned incense and were largely comprised of polar and oxygenated species, with high abundance of biomass-burning tracers such as levoglucosan. Differences in PM_2.5 EFs and chemical profiles were observed in relation to the type of incense burned. Nine indoor SVOCs considered to originate from sources other than incense combustion were enhanced during incense events. Time-resolved concentrations of these SVOCs correlated well with PM_2.5 mass (R² > 0.75), suggesting that low-volatility SVOCs such as bis(2-ethylhexyl)phthalate and butyl benzyl phthalate partitioned to incense-generated PM_2.5. Both direct emissions and enhanced partitioning of low-volatility indoor SVOCs to incense-generated PM_2.5 can influence inhalation exposures during and after indoor incense use.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2352678

Journal Information:: Environmental Science and Technology, Journal Name: Environmental Science and Technology Journal Issue: 11 Vol. 58; ISSN 0013-936X

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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incense burning
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Characterizing PM2.5 Emissions and Temporal Evolution of Organic Composition from Incense Burning in a California Residence

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