Gapless surface electronic structure of $1T–$$\mathrm{TiSe_2}$ in the distorted phase

Yilmaz, Turgut; Vescovo, Elio

doi:10.1103/physrevb.108.155105

Gapless surface electronic structure of $1T–$$$$\mathrm{TiSe_2}$$ in the distorted phase

Journal Article · Tue Oct 03 04:00:00 EDT 2023 · Physical Review. B

DOI:https://doi.org/10.1103/physrevb.108.155105· OSTI ID:2352193

^[1]; Vescovo, Elio ^[1]

Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)

Here, low temperature, high resolution angle resolved photoemission experiments performed on bulk $1T–$$$$\mathrm{TiSe_2}$$ samples display conspicuous band folding as the only prominent signature of the periodic lattice distortion. The presence of a bulk electronic gap supporting a charge density wave phase is not confirmed in light of the new data. These observations cast serious doubts on the common belief of an electronic instability as the likely origin for the observed structural transition in $$\mathrm{TiSe_2}$$.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: SC0012704

OSTI ID:: 2352193

Report Number(s):: BNL--225622-2024-JAAM

Journal Information:: Physical Review. B, Journal Name: Physical Review. B Journal Issue: 15 Vol. 108; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

References (34)

Modelling the contrasting semimetallic characters of TiS2 and TiSe2 Wilson, J. A. Physica Status Solidi (b), Vol. 86, Issue 1 https://doi.org/10.1002/pssb.2220860102	journal	March 1978
Suppression of antiferroelectricity in TiSe2 by excess carriers White, R. M.; Lucovsky, G. Il Nuovo Cimento B Series 11, Vol. 38, Issue 2 https://doi.org/10.1007/BF02723497	journal	April 1977
Charge density wave phase suppression in 1T-TiSe2 through Sn intercalation Adam, Mukhtar Lawan; Zhu, Hongen; Liu, Zhanfeng Nano Research, Vol. 15, Issue 3 https://doi.org/10.1007/s12274-021-3859-0	journal	October 2021
Concerning the semimetallic characters of TiS2 and TiSe2 Wilson, John A. Solid State Communications, Vol. 22, Issue 9 https://doi.org/10.1016/0038-1098(77)90133-8	journal	June 1977
Mechanisms for the 200 K transition in TiSe2: A measurement of the specific heat Craven, R. A.; Di Salvo, F. J.; Hsu, F. S. L. Solid State Communications, Vol. 25, Issue 1 https://doi.org/10.1016/0038-1098(78)91165-1	journal	January 1978
Transport properties of iodine-free TiSe2 Taguchi, I.; Asai, M.; Watanabe, Y. Physica B+C, Vol. 105, Issue 1-3 https://doi.org/10.1016/0378-4363(81)90234-5	journal	May 1981
Splitting of the Ti-3d bands of TiSe2 in the charge-density wave phase Ghafari, A.; Petaccia, L.; Janowitz, C. Applied Surface Science, Vol. 396 https://doi.org/10.1016/j.apsusc.2016.12.016	journal	February 2017
Recent development of two-dimensional transition metal dichalcogenides and their applications Choi, Wonbong; Choudhary, Nitin; Han, Gang Hee Materials Today, Vol. 20, Issue 3 https://doi.org/10.1016/j.mattod.2016.10.002	journal	April 2017
Dimensional Effects on the Charge Density Waves in Ultrathin Films of TiSe ₂ Chen, P.; Chan, Y. -H.; Wong, M. -H. Nano Letters, Vol. 16, Issue 10 https://doi.org/10.1021/acs.nanolett.6b02710	journal	September 2016
2D transition metal dichalcogenides Manzeli, Sajedeh; Ovchinnikov, Dmitry; Pasquier, Diego Nature Reviews Materials, Vol. 2, Issue 8 https://doi.org/10.1038/natrevmats.2017.33	journal	June 2017
Ultrafast charge ordering by self-amplified exciton–phonon dynamics in TiSe2 Lian, Chao; Zhang, Sheng-Jie; Hu, Shi-Qi Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-019-13672-7	journal	January 2020
Metal-to-insulator transition in Pt-doped TiSe2 driven by emergent network of narrow transport channels Lee, Kyungmin; Choe, Jesse; Iaia, Davide npj Quantum Materials, Vol. 6, Issue 1 https://doi.org/10.1038/s41535-020-00305-2	journal	January 2021
Hidden Order and Dimensional Crossover of the Charge Density Waves in TiSe2 Chen, P.; Chan, Y. -H.; Fang, X. -Y. Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep37910	journal	November 2016
Structural distortion in TiSe ₂ and related materials-a possible Jahn-Teller effect? Hughes, H. P. Journal of Physics C: Solid State Physics, Vol. 10, Issue 11 https://doi.org/10.1088/0022-3719/10/11/009	journal	June 1977
On the origin of charge-density waves in select layered transition-metal dichalcogenides Rossnagel, K. Journal of Physics: Condensed Matter, Vol. 23, Issue 21 https://doi.org/10.1088/0953-8984/23/21/213001	journal	May 2011
Aspects of symmetry and topology in the charge density wave phase of 1T–TiSe₂ Huang, Shin-Ming; Xu, Su-Yang; Singh, Bahadur New Journal of Physics, Vol. 23, Issue 8 https://doi.org/10.1088/1367-2630/ac1bf4	journal	August 2021
Spectroscopic fingerprints of many-body renormalization in 1 T − TiSe 2 Zhao, J.; Lee, Kyungmin; Li, J. Physical Review B, Vol. 100, Issue 4 https://doi.org/10.1103/PhysRevB.100.045106	journal	July 2019
Phase separation in the vicinity of Fermi surface hot spots Jaouen, T.; Hildebrand, B.; Mottas, M. -L. Physical Review B, Vol. 100, Issue 7 https://doi.org/10.1103/PhysRevB.100.075152	journal	August 2019
Evidence for pseudo–Jahn-Teller distortions in the charge density wave phase of 1 T − TiSe 2 Wegner, A.; Zhao, J.; Li, J. Physical Review B, Vol. 101, Issue 19 https://doi.org/10.1103/PhysRevB.101.195145	journal	May 2020
Multiband Fermi surface in 1T−VSe2 and its implication for the charge density wave phase Yilmaz, Turgut; Vescovo, Elio; Sinkovic, Boris Physical Review B, Vol. 107, Issue 16 https://doi.org/10.1103/PhysRevB.107.165109	journal	April 2023
Electronic properties and superlattice formation in the semimetal TiSe 2 Di Salvo, F. J.; Moncton, D. E.; Waszczak, J. V. Physical Review B, Vol. 14, Issue 10 https://doi.org/10.1103/PhysRevB.14.4321	journal	November 1976
Band structure and lattice instability of Ti Se 2 Zunger, Alex; Freeman, A. J. Physical Review B, Vol. 17, Issue 4 https://doi.org/10.1103/PhysRevB.17.1839	journal	February 1978
Transport properties and the phase transition in Ti 1 − x M x Se 2 ( M = Ta or V ) Di Salvo, F. J.; Waszczak, J. V. Physical Review B, Vol. 17, Issue 10 https://doi.org/10.1103/PhysRevB.17.3801	journal	May 1978
Photoemission of bands above the Fermi level: The excitonic insulator phase transition in 1 T − TiSe 2 Pillo, Th.; Hayoz, J.; Berger, H. Physical Review B, Vol. 61, Issue 23 https://doi.org/10.1103/PhysRevB.61.16213	journal	June 2000
Charge-density-wave phase transition in 1 T − TiSe 2 : Excitonic insulator versus band-type Jahn-Teller mechanism Rossnagel, K.; Kipp, L.; Skibowski, M. Physical Review B, Vol. 65, Issue 23 https://doi.org/10.1103/PhysRevB.65.235101	journal	May 2002
Temperature-dependent photoemission on 1 T -TiSe 2 : Interpretation within the exciton condensate phase model Monney, C.; Schwier, E. F.; Garnier, M. G. Physical Review B, Vol. 81, Issue 15 https://doi.org/10.1103/PhysRevB.81.155104	journal	April 2010
Exciton-phonon-driven charge density wave in TiSe 2 van Wezel, Jasper; Nahai-Williamson, Paul; Saxena, Siddarth S. Physical Review B, Vol. 81, Issue 16 https://doi.org/10.1103/PhysRevB.81.165109	journal	April 2010
Electronic and vibrational properties of TiSe 2 in the charge-density-wave phase from first principles Bianco, Raffaello; Calandra, Matteo; Mauri, Francesco Physical Review B, Vol. 92, Issue 9 https://doi.org/10.1103/PhysRevB.92.094107	journal	September 2015
Tunable Se vacancy defects and the unconventional charge density wave in 1 T − TiSe 2 − δ Huang, S. H.; Shu, G. J.; Pai, Woei Wu Physical Review B, Vol. 95, Issue 4 https://doi.org/10.1103/PhysRevB.95.045310	journal	January 2017
Orbital- and k z -Selective Hybridization of Se 4 p and Ti 3 d States in the Charge Density Wave Phase of TiSe 2 Watson, Matthew D.; Clark, Oliver J.; Mazzola, Federico Physical Review Letters, Vol. 122, Issue 7 https://doi.org/10.1103/PhysRevLett.122.076404	journal	February 2019
Charge Density Wave, Superconductivity, and Anomalous Metallic Behavior in 2D Transition Metal Dichalcogenides Castro Neto, A. H. Physical Review Letters, Vol. 86, Issue 19 https://doi.org/10.1103/PhysRevLett.86.4382	journal	May 2001
Electron-Hole Coupling and the Charge Density Wave Transition in TiSe 2 Kidd, T. E.; Miller, T.; Chou, M. Y. Physical Review Letters, Vol. 88, Issue 22 https://doi.org/10.1103/PhysRevLett.88.226402	journal	May 2002
Semimetal-to-Semimetal Charge Density Wave Transition in 1 T − TiSe 2 Li, G.; Hu, W. Z.; Qian, D. Physical Review Letters, Vol. 99, Issue 2 https://doi.org/10.1103/PhysRevLett.99.027404	journal	July 2007
Evidence for an Excitonic Insulator Phase in 1 T − TiSe 2 Cercellier, H.; Monney, C.; Clerc, F. Physical Review Letters, Vol. 99, Issue 14 https://doi.org/10.1103/PhysRevLett.99.146403	journal	October 2007

Similar Records

Multiband Fermi surface in $1T–$$\mathrm{VSe_2}$ and its implication for the charge density wave phase

Journal Article · Thu Apr 06 00:00:00 EDT 2023 · Physical Review. B · OSTI ID:2352192

Quantum spin Hall state in monolayer 1T^'-WTe₂

Journal Article · Mon Jun 26 00:00:00 EDT 2017 · Nature Physics · OSTI ID:1373205

Related Subjects

36 MATERIALS SCIENCE
angle-resolved photoemission spectroscopy
charge density waves
transition metal dichalcogenides

Gapless surface electronic structure of $1T–$$$$\mathrm{TiSe_2}$$ in the distorted phase

Citation Formats

References (34)

Similar Records

Related Subjects