Characterization of the first Peacock–Weakley polyoxometalate containing a transplutonium element: curium bis-pentatungstate [Cm(W 5 O 18 ) 2 ] 9−

Colliard, Ian; Deblonde, Gauthier J. -P.

doi:10.1039/D4CC01381F

Characterization of the first Peacock–Weakley polyoxometalate containing a transplutonium element: curium bis-pentatungstate [Cm(W ₅ O ₁₈ ) ₂ ] ⁹⁻

Journal Article · Thu Jun 06 00:00:00 EDT 2024 · ChemComm

DOI:https://doi.org/10.1039/D4CC01381F· OSTI ID:2350851

Colliard, Ian ^[1]; ^[2]

Physical and Life Sciences Directorate, Glenn T. Seaborg Institute, Lawrence Livermore National Laboratory, Livermore, California 94550, USA, Material Sciences Division, Lawrence Livermore National Laboratory, Livermore, California 94550, USA
Physical and Life Sciences Directorate, Glenn T. Seaborg Institute, Lawrence Livermore National Laboratory, Livermore, California 94550, USA, Nuclear and Chemical Sciences Division, Lawrence Livermore National Laboratory, Livermore, California 94550, USA

Leveraging microgram-level techniques, we here present the first transplutonium bis-pentatungstate complex: NaCs ₈ Cm(W ₅ O ₁₈ ) ₂ ·14H ₂ O (CmW ₅ ).

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Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 2350851

Alternate ID(s):: OSTI ID: 2407219

Report Number(s):: LLNL--JRNL-861963

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 47 Vol. 60; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Characterization of the first Peacock–Weakley polyoxometalate containing a transplutonium element: curium bis-pentatungstate [Cm(W ₅ O ₁₈ ) ₂ ] ⁹⁻