Thermodynamics and kinetics of interconversion between platinum nanoparticles and cations in zeolites

Jayaraman, Anupama; Wijerathne, Asanka; Mandal, Keka; Gounder, Rajamani; Paolucci, Christopher

doi:10.1016/j.jcat.2024.115507

Thermodynamics and kinetics of interconversion between platinum nanoparticles and cations in zeolites

Journal Article · Sun Apr 21 00:00:00 EDT 2024 · Journal of Catalysis

DOI:https://doi.org/10.1016/j.jcat.2024.115507· OSTI ID:2339570

Jayaraman, Anupama ^[1]; Wijerathne, Asanka ^[2]; Mandal, Keka ^[2]; Gounder, Rajamani ^[3]; Paolucci, Christopher ^[2]

University of Virginia, Charlottesville, VA (United States); Purdue University
University of Virginia, Charlottesville, VA (United States)
Purdue University, West Lafayette, IN (United States)

In metal-containing zeolites, sintering and redispersion processes exercise control over the identity of metal site structures, but the thermodynamic and kinetic factors that influence these molecular-level processes are not completely understood. Furthermore, we assess the ability of first principles informed free energy models (for supported and unsupported nanoparticles) and kinetic models integrating Ostwald ripening with atom trapping to describe the interconversion between Pt cations and nanoparticles encapsulated in chabazite (CHA) zeolites. Density functional theory-derived thermodynamic phase diagrams show that the interconversion between cations, favored in oxidizing environments, and particles, favored in reducing environments, is fully reversible within a wide range of their respective conditions (temperatures and pressures) for CHA and several other zeolite topologies. Kinetic Monte Carlo simulations of Pt redispersion are consistent with experimentally observed redispersion kinetics of encapsulated Pt nanoparticles in CHA zeolites, and model results suggest the zeolite host imparts additional stability for Pt nanoparticles. We envision our thermodynamic and kinetic models for Pt-CHA are also capable of describing nanoparticle and cation interconversions for other zeolite frameworks under similar conditions.

View Accepted Manuscript (DOE)

Research Organization:: Purdue University, West Lafayette, IN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019026

OSTI ID:: 2339570

Alternate ID(s):: OSTI ID: 2346249

Journal Information:: Journal of Catalysis, Journal Name: Journal of Catalysis Vol. 434; ISSN 0021-9517

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (81)

Noble Metal Particles Confined in Zeolites: Synthesis, Characterization, and Applications Chai, Yuchao; Shang, Weixiang; Li, Weijie Advanced Science, Vol. 6, Issue 16 https://doi.org/10.1002/advs.201900299	journal	June 2019
Single‐Site vs. Cluster Catalysis in High Temperature Oxidations Serna, Pedro; Rodríguez‐Fernández, Aida; Yacob, Sara Angewandte Chemie, Vol. 133, Issue 29 https://doi.org/10.1002/ange.202102339	journal	June 2021
Effect of the damping function in dispersion corrected density functional theory Grimme, Stefan; Ehrlich, Stephan; Goerigk, Lars Journal of Computational Chemistry, Vol. 32, Issue 7 https://doi.org/10.1002/jcc.21759	journal	March 2011
Atomic Dispersion of Pt Clusters Encapsulated Within ZSM‐5 Depending on Aluminum Sites and Calcination Temperature Zhang, Shaocheng; Li, Yufeng; Ding, Chuanmin Small Structures, Vol. 4, Issue 2 https://doi.org/10.1002/sstr.202200115	journal	October 2022
Preparation of Highly Dispersed Pt Particles in Zeolite Y with a Narrow Particle Size Distribution: Characterization by Hydrogen Chemisorption, TEM, EXAFS Spectroscopy, and Particle Modeling de Graaf, J.; van Dillen, A. J.; de Jong, K. P. Journal of Catalysis, Vol. 203, Issue 2 https://doi.org/10.1006/jcat.2001.3337	journal	October 2001
Redispersion of Pt nanoparticles encapsulated within ZSM-5 in oxygen and catalytic properties in partial oxidation of methane Wang, Tao; Ding, Chuanmin; Ma, Lichao Journal of Porous Materials, Vol. 29, Issue 5 https://doi.org/10.1007/s10934-022-01250-0	journal	May 2022
Particle growth in model supported metal catalysts—I. Theory Wynblatt, P.; Gjostein, N. A. Acta Metallurgica, Vol. 24, Issue 12 https://doi.org/10.1016/0001-6160(76)90034-1	journal	December 1976
Löwenstein's rule in zeolite A: A computational study Bell, R. G.; Jackson, R. A.; Catlow, C. R. A. Zeolites, Vol. 12, Issue 7 https://doi.org/10.1016/0144-2449(92)90065-W	journal	September 1992
Activation of Pd/SSZ-13 catalyst by hydrothermal aging treatment in passive NO adsorption performance at low temperature for cold start application Ryou, YoungSeok; Lee, Jaeha; Cho, Sung June Applied Catalysis B: Environmental, Vol. 212 https://doi.org/10.1016/j.apcatb.2017.04.077	journal	September 2017
Effect of various activation conditions on the low temperature NO adsorption performance of Pd/SSZ-13 passive NOx adsorber Ryou, YoungSeok; Lee, Jaeha; Lee, Hyokyoung Catalysis Today, Vol. 320 https://doi.org/10.1016/j.cattod.2017.11.030	journal	January 2019
Python Materials Genomics (pymatgen): A robust, open-source python library for materials analysis Ong, Shyue Ping; Richards, William Davidson; Jain, Anubhav Computational Materials Science, Vol. 68 https://doi.org/10.1016/j.commatsci.2012.10.028	journal	February 2013
Deactivation and regeneration studies on Pd-containing medium pore zeolites as passive NOx adsorbers (PNAs) in cold-start applications Bello, Estefanía; Margarit, Vicente J.; Gallego, Eva M. Microporous and Mesoporous Materials, Vol. 302 https://doi.org/10.1016/j.micromeso.2020.110222	journal	August 2020
Efficient creation and convergence of surface slabs Sun, Wenhao; Ceder, Gerbrand Surface Science, Vol. 617 https://doi.org/10.1016/j.susc.2013.05.016	journal	November 2013
Structural Interconversion between Agglomerated Palladium Domains and Mononuclear Pd(II) Cations in Chabazite Zeolites Lardinois, Trevor M.; Bates, Jason S.; Lippie, Harrison H. Chemistry of Materials, Vol. 33, Issue 5 https://doi.org/10.1021/acs.chemmater.0c04465	journal	February 2021
Nanoparticle Size Effects on Phase Stability for Molybdenum and Tungsten Carbides Shrestha, Anukriti; Gao, Xutao; Hicks, Jason C. Chemistry of Materials, Vol. 33, Issue 12 https://doi.org/10.1021/acs.chemmater.1c01120	journal	June 2021
Tandem Reduction–Reoxidation Augments the Catalytic Activity of Sn-Beta Zeolites by Redispersion and Respeciation of SnO₂ Clusters Peeters, Elise; Khalil, Ibrahim; Eloy, Pierre Chemistry of Materials, Vol. 33, Issue 23 https://doi.org/10.1021/acs.chemmater.1c03265	journal	November 2021
Zeolite Adsorption Free Energies from ab Initio Potentials of Mean Force Li, Hui; Paolucci, Christopher; Schneider, William F. Journal of Chemical Theory and Computation, Vol. 14, Issue 2 https://doi.org/10.1021/acs.jctc.7b00716	journal	January 2018
Kinetic and Thermodynamic Factors Influencing Palladium Nanoparticle Redispersion into Mononuclear Pd(II) Cations in Zeolite Supports Lardinois, Trevor M.; Mandal, Keka; Yadav, Vamakshi The Journal of Physical Chemistry C, Vol. 126, Issue 19 https://doi.org/10.1021/acs.jpcc.2c01613	journal	May 2022
Oxidation of Gas-Phase and Supported Pt Nanoclusters: An Ab Initio Investigation Taleblou, Mina; Camellone, Matteo Farnesi; Fabris, Stefano The Journal of Physical Chemistry C, Vol. 126, Issue 26 https://doi.org/10.1021/acs.jpcc.2c02176	journal	June 2022
DFT Analysis of NO Oxidation Intermediates on Undoped and Doped LaCoO ₃ Perovskite Penninger, Michael W.; Kim, Chang Hwan; Thompson, Levi T. The Journal of Physical Chemistry C, Vol. 119, Issue 35 https://doi.org/10.1021/acs.jpcc.5b06351	journal	August 2015
Modeling the Interface of Platinum and α-Quartz(001): Implications for Sintering Plessow, Philipp N.; Sánchez-Carrera, Roel S.; Li, Lin The Journal of Physical Chemistry C, Vol. 120, Issue 19 https://doi.org/10.1021/acs.jpcc.6b01403	journal	May 2016
Pt Nanoparticle Sintering and Redispersion on a Heterogeneous Nanostructured Support Tabib Zadeh Adibi, Pooya; Pingel, Torben; Olsson, Eva The Journal of Physical Chemistry C, Vol. 120, Issue 27 https://doi.org/10.1021/acs.jpcc.6b03874	journal	June 2016
First-Principles Comparison of Proton and Divalent Copper Cation Exchange Energy Landscapes in SSZ-13 Zeolite Li, Sichi; Li, Hui; Gounder, Rajamani The Journal of Physical Chemistry C, Vol. 122, Issue 41 https://doi.org/10.1021/acs.jpcc.8b07213	journal	June 2018
Interaction of H ₂ O with the Platinum Pt (001), (011), and (111) Surfaces: A Density Functional Theory Study with Long-Range Dispersion Corrections Ungerer, Marietjie J.; Santos-Carballal, David; Cadi-Essadek, Abdelaziz The Journal of Physical Chemistry C, Vol. 123, Issue 45 https://doi.org/10.1021/acs.jpcc.9b06136	journal	September 2019
Global Structure Optimization of Pt Clusters Based on the Modified Empirical Potentials, Calibrated using Density Functional Theory Ignatov, Stanislav K.; Razuvaev, Alexey G.; Loginova, Anastasiia S. The Journal of Physical Chemistry C, Vol. 123, Issue 47 https://doi.org/10.1021/acs.jpcc.9b08691	journal	October 2019
Understanding and Controlling the Aggregative Growth of Platinum Nanoparticles in Atomic Layer Deposition: An Avenue to Size Selection Grillo, Fabio; Van Bui, Hao; Moulijn, Jacob A. The Journal of Physical Chemistry Letters, Vol. 8, Issue 5 https://doi.org/10.1021/acs.jpclett.6b02978	journal	February 2017
Origin of the Unusual Stability of Zeolite-Encapsulated Sub-Nanometer Platinum Hou, Dianwei; Grajciar, Lukáš; Nachtigall, Petr ACS Catalysis, Vol. 10, Issue 19 https://doi.org/10.1021/acscatal.0c01344	journal	August 2020
Condition-Dependent Pd Speciation and NO Adsorption in Pd/Zeolites Mandal, Keka; Gu, Yuntao; Westendorff, Karl S. ACS Catalysis, Vol. 10, Issue 21 https://doi.org/10.1021/acscatal.0c03585	journal	September 2020
Predicting a Key Catalyst-Performance Descriptor for Supported Metal Nanoparticles: Metal Chemical Potential Mao, Zhongtian; Campbell, Charles T. ACS Catalysis, Vol. 11, Issue 13 https://doi.org/10.1021/acscatal.1c01870	journal	June 2021
Influence of Adhesion on the Chemical Potential of Supported Nanoparticles as Modeled with Spherical Caps Plessow, Philipp N.; Campbell, Charles T. ACS Catalysis, Vol. 12, Issue 4 https://doi.org/10.1021/acscatal.1c04633	journal	January 2022
Metal Redispersion Strategies for Recycling of Supported Metal Catalysts: A Perspective Morgan, Kevin; Goguet, Alexandre; Hardacre, Christopher ACS Catalysis, Vol. 5, Issue 6 https://doi.org/10.1021/acscatal.5b00535	journal	May 2015
Sintering of Pt Nanoparticles via Volatile PtO ₂ : Simulation and Comparison with Experiments Plessow, Philipp N.; Abild-Pedersen, Frank ACS Catalysis, Vol. 6, Issue 10 https://doi.org/10.1021/acscatal.6b01646	journal	September 2016
Chemical Potential of Metal Atoms in Supported Nanoparticles: Dependence upon Particle Size and Support Campbell, Charles T.; Mao, Zhongtian ACS Catalysis, Vol. 7, Issue 12 https://doi.org/10.1021/acscatal.7b03090	journal	November 2017
Trapping of Metal Atoms and Metal Clusters by Chabazite under Severe Redox Stress Moliner, Manuel; Gabay, Jadeene; Kliewer, Chris ACS Catalysis, Vol. 8, Issue 10 https://doi.org/10.1021/acscatal.8b01717	journal	August 2018
Stabilizing High Metal Loadings of Thermally Stable Platinum Single Atoms on an Industrial Catalyst Support Kunwar, Deepak; Zhou, Shulan; DeLaRiva, Andrew ACS Catalysis, Vol. 9, Issue 5 https://doi.org/10.1021/acscatal.8b04885	journal	February 2019
Low-Temperature Catalytic NO Reduction with CO by Subnanometric Pt Clusters Fernández, Estefanía; Liu, Lichen; Boronat, Mercedes ACS Catalysis, Vol. 9, Issue 12 https://doi.org/10.1021/acscatal.9b03207	journal	October 2019
Trends in Adhesion Energies of Metal Nanoparticles on Oxide Surfaces: Understanding Support Effects in Catalysis and Nanotechnology Hemmingson, Stephanie L.; Campbell, Charles T. ACS Nano, Vol. 11, Issue 2 https://doi.org/10.1021/acsnano.6b07502	journal	January 2017
Interplay between Reaction Mechanism and Hydroxyl Species for Water Formation on Pt(111) Ferreira de Morais, Rodrigo; Franco, Alejandro A.; Sautet, Philippe ACS Catalysis, Vol. 5, Issue 2 https://doi.org/10.1021/cs5012525	journal	January 2015
XANES Determination of the Platinum Oxidation State Distribution in Cancer Cells Treated with Platinum(IV) Anticancer Agents Hall, Matthew D.; Foran, Garry J.; Zhang, Mei Journal of the American Chemical Society, Vol. 125, Issue 25 https://doi.org/10.1021/ja0354770	journal	June 2003
Mercaptosilane-Assisted Synthesis of Metal Clusters within Zeolites and Catalytic Consequences of Encapsulation Choi, Minkee; Wu, Zhijie; Iglesia, Enrique Journal of the American Chemical Society, Vol. 132, Issue 26 https://doi.org/10.1021/ja102778e	journal	July 2010
The Entropies of Adsorbed Molecules Campbell, Charles T.; Sellers, Jason R. V. Journal of the American Chemical Society, Vol. 134, Issue 43 https://doi.org/10.1021/ja3080117	journal	October 2012
Atomistic Theory of Ostwald Ripening and Disintegration of Supported Metal Particles under Reaction Conditions Ouyang, Runhai; Liu, Jin-Xun; Li, Wei-Xue Journal of the American Chemical Society, Vol. 135, Issue 5 https://doi.org/10.1021/ja3087054	journal	January 2013
Zeolite-Encaged Isolated Platinum Ions Enable Heterolytic Dihydrogen Activation and Selective Hydrogenations Deng, Xin; Qin, Bin; Liu, Runze Journal of the American Chemical Society, Vol. 143, Issue 49 https://doi.org/10.1021/jacs.1c09535	journal	December 2021
Interconversion of Atomically Dispersed Platinum Cations and Platinum Clusters in Zeolite ZSM-5 and Formation of Platinum gem-Dicarbonyls Felvey, Noah; Guo, Jiawei; Rana, Rachita Journal of the American Chemical Society, Vol. 144, Issue 30 https://doi.org/10.1021/jacs.2c05386	journal	July 2022
Energy Analysis of Aluminosilicate Zeolites with Comprehensive Ranges of Framework Topologies, Chemical Compositions, and Aluminum Distributions Muraoka, Koki; Chaikittisilp, Watcharop; Okubo, Tatsuya Journal of the American Chemical Society, Vol. 138, Issue 19 https://doi.org/10.1021/jacs.6b01341	journal	May 2016
Catalysis in a Cage: Condition-Dependent Speciation and Dynamics of Exchanged Cu Cations in SSZ-13 Zeolites Paolucci, Christopher; Parekh, Atish A.; Khurana, Ishant Journal of the American Chemical Society, Vol. 138, Issue 18 https://doi.org/10.1021/jacs.6b02651	journal	April 2016
Reversible Transformation of Pt Nanoparticles into Single Atoms inside High-Silica Chabazite Zeolite Moliner, Manuel; Gabay, Jadeene E.; Kliewer, Chris E. Journal of the American Chemical Society, Vol. 138, Issue 48 https://doi.org/10.1021/jacs.6b10169	journal	November 2016
Selective Catalytic Reduction over Cu/SSZ-13: Linking Homo- and Heterogeneous Catalysis Gao, Feng; Mei, Donghai; Wang, Yilin Journal of the American Chemical Society, Vol. 139, Issue 13 https://doi.org/10.1021/jacs.7b01128	journal	March 2017
A General Strategy for Fabricating Isolated Single Metal Atomic Site Catalysts in Y Zeolite Liu, Yiwei; Li, Zhi; Yu, Qiuying Journal of the American Chemical Society, Vol. 141, Issue 23 https://doi.org/10.1021/jacs.9b02936	journal	May 2019
Competition between Mononuclear and Binuclear Copper Sites across Different Zeolite Topologies Wijerathne, Asanka; Sawyer, Allison; Daya, Rohil JACS Au, Vol. 4, Issue 1 https://doi.org/10.1021/jacsau.3c00632	journal	January 2024
Effect of Particle Size on the Oxidizability of Platinum Clusters Xu, Ye; Shelton, William A.; Schneider, William F. The Journal of Physical Chemistry A, Vol. 110, Issue 17 https://doi.org/10.1021/jp0547111	journal	May 2006
Formation and Thermal Stability of Platinum Oxides on Size-Selected Platinum Nanoparticles: Support Effects Ono, L. K.; Yuan, B.; Heinrich, H. The Journal of Physical Chemistry C, Vol. 114, Issue 50 https://doi.org/10.1021/jp1086703	journal	November 2010
The Energy of Adsorbed Hydroxyl on Pt(111) by Microcalorimetry Lew, Wanda; Crowe, Matthew C.; Karp, Eric The Journal of Physical Chemistry C, Vol. 115, Issue 23 https://doi.org/10.1021/jp201632t	journal	May 2011
CO- and NO-Induced Disintegration and Redispersion of Three-Way Catalysts Rhodium, Palladium, and Platinum: An ab Initio Thermodynamics Study Goldsmith, Bryan R.; Sanderson, Evan D.; Ouyang, Runhai The Journal of Physical Chemistry C, Vol. 118, Issue 18 https://doi.org/10.1021/jp502201f	journal	April 2014
Rigid-Unit Modes and the Quantitative Determination of the Flexibility Possessed by Zeolite Frameworks Hammonds, Kenton D.; Heine, Volker; Dove, Martin T. The Journal of Physical Chemistry B, Vol. 102, Issue 10 https://doi.org/10.1021/jp980006z	journal	March 1998
Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts Shan, Junjun; Li, Mengwei; Allard, Lawrence F. Nature, Vol. 551, Issue 7682 https://doi.org/10.1038/nature24640	journal	November 2017
Non-equilibrium crystallization pathways of manganese oxides in aqueous solution Sun, Wenhao; Kitchaev, Daniil A.; Kramer, Denis Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08494-6	journal	February 2019
Direct assessment of confinement effect in zeolite-encapsulated subnanometric metal species Liu, Lichen; Lopez-Haro, Miguel; Perez-Omil, Jose Antonio Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-28356-y	journal	February 2022
Regioselective generation and reactivity control of subnanometric platinum clusters in zeolites for high-temperature catalysis Liu, Lichen; Lopez-Haro, Miguel; Lopes, Christian W. Nature Materials, Vol. 18, Issue 8 https://doi.org/10.1038/s41563-019-0412-6	journal	July 2019
A highly CO-tolerant atomically dispersed Pt catalyst for chemoselective hydrogenation Lin, Lili; Yao, Siyu; Gao, Rui Nature Nanotechnology, Vol. 14, Issue 4 https://doi.org/10.1038/s41565-019-0366-5	journal	February 2019
Confining isolated atoms and clusters in crystalline porous materials for catalysis Liu, Lichen; Corma, Avelino Nature Reviews Materials, Vol. 6, Issue 3 https://doi.org/10.1038/s41578-020-00250-3	journal	October 2020
Catalyst deactivation via decomposition into single atoms and the role of metal loading Goodman, Emmett D.; Johnston-Peck, Aaron C.; Dietze, Elisabeth M. Nature Catalysis, Vol. 2, Issue 9 https://doi.org/10.1038/s41929-019-0328-1	journal	August 2019
Surface energies of elemental crystals Tran, Richard; Xu, Zihan; Radhakrishnan, Balachandran Scientific Data, Vol. 3, Issue 1 https://doi.org/10.1038/sdata.2016.80	journal	September 2016
Size controllable redispersion of sintered Au nanoparticles by using iodohydrocarbon and its implications Duan, Xinping; Tian, Xuelin; Ke, Jinhuo Chemical Science, Vol. 7, Issue 5 https://doi.org/10.1039/C5SC04283F	journal	January 2016
Alumina-supported sub-nanometer Pt ₁₀ clusters: amorphization and role of the support material in a highly active CO oxidation catalyst Yin, Chunrong; Negreiros, Fabio R.; Barcaro, Giovanni Journal of Materials Chemistry A, Vol. 5, Issue 10 https://doi.org/10.1039/C6TA10989F	journal	January 2017
Effects of surface hydroxylation on adhesion at zinc/silica interfaces Le, Ha-Linh Thi; Goniakowski, Jacek; Noguera, Claudine Physical Chemistry Chemical Physics, Vol. 20, Issue 22 https://doi.org/10.1039/C8CP02139B	journal	January 2018
Hybrid functionals based on a screened Coulomb potential Heyd, Jochen; Scuseria, Gustavo E.; Ernzerhof, Matthias The Journal of Chemical Physics, Vol. 118, Issue 18 https://doi.org/10.1063/1.1564060	journal	May 2003
Efficient hybrid density functional calculations in solids: Assessment of the Heyd–Scuseria–Ernzerhof screened Coulomb hybrid functional Heyd, Jochen; Scuseria, Gustavo E. The Journal of Chemical Physics, Vol. 121, Issue 3, p. 1187-1192 https://doi.org/10.1063/1.1760074	journal	July 2004
Influence of the exchange screening parameter on the performance of screened hybrid functionals Krukau, Aliaksandr V.; Vydrov, Oleg A.; Izmaylov, Artur F. The Journal of Chemical Physics, Vol. 125, Issue 22 https://doi.org/10.1063/1.2404663	journal	December 2006
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu Grimme, Stefan; Antony, Jens; Ehrlich, Stephan The Journal of Chemical Physics, Vol. 132, Issue 15 https://doi.org/10.1063/1.3382344	journal	April 2010
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy APL Materials, Vol. 1, Issue 1 https://doi.org/10.1063/1.4812323	journal	July 2013
Accurate and simple analytic representation of the electron-gas correlation energy Perdew, John P.; Wang, Yue Physical Review B, Vol. 45, Issue 23, p. 13244-13249 https://doi.org/10.1103/PhysRevB.45.13244	journal	June 1992
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Bulk structures of PtO and PtO2from density functional calculations Nomiyama, Ricardo K.; Piotrowski, Maurício J.; Da Silva, Juarez L. F. Physical Review B, Vol. 84, Issue 10 https://doi.org/10.1103/PhysRevB.84.100101	journal	September 2011
Thermally stable single-atom platinum-on-ceria catalysts via atom trapping Jones, J.; Xiong, H.; DeLaRiva, A. T. Science, Vol. 353, Issue 6295 https://doi.org/10.1126/science.aaf8800	journal	July 2016
Dynamic multinuclear sites formed by mobilized copper ions in NO _x selective catalytic reduction Paolucci, Christopher; Khurana, Ishant; Parekh, Atish A. Science, Vol. 357, Issue 6354 https://doi.org/10.1126/science.aan5630	journal	August 2017
Activation of surface lattice oxygen in single-atom Pt/CeO ₂ for low-temperature CO oxidation Nie, Lei; Mei, Donghai; Xiong, Haifeng Science, Vol. 358, Issue 6369 https://doi.org/10.1126/science.aao2109	journal	December 2017
XXV. Zur Frage der Geschwindigkeit des Wachsthums und der Auflösung der Krystallflächen Wulff, G. Zeitschrift für Kristallographie - Crystalline Materials, Vol. 34, Issue 1-6 https://doi.org/10.1524/zkri.1901.34.1.449	journal	January 1901
Influence of Cation Exchange on the²⁷Al-NMR Spectra of Zeolites Masierak, W.; Emmler, T.; Buntkowsky, Gerd Zeitschrift für Physikalische Chemie, Vol. 217, Issue 12 https://doi.org/10.1524/zpch.217.12.1613.20478	journal	December 2003

Similar Records

Structural Interconversion between Agglomerated Palladium Domains and Mononuclear Pd(II) Cations in Chabazite Zeolites

Journal Article · Sun Feb 14 19:00:00 EST 2021 · Chemistry of Materials · OSTI ID:1777740

Zeolite-Encapsulated Pt Nanoparticles for Tandem Catalysis

Journal Article · Thu Sep 20 20:00:00 EDT 2018 · Journal of the American Chemical Society · OSTI ID:1495319

Related Subjects

36 MATERIALS SCIENCE
Encapsulation
Ion-exchange
Kinetic Monte Carlo
Ostwald Ripening
Platinum
Zeolite

Thermodynamics and kinetics of interconversion between platinum nanoparticles and cations in zeolites

Citation Formats

References (81)

Similar Records

Related Subjects