Sublimation and oxidation measurements of graphite and carbon black at high temperatures in a shock tube using absorption imaging and thermal emission

Willhardt, Colton; Chen, Damon; Daniel, Kyle; Guildenbecher, Daniel; Glumac, Nick

doi:10.1016/j.combustflame.2024.113468

Sublimation and oxidation measurements of graphite and carbon black at high temperatures in a shock tube using absorption imaging and thermal emission

Journal Article · Tue Apr 30 00:00:00 EDT 2024 · Combustion and Flame

DOI:https://doi.org/10.1016/j.combustflame.2024.113468· OSTI ID:2345281

^[1]; Chen, Damon ^[1]; Daniel, Kyle ^[2]; Guildenbecher, Daniel ^[2]; Glumac, Nick ^[1]

Univ. of Illinois at Urbana-Champaign, IL (United States)
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Surface mass loss rates due to sublimation and oxidation at temperatures of 3000–7000 K have been measured in a shock tube for graphite and carbon black (CB) particles. Diagnostics are presented for measuring surface mass loss rates by diffuse backlit illumination extinction imaging and thermal emission. Here, the surface mass loss rate is found by regression fitting extinction and emission signals with an independent spherical primary particle assumption. Measured graphite sublimation and oxidation rates are reported to be an order of magnitude greater than CB sublimation and oxidation rates. It is speculated that the difference between CB and graphite surface mass loss rates is largely due to the primary particle assumption of the presented technique which misrepresents the effective surface area of an aggregate particle where primary particles overlap and shield inner particles. Measured sublimation rates are compared to sublimation models in the literature, and it is seen graphite shows fair agreement with the models while CB underestimates, likely a result of the particle shielding affect not being considered in the sublimation model.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0003525

OSTI ID:: 2345281

Report Number(s):: SAND--2024-05474J

Journal Information:: Combustion and Flame, Journal Name: Combustion and Flame Vol. 265; ISSN 0010-2180

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
Carbon
High temperature
Oxidation
Shock tube
Soot
Sublimation

Sublimation and oxidation measurements of graphite and carbon black at high temperatures in a shock tube using absorption imaging and thermal emission

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