Piezochromic Behavior of 2,4,6-Triphenylpyrylium Tetrachloroferrate

Canasa, Princess; King, David; Cifligu, Petrika; Lua Sanchez, Adrian F.; Chen, Si L.; Han, Haesook; Malik, Trimaan; Billinghurst, Brant; Zhao, Jianbao; Park, Changyong; Rossman, George R.; Pravica, Michael; Bhowmik, Pradip K.; Evlyukhin, Egor

doi:10.1002/smsc.202400106

Piezochromic Behavior of 2,4,6-Triphenylpyrylium Tetrachloroferrate

Journal Article · Fri Apr 26 00:00:00 EDT 2024 · Small Science

DOI:https://doi.org/10.1002/smsc.202400106· OSTI ID:2341405

Canasa, Princess ^[1]; King, David ^[2]; Cifligu, Petrika ^[2]; Lua Sanchez, Adrian F. ^[2]; Chen, Si L. ^[2]; Han, Haesook ^[2]; Malik, Trimaan ^[2]; Billinghurst, Brant ^[3]; ^[3]; ^[4]; ^[5]; ^[2]; ^[2]; ^[2]

Univ. of Nevada, Las Vegas, NV (United States); University of Nevada, Las Vegas
Univ. of Nevada, Las Vegas, NV (United States)
Univ. of Saskatchewan, Saskatoon, SK (Canada)
Argonne National Laboratory (ANL), Argonne, IL (United States). High Pressure Collaborative Access Team (HPCAT)
California Institute of Technology (CalTech), Pasadena, CA (United States)

In advanced photonics, there is a growing interest in piezochromic luminescent materials that exhibit multicolor switching, driven by their potential applications in optical recording, memory, and sensors. Here, the piezochromic behavior of 2,4,6-triphenylpyrylium tetrachloroferrate (Py-FeCl₄) under high pressures from 0 to 9 GPa is reported. The observed multicolor changing properties of Py-FeCl₄ (yellow–orange–red–maroon–black) are found to be fully reversible upon decompression to ambient conditions. The mechanism of Py-FeCl₄ piezochromism is investigated via Raman, infrared, and UV–vis spectroscopy combined with powder X-ray Diffraction. The absence of structural phase transitions as well as the abrupt shifts of bandgap values together with characteristic Raman and IR peaks within 0-9 GPa suggests that the Py-FeCl₄ multicoloring switching behavior is driven by an electron transfer between the inorganic FeCl₄^– anion and the organic pyrylium cation. The obtained results demonstrate that Py-FeCl₄ dye is a good candidate for developing high-pressure sensing technologies designed to function in extreme environments. Moreover, due to the inherent role of molecular-structure relationships in the pyrylium salt's photophysical properties, findings suggest the potential discovery of piezochromic behavior in other pyrylium compounds.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Nevada, Las Vegas, NV (United States); University of Nevada, Las Vegas, NE (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: AC02-06CH11357; SC0023248

OSTI ID:: 2341405

Alternate ID(s):: OSTI ID: 2382818

Journal Information:: Small Science, Journal Name: Small Science Journal Issue: 8 Vol. 4; ISSN 2688-4046

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (61)

A Supramolecule‐Triggered Mechanochromic Switch of Cyclodextrin‐Jacketed Rhodamine and Spiropyran Derivatives Wan, Shulin; Ma, Zhiyong; Chen, Chen Advanced Functional Materials, Vol. 26, Issue 3 https://doi.org/10.1002/adfm.201504048	journal	December 2015
Composition-Tuned Wide Bandgap Perovskites: From Grain Engineering to Stability and Performance Improvement Zhou, Yang; Jia, Yong-Heng; Fang, Hong-Hua Advanced Functional Materials, Vol. 28, Issue 35 https://doi.org/10.1002/adfm.201803130	journal	July 2018
Advanced Organic Optoelectronic Materials: Harnessing Excited-State Intramolecular Proton Transfer (ESIPT) Process Kwon, Ji Eon; Park, Soo Young Advanced Materials, Vol. 23, Issue 32 https://doi.org/10.1002/adma.201102046	journal	July 2011
Thermally Induced 2D Alloy-Heterostructure Transformation in Quaternary Alloys Susarla, Sandhya; Hachtel, Jordan A.; Yang, Xiting Advanced Materials, Vol. 30, Issue 45 https://doi.org/10.1002/adma.201804218	journal	September 2018
Time‐Resolved Bright Red to Cyan Color Tunable Mechanoluminescence from CaZnOS: Bi³⁺, Mn²⁺ for Anti‐Counterfeiting Device and Stress Sensor Yang, Yun‐Ling; Yang, Xue‐Chun; Yuan, Jia‐Yong Advanced Optical Materials, Vol. 9, Issue 16 https://doi.org/10.1002/adom.202100668	journal	May 2021
Staggered to Eclipsed Conformational Rearrangement of [Co₂(CO)₆(PPh₃)₂] in the Solid State: An X‐ray Diffraction Study at High Pressure and Low Temperature Casati, Nicola; Macchi, Piero; Sironi, Angelo Angewandte Chemie International Edition, Vol. 44, Issue 47 https://doi.org/10.1002/anie.200502241	journal	November 2005
The Chemical Imagination at Work inVery Tight Places Grochala, Wojciech; Hoffmann, Roald; Feng, Ji Angewandte Chemie International Edition, Vol. 46, Issue 20 https://doi.org/10.1002/anie.200602485	journal	May 2007
Piezochromism and Conductivity Modulations under High Pressure by Manipulating the Viologen Radical Concentration Sui, Qi; Wang, He‐Chong; Zhang, Yan‐Yan Chemistry – A European Journal, Vol. 29, Issue 48 https://doi.org/10.1002/chem.202301575	journal	July 2023
Near‐infrared Piezochromic Materials at High Pressure Li, Chengjian; Lv, Chunyan; Ouyang, Mi ChemPhysChem, Vol. 24, Issue 13 https://doi.org/10.1002/cphc.202200922	journal	May 2023
Ratiometric Piezochromism of Electrospun Polymer Films: Intermolecular Interactions for Enhanced Sensitivity and Color Difference Yang, Heyi; Sun, Zhanghua; Lv, Chunyan ChemPlusChem, Vol. 83, Issue 3 https://doi.org/10.1002/cplu.201800080	journal	March 2018
Optical Properties and Electronic Structure of Amorphous Germanium Tauc, J.; Grigorovici, R.; Vancu, A. physica status solidi (b), Vol. 15, Issue 2 https://doi.org/10.1002/pssb.19660150224	journal	January 1966
Electronic structure and optical properties of CdTe rock‐salt high pressure phase Güder, H. S.; Gilliland, S.; Sans, J. A. physica status solidi (b), Vol. 235, Issue 2 https://doi.org/10.1002/pssb.200301612	journal	January 2003
Overview of HPCAT and capabilities for studying minerals and various other materials at high-pressure conditions Bommannavar, Arunkumar; Chow, Paul; Ferry, Rich Physics and Chemistry of Minerals, Vol. 49, Issue 9 https://doi.org/10.1007/s00269-022-01209-2	journal	August 2022
Reactions of Organic Ions at Ambient Surfaces in a Solvent-Free Environment Badu-Tawiah, Abraham K.; Cyriac, Jobin; Cooks, R. Graham Journal of The American Society for Mass Spectrometry, Vol. 23, Issue 5, p. 842-849 https://doi.org/10.1007/s13361-012-0337-7	journal	January 2012
Optical properties and electronic structure of amorphous Ge and Si Tauc, J. Materials Research Bulletin, Vol. 3, Issue 1 https://doi.org/10.1016/0025-5408(68)90023-8	journal	January 1968
Synthesis, optical spectroscopy and laser potential of 2,4,6-triphenylpyrylium chloride Bhowmik, Pradip Kumar; Principe, Ronald Carlo G.; Chen, Si L. Chemical Physics Letters, Vol. 805 https://doi.org/10.1016/j.cplett.2022.139927	journal	October 2022
CZTS stoichiometry effects on the band gap energy Malerba, Claudia; Biccari, Francesco; Azanza Ricardo, Cristy Leonor Journal of Alloys and Compounds, Vol. 582 https://doi.org/10.1016/j.jallcom.2013.07.199	journal	January 2014
Hybrid piezochromic coatings for impact detection on composite substrates for aeronautic Morelle, Q.; Senani, S.; Nicole, L. Materials Letters, Vol. 253 https://doi.org/10.1016/j.matlet.2019.06.045	journal	October 2019
Synthesis, optical spectroscopy and laser potential of pyrylium tosylates Koh, Jung Jae; Lee, Christina Inbok; Ciulei, Mihaela Alexa Journal of Molecular Structure, Vol. 1171 https://doi.org/10.1016/j.molstruc.2018.06.025	journal	November 2018
Synthesis, optical, and thermal properties of 2,4,6-tris(4-substituted phenyl)pyrylium tosylates and triflimides Bhowmik, Pradip Kumar; Lee, Christina Inbok; Koh, Jung Jae Journal of Molecular Structure, Vol. 1202 https://doi.org/10.1016/j.molstruc.2019.127325	journal	February 2020
Optical and structural properties of CsI thin film photocathode No authors listed Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 785 https://doi.org/10.1016/j.nima.2015.02.059	journal	June 2015
Magnetic and optical investigations on LaFeO3 powders with different particle sizes and corresponding ceramics Köferstein, Roberto; Jäger, Lothar; Ebbinghaus, Stefan G. Solid State Ionics, Vol. 249-250 https://doi.org/10.1016/j.ssi.2013.07.001	journal	November 2013
Structural Phase Transitions of NbO₂: Bulk versus Surface Páez Fajardo, Galo Jaime; Howard, Sebastian A.; Evlyukhin, Egor Chemistry of Materials, Vol. 33, Issue 4 https://doi.org/10.1021/acs.chemmater.0c04566	journal	February 2021
Wide Band Gap Chalcogenide Semiconductors Woods-Robinson, Rachel; Han, Yanbing; Zhang, Hanyu Chemical Reviews, Vol. 120, Issue 9 https://doi.org/10.1021/acs.chemrev.9b00600	journal	April 2020
Cationic Dependence of X-ray Induced Damage in Strontium and Barium Nitrate Goldberger, David; Park, Changyong; Evlyukhin, Egor The Journal of Physical Chemistry A, Vol. 122, Issue 44 https://doi.org/10.1021/acs.jpca.8b08224	journal	October 2018
Coupling-Assisted Renormalization of Excitons and Vibrations in Compressed MoSe ₂ –WSe ₂ Heterostructure Fu, Xinpeng; Li, Fangfei; Lin, Jung-Fu The Journal of Physical Chemistry C, Vol. 122, Issue 10 https://doi.org/10.1021/acs.jpcc.8b01453	journal	February 2018
Pressure-Induced Band Structure Evolution of Halide Perovskites: A First-Principles Atomic and Electronic Structure Study Huang, Yang; Wang, Lingrui; Ma, Zhuang The Journal of Physical Chemistry C, Vol. 123, Issue 1 https://doi.org/10.1021/acs.jpcc.8b11500	journal	December 2018
Pressure-Induced Phase Transition and Band Gap Engineering in Propylammonium Lead Bromide Perovskite Ren, Xiangting; Yan, Xiaozhi; Ahmad, Azkar Saeed The Journal of Physical Chemistry C, Vol. 123, Issue 24 https://doi.org/10.1021/acs.jpcc.9b02854	journal	May 2019
Effects of Different Counter Anions on Solid-State Electron Transfer in Viologen Compounds: Modulation of Color and Piezo- and Photochromic Properties Sui, Qi; Li, Peng; Sun, Rong The Journal of Physical Chemistry Letters, Vol. 11, Issue 21 https://doi.org/10.1021/acs.jpclett.0c02690	journal	October 2020
Self-Powered Filterless Narrow-Band p–n Heterojunction Photodetector for Low Background Limited Near-Infrared Image Sensor Application Wang, Li; Li, Zhen; Li, Ming ACS Applied Materials & Interfaces, Vol. 12, Issue 19 https://doi.org/10.1021/acsami.0c02827	journal	April 2020
2,4,6-Triphenylpyrylium Tetrafluoroborate as an Electron-Transfer Photosensitizer Miranda, Miguel A.; Garcia, Hermenegildo Chemical Reviews, Vol. 94, Issue 4 https://doi.org/10.1021/cr00028a009	journal	June 1994
Ionic Liquids Based on FeCl ₃ and FeCl ₂ . Raman Scattering and ab Initio Calculations Sitze, Melissa S.; Schreiter, Eric R.; Patterson, Eric V. Inorganic Chemistry, Vol. 40, Issue 10 https://doi.org/10.1021/ic001042r	journal	May 2001
Moessbauer and far-infrared studies of tetrahaloferrate anions of the type FeCl4-nBrn- Clausen, C. A.; Good, Mary L. Inorganic Chemistry, Vol. 9, Issue 2 https://doi.org/10.1021/ic50084a005	journal	February 1970
Material Design for Piezochromic Luminescence: Hydrogen-Bond-Directed Assemblies of a Pyrene Derivative Sagara, Yoshimitsu; Mutai, Toshiki; Yoshikawa, Isao Journal of the American Chemical Society, Vol. 129, Issue 6 https://doi.org/10.1021/ja0677362	journal	February 2007
Pressure-Induced Conductivity and Yellow-to-Black Piezochromism in a Layered Cu–Cl Hybrid Perovskite Jaffe, Adam; Lin, Yu; Mao, Wendy L. Journal of the American Chemical Society, Vol. 137, Issue 4 https://doi.org/10.1021/ja512396m	journal	January 2015
Direct Correlation of Structural Domain Formation with the Metal Insulator Transition in a VO ₂ Nanobeam Zhang, Shixiong; Chou, Jung Yen; Lauhon, Lincoln J. Nano Letters, Vol. 9, Issue 12 https://doi.org/10.1021/nl9028973	journal	December 2009
High Pressure Experimental Studies on CuO: Indication of Re-entrant Multiferroicity at Room Temperature Jana, Rajesh; Saha, Pinku; Pareek, Vivek Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep31610	journal	August 2016
Structural properties of ammonium iodide under high pressure Huang, Yanping; Huang, Xiaoli; Wang, Lu RSC Advances, Vol. 5, Issue 50 https://doi.org/10.1039/C5RA04211A	journal	January 2015
Fluorescence mutation and structural evolution of a π-conjugated molecular crystal during phase transition Xu, Yuanxiang; Wang, Kai; Zhang, Yujian Journal of Materials Chemistry C, Vol. 4, Issue 6 https://doi.org/10.1039/C5TC03745J	journal	January 2016
Piezochromism and hydrochromism through electron transfer: new stories for viologen materials Sui, Qi; Ren, Xiang-Ting; Dai, Yu-Xiang Chemical Science, Vol. 8, Issue 4 https://doi.org/10.1039/C6SC04579K	journal	January 2017
Amino acid-derived stimuli-responsive polymers and their applications Bauri, Kamal; Nandi, Mridula; De, Priyadarsi Polymer Chemistry, Vol. 9, Issue 11 https://doi.org/10.1039/C7PY02014G	journal	January 2018
Photoorganocatalysis, small organic molecules and light in the service of organic synthesis: the awakening of a sleeping giant Sideri, Ioanna K.; Voutyritsa, Errika; Kokotos, Christoforos G. Organic & Biomolecular Chemistry, Vol. 16, Issue 25 https://doi.org/10.1039/C8OB00725J	journal	January 2018
Synthesis of a novel strontium-based wide-bandgap semiconductor via X-ray photochemistry under extreme conditions Evlyukhin, Egor; Kim, Eunja; Cifligu, Petrika Journal of Materials Chemistry C, Vol. 6, Issue 46 https://doi.org/10.1039/C8TC04496A	journal	January 2018
Triazatruxene-based small molecules with thermally activated delayed fluorescence, aggregation-induced emission and mechanochromic luminescence properties for solution-processable nondoped OLEDs Chen, Yonghong; Wang, Shumeng; Wu, Xiaofu Journal of Materials Chemistry C, Vol. 6, Issue 46 https://doi.org/10.1039/C8TC04721A	journal	January 2018
Enhancing the light emission of GaAs nanowires by pressure-modulated charge transfer Ma, Luoman; Wang, Peng; Yin, Xuetong Nanoscale Advances, Vol. 2, Issue 6 https://doi.org/10.1039/D0NA00188K	journal	January 2020
Piezochromic luminescence in all-inorganic core–shell InP/ZnS nanocrystals via pressure-modulated strain engineering Liu, Hao; Zhao, Xiaohui; Yang, Xinyi Nanoscale Horizons, Vol. 5, Issue 8 https://doi.org/10.1039/D0NH00145G	journal	January 2020
Directly measuring the structural transition pathways of strain-engineered VO ₂ thin films Evlyukhin, Egor; Howard, Sebastian A.; Paik, Hanjong Nanoscale, Vol. 12, Issue 36 https://doi.org/10.1039/D0NR04776G	journal	January 2020
Piezochromic mechanism of organic crystals under hydrostatic pressure Li, Aisen; Xu, Shuping; Bi, Changjiang Materials Chemistry Frontiers, Vol. 5, Issue 6 https://doi.org/10.1039/D0QM00975J	journal	January 2021
Over one century after discovery: pyrylium salt chemistry emerging as a powerful approach for the construction of complex macrocycles and metallo-supramolecules Li, Yiming; Wang, Heng; Li, Xiaopeng Chemical Science, Vol. 11, Issue 45 https://doi.org/10.1039/D0SC04585C	journal	January 2020
Multi-stimuli responsive macromolecules and their assemblies Zhuang, Jiaming; Gordon, Mallory R.; Ventura, Judy Chemical Society Reviews, Vol. 42, Issue 17 https://doi.org/10.1039/c3cs60094g	journal	January 2013
Selective C–C bond cleavage of cyclopentadiene rings assisted by ferric chloride to synthesize water-soluble pyrylium salts Ye, Junwei; Zhang, Xiangdong; Deng, Dai RSC Advances, Vol. 3, Issue 22 https://doi.org/10.1039/c3ra41274a	journal	January 2013
Blue shift in ultraviolet absorption spectra of monodisperse CeO2−x nanoparticles Tsunekawa, S.; Fukuda, T.; Kasuya, A. Journal of Applied Physics, Vol. 87, Issue 3 https://doi.org/10.1063/1.372016	journal	February 2000
High pressure effect on structure, electronic structure, and thermoelectric properties of MoS2 Guo, Huaihong; Yang, Teng; Tao, Peng Journal of Applied Physics, Vol. 113, Issue 1 https://doi.org/10.1063/1.4772616	journal	January 2013
The laser micro-machining system for diamond anvil cell experiments and general precision machining applications at the High Pressure Collaborative Access Team Hrubiak, Rostislav; Sinogeikin, Stanislav; Rod, Eric Review of Scientific Instruments, Vol. 86, Issue 7 https://doi.org/10.1063/1.4926889	journal	July 2015
The high pressure dependence of x-ray induced decomposition of cadmium oxalate Lua Sanchez, Adrian F.; Cifligu, Petrika; Graff, Marc AIP Advances, Vol. 13, Issue 10 https://doi.org/10.1063/5.0168449	journal	October 2023
DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration Prescher, Clemens; Prakapenka, Vitali B. High Pressure Research, Vol. 35, Issue 3 https://doi.org/10.1080/08957959.2015.1059835	journal	May 2015
Pressure-induced electronic and isostructural phase transitions in PdPS: Raman, x-ray, and first-principles study Gupta, Satyendra Nath; Singh, Anjali; Sarkar, Sujoy Physical Review B, Vol. 101, Issue 3 https://doi.org/10.1103/PhysRevB.101.035123	journal	January 2020
Role of V-V dimers on structural, electronic, magnetic, and vibrational properties of VO2 by first-principles simulations and Raman spectroscopic analysis Mondal, Wasim Raja; Evlyukhin, Egor; Howard, Sebastian A. Physical Review B, Vol. 103, Issue 21 https://doi.org/10.1103/PhysRevB.103.214107	journal	June 2021
Observation of an Electric-Field-Induced Band Gap in Bilayer Graphene by Infrared Spectroscopy Mak, Kin Fai; Lui, Chun Hung; Shan, Jie Physical Review Letters, Vol. 102, Issue 25 https://doi.org/10.1103/PhysRevLett.102.256405	journal	June 2009
Pressure-Induced Intermolecular Interactions in Crystalline Silane-Hydrogen Yim, Wai-Leung; Tse, John S.; Iitaka, Toshiaki Physical Review Letters, Vol. 105, Issue 21 https://doi.org/10.1103/PhysRevLett.105.215501	journal	November 2010
Spectroscopic standards for four- and fivefold-coordinated Fe ²⁺ in oxygen-based minerals Rossman, George R.; Taran, Michael N. American Mineralogist, Vol. 86, Issue 7-8 https://doi.org/10.2138/am-2001-0713	journal	July 2001

Similar Records

High-Pressure Investigation of 2,4,6-Trinitro-3-bromoanisole (TNBA): Structural Determination and Piezochromism

Journal Article · Thu Jan 06 19:00:00 EST 2022 · Journal of Physical Chemistry. C · OSTI ID:1841858

Pressure-induced polymorphism and piezochromism in Mn₂FeSbO₆

Journal Article · Mon Apr 22 20:00:00 EDT 2019 · Applied Physics Letters · OSTI ID:1524678

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
diamond anvil cells
high pressures
piezochromic
pyrylium salts

Piezochromic Behavior of 2,4,6-Triphenylpyrylium Tetrachloroferrate

Citation Formats

References (61)

Similar Records

Related Subjects