Quest for Multifunctionality: Current Progress in the Characterization of Heterometallic Metal–Organic Frameworks

Sikma, Ronald Eric; Butler, Kimberly S.; Vogel, Dayton Jonathan; Harvey, Jacob A.; Sava Gallis, Dorina F.

doi:10.1021/jacs.3c05425

Quest for Multifunctionality: Current Progress in the Characterization of Heterometallic Metal–Organic Frameworks

Journal Article · Fri Feb 16 00:00:00 EST 2024 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.3c05425· OSTI ID:2341394

Sikma, Ronald Eric ^[1]; ^[1]; ^[1]; ^[1]; ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Metal–organic frameworks (MOFs) are a class of porous, crystalline materials that have been systematically developed for a broad range of applications. Incorporation of two or more metals into a single crystalline phase to generate heterometallic MOFs has been shown to lead to synergistic effects, in which the whole is oftentimes greater than the sum of its parts. Because geometric proximity is typically required for metals to function cooperatively, deciphering and controlling metal distributions in heterometallic MOFs is crucial to establish structure–function relationships. However, determination of short- and long-range metal distributions is nontrivial and requires the use of specialized characterization techniques. Advancements in the characterization of metal distributions and interactions at these length scales is key to rapid advancement and rational design of functional heterometallic MOFs. Further, this perspective summarizes the state-of-the-art in the characterization of heterometallic MOFs, with a focus on techniques that allow metal distributions to be better understood. Using complementary analyses, in conjunction with computational methods, is critical as this field moves toward increasingly complex, multifunctional systems.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: NA0003525

OSTI ID:: 2341394

Report Number(s):: SAND--2024-05030J

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 9 Vol. 146; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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