Cation Migration in Physically Paired 2D and 3D Lead Halide Perovskite Films

Mathew, Prrethi S.; Kamat, Prashant V.

doi:10.1002/adom.202300957

Cation Migration in Physically Paired 2D and 3D Lead Halide Perovskite Films

Journal Article · Sat Aug 26 00:00:00 EDT 2023 · Advanced Optical Materials

DOI:https://doi.org/10.1002/adom.202300957· OSTI ID:2338295

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University of Notre Dame, IN (United States); University of Notre Dame
University of Notre Dame, IN (United States)

2D/3D interfaces provide long-term stability for the operation of metal halide perovskite solar cells. However, the cation migration under heat and light can disturb the interface and create a graded cation interface. This study has now probed the cation migration by physically pairing X₂PbI₄ (X = butylammonium BA, oleylammonium OA, or phenethylammonium PEA) 2D film and (CH₃NH₃, MA)PbI₃ 3D film at different temperatures and recording changes in the absorption and emission spectra. The migration of the methyl ammonium cation toward the 2D film slowly transforms the n = 1 layered phase into n = 2 and 3 layered phases. The 3D film, on the other hand, exhibits relatively small changes, as the inclusion of spacer cation has little effect on its phase. The apparent activation energy determined from the temperature-dependent cation migration kinetics (E_a = 29– 50 kJ mol^–1) indicates alkyl ammonium cations such as butyl ammonium migrate more readily into the 3D layer than aromatic cations such as PEA. As a result, the ease of migration of spacer cations between physically paired films suggests that the varied composition at the interface should be considered while evaluating the effectiveness of the 2D/3D design strategy for improving the performance of perovskite solar cells.

View Accepted Manuscript (DOE)

Research Organization:: University of Notre Dame, IN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: FC02-04ER15533; SC0014334

OSTI ID:: 2338295

Alternate ID(s):: OSTI ID: 2324715

Journal Information:: Advanced Optical Materials, Journal Name: Advanced Optical Materials Journal Issue: 8 Vol. 12; ISSN 2195-1071

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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