Green mechanochemical synthesis of imine-linked covalent organic frameworks for high iodine capture

Brown, Normanda; Alsudairy, Ziad; Behera, Ranjan; Akram, Fazli; Chen, Kuangcai; Smith-Petty, Kayla; Motley, Bria; Williams, Spirit; Huang, Wenyu; Ingram, Conrad; Li, Xinle

doi:10.1039/d3gc01927f

Green mechanochemical synthesis of imine-linked covalent organic frameworks for high iodine capture

Journal Article · Tue Jul 25 00:00:00 EDT 2023 · Green Chemistry

DOI:https://doi.org/10.1039/d3gc01927f· OSTI ID:2337851

Brown, Normanda ^[1]; ^[2]; Behera, Ranjan ^[3]; ^[2]; ^[4]; Smith-Petty, Kayla ^[2]; Motley, Bria ^[2]; Williams, Spirit ^[2]; ^[3]; Ingram, Conrad ^[2]; ^[2]

Clark Atlanta Univ., Atlanta, GA (United States); Clark Atlanta university
Clark Atlanta Univ., Atlanta, GA (United States)
Iowa State Univ., Ames, IA (United States)
Georgia State Univ., Atlanta, GA (United States)

Covalent organic frameworks (COFs) have emerged as promising adsorbents for radioiodine capture. However, the conventional solvothermal synthesis contradicts the principles of green chemistry due to the use of hazardous solvents, long reaction times (typically 3 days), and high reaction temperatures. Here, to address these issues, we demonstrate for the first time the green, efficient, liquid-assisted mechanochemical synthesis of COF adsorbents for high iodine capture. The ball milling synthesis was performed with various liquid additives at ambient temperature, yielding six imine-linked COFs of diverse pore sizes and functionalities in merely 1 hour. Notably, one representative COF exhibited high crystallinity and a remarkable surface area of 1387 m² g^–1 in just 1 minute of ball milling. When tested as adsorbents for static iodine vapor capture at 75 °C, four mechanochemically synthesized COFs exhibited outstanding iodine adsorption capacities of 6.4–7.1 g g^–1, comparable to or exceeding those of solvothermally synthesized COF and most reported COF adsorbents. Furthermore, Fourier transform infrared and X-ray photoelectron spectroscopy corroborated the charge transfer between iodine and COF adsorbents. This mechanochemical methodology will pave the path for green, rapid, facile, and scalable synthesis of COFs, revealing great prospects for applications in environmental remediation and beyond.

View Accepted Manuscript (DOE)

Research Organization:: Clark Atlanta Univ., Atlanta, GA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: SC0022000

OSTI ID:: 2337851

Alternate ID(s):: OSTI ID: 1992967

Journal Information:: Green Chemistry, Journal Name: Green Chemistry Journal Issue: 16 Vol. 25; ISSN 1463-9262

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
54 ENVIRONMENTAL SCIENCES
covalent organic frameworks
iodine capture
mechanochemical synthesis

Green mechanochemical synthesis of imine-linked covalent organic frameworks for high iodine capture

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