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Tuning and high throughput experimental screening of eutectic electrolytes with co-solvents for redox flow batteries

Journal Article · · Electrochimica Acta
Eutectic solvents, with high salt concentrations and suppressed volatility, are promising alternatives to aqueous and volatile organic electrolytes for grid-scale energy storage devices such as redox flow batteries (RFBs). However, it is not known a priori which hydrogen bond acceptors and donors would form a eutectic solvent and at which compositions of these mixtures would yield desirable properties for RFBs. Specifically, the known deep eutectic solvents generally have high viscosities and low ionic conductivities, especially in the landscape of RFB electrolytes. We report a high throughput experimental (HTE) study was carried out to assess the properties of eutectic solvents based on choline chloride as the hydrogen bond acceptor and ethylene glycol and aniline as the hydrogen bond donors. In addition, water, acetonitrile, and dimethyl sulfoxide as co-solvents were examined in terms of tuning the viscosity, conductivity, and solubility of two redox-active species: methyl viologen dichloride hydrate (MVCl2·H2O, or MV for simplicity) and 2,1,3-benzothiadiazole (BTZ) that are relevant to RFBs. The HTE framework enabled the development of a rapid and comprehensive understanding of the design of new eutectic electrolytes incorporating co-solvents to improve the physicochemical and electrochemical properties for RFBs.
Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE; USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE Office of Science (SC)
Grant/Contract Number:
AC05-76RL01830; SC0019409
OSTI ID:
2337786
Alternate ID(s):
OSTI ID: 2217687
Report Number(s):
PNNL-SA--194516
Journal Information:
Electrochimica Acta, Journal Name: Electrochimica Acta Vol. 474; ISSN 0013-4686
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

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