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Ceramic–Metal (Cermet) Composites: A Review of Key Properties and Synthesis Methods Focused on Nuclear Waste Immobilization

Journal Article · · Industrial and Engineering Chemistry Research

Here this paper reviews key properties, applications, and examples of ceramic-metal composites (cermets), and metal matrix composites (MMC) with emphasis on their applicability as waste forms for immobilizing nuclear waste. While the literature is mature for vitrified and cementitious radioactive waste forms, cermet materials have not received adequate attention as potential candidates for immobilizing nuclear waste. To promulgate this effort, this review connects cermet and MMC design, such as hardened tools, with the chemistry of radioactive waste streams. A discussion on certification and qualification standards for cermet waste forms, literature gaps, and “how-to” sections on cermet processing techniques. Key parameters discussed include thermal conductivity, chemical durability, and waste loading, as well as examples for metal-containing waste forms. As cermet waste forms gain momentum within the community, this review paper aims ensure the end-of-life nuclear fuel cycle is addressed from a materials and waste disposition perspective.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE Office of Nuclear Energy (NE); USDOE Advanced Research Projects Agency - Energy (ARPA-E)
Grant/Contract Number:
AC05-76RL01830
OSTI ID:
2337426
Report Number(s):
PNNL-SA--191155
Journal Information:
Industrial and Engineering Chemistry Research, Journal Name: Industrial and Engineering Chemistry Research Journal Issue: 14 Vol. 63; ISSN 0888-5885
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English

References (121)

Functionalized Silica Aerogels: Advanced Materials to Capture and Immobilize Radioactive Iodine book September 2011
Waste Immobilization in Glass and Ceramic Based Hosts book April 2010
Berechnung verschiedener physikalischer Konstanten von heterogenen Substanzen. I. Dielektrizitätskonstanten und Leitfähigkeiten der Mischkörper aus isotropen Substanzen journal January 1935
Advanced production routes for metal matrix composites journal November 2020
A history of Hanford tank waste, implications for waste treatment, and disposal journal December 2020
Composite Materials book September 2012
Initial dislocation distributions in tungsten fibre-copper composites journal January 1972
Effective thermal conductivity of dispersed materials journal March 1980
Allgemeine Gesetzmäßigkeiten für das Wärmeleitvermögen verschiedener Stoffarten und Aggregatzustände journal January 1940
Role of the Binder Phase in Cemened Tungsten Carbide-Cobalt Alloys journal October 1952
Uncertainty of Thermal Diffusivity Measurements by Laser Flash Method journal November 2005
New Transient Hot-Bridge Sensor to Measure Thermal Conductivity, Thermal Diffusivity, and Volumetric Specific Heat journal May 2006
Enhanced Transient Hot Bridge Method Using a Finite Element Analysis journal December 2018
Identification and characterization of diffusion barriers for Cu/SiC systems journal July 2005
The effect of electric field and pressure on the synthesis and consolidation of materials: A review of the spark plasma sintering method journal February 2006
Review: liquid phase sintering journal January 2009
Fundamental aspects of hot isostatic pressing: An overview journal December 2000
Effects of tungsten particle size and copper content on densification of liquid-phase-sintered W-Cu journal October 2005
Al-TiC composites In Situ-processed by ingot metallurgy and rapid solidification technology: Part I. Microstructural evolution journal March 1998
Solid-state contributions to densification during liquid-phase sintering journal December 1996
The galvanic corrosion of SiC monofilament/ZE41 Mg metal-matrix composite in 0.5 M NaNO3 journal November 1993
Thermal cycling of copper matrix-tungsten fiber composites: A metallographic study journal April 1973
Mechanical properties of hard metals and their erosive wear resistance journal October 1994
A modified Maxwell-Eucken equation for calculating the thermal conductivity of two-component solutions or mixtures journal July 1981
Cermets and Hardmetals book January 2001
Powder Metallurgy Routes for Composite Materials Production book July 2021
Reactive and liquid-phase sintering techniques book June 2017
Structure and properties of boron carbide with aluminum incorporation journal March 2000
Electromigration effects in Al-Au multilayers journal March 2001
Effects of Graphite on the Corrosion Behavior of Aluminum-Graphite Composite in Sodium Chloride Solutions journal April 2011
Effect of nano addition on the microstructures and mechanical properties of Ti(C, N)-based cermets journal January 2005
Synthesis and thermal behavior of Cu/Y2W3O12 composite journal June 2014
Development of Pyrochemical Reprocessing for Spent Metal Fuels journal January 2011
Current status on manufacturing routes to produce metal matrix composites: State-of-the-art journal February 2023
Cermets with Fe-alloy binder: A review journal November 2020
Liquid-phase sintering of Ti(C,N)-based cermets. The effects of binder nature and content on the solubility and wettability of hard ceramic phases journal May 2013
Bismuth-based materials for iodine capture and storage: A review journal August 2021
Comparison of the effect of different alkali halides on the preparation of transparent MgAl2O4 spinel ceramics via spark plasma sintering (SPS) journal December 2020
Hanford low-activity waste vitrification: A review journal January 2024
On the mechanics of cold die compaction for powder metallurgy journal July 2005
Mechanical, corrosion and biocompatibility behaviour of Mg-3Zn-HA biodegradable composites for orthopaedic fixture accessories journal February 2018
Enhancing high-temperature properties of stainless steel composite with titanium carbide reinforcement: a study on coefficient of thermal expansion, thermal conductivity, and strength journal July 2023
Structural analysis of some sodium and alumina rich high-level nuclear waste glasses journal February 2012
Nepheline crystallization in boron-rich alumino-silicate glasses as investigated by multi-nuclear NMR, Raman, & Mössbauer spectroscopies journal February 2015
Literature review of thermal and radiation performance parameters for high-temperature, uranium dioxide fueled cermet materials journal July 2007
Microstructure and thermal conductivity of Mo–TiC cermets processed by hot isostatic pressing journal October 2008
Tellurite glass as a waste form for mixed alkali–chloride waste streams: Candidate materials selection and initial testing journal May 2012
Nuclear fuel cycle waste stream immobilization with cermets for improved thermal properties and waste consolidation journal July 2013
Epsilon metal waste form for immobilization of noble metals from used nuclear fuel journal October 2013
The influence of SiC particle size and volume fraction on the thermal conductivity of spark plasma sintered UO2–SiC composites journal November 2013
Iodine solubility in a low-activity waste borosilicate glass at 1000°C journal September 2014
Capture of iodine from the vapour phase and immobilisation as sodalite journal December 2015
Materials and processes for the effective capture and immobilization of radioiodine: A review journal March 2016
Dilute condition corrosion behavior of glass-ceramic waste form journal December 2016
Silver iodide sodalite – Wasteform / Hip canister interactions and aqueous durability journal April 2019
Effect of zeolite type, temperature, and pH on Stage III glass alteration behavior for two nuclear waste glasses journal August 2022
Cermet nuclear waste forms: Phase identification and connectivity journal December 2022
Grain Size Control by Matrix Phase Additives in Nuclear Thermal Propulsion Cermets journal April 2023
TiC-(Ti,M)C core-rim structures in solid-state manufactured steel-based MMCs journal October 2019
Nano-particles dispersion effect on Ni/Al2O3 composite coatings journal July 2004
Thermal expansion and thermal conductivity characteristics of Cu–Al2O3 nanocomposites journal April 2013
Corrosion study on AA5083 aluminum alloy - boron carbide composite journal January 2019
Ultrafast high-temperature sintering to avoid metal loss toward high-performance and scalable cermets journal February 2022
Overcoming the effect of contaminant in solid oxide fuel cell (SOFC) electrolyte: spark plasma sintering (SPS) of 0.5wt.% silica-doped yttria-stabilized zirconia (YSZ) journal June 2004
Thermal conductivity of Al–SiC composites with monomodal and bimodal particle size distribution journal May 2008
Challenges with vitrification of Hanford High-Level Waste (HLW) to borosilicate glass – An overview journal December 2019
Molten salt reactor waste and effluent management strategies: A review journal April 2019
Investigation of thermal conductivity and microstructure of the α-Al2O3 particulate reinforced aluminum composites (Al/Al2O3-MMC) by powder metallurgy method journal February 2010
Radioactive waste partitioning and transmutation within advanced fuel cycles: Achievements and challenges journal January 2011
Capture of Elemental and Organic Iodine from Dilute Gas Streams by Silver-exchanged Mordenite journal January 2016
Fabrication, Surface Morphology and Corrosion Investigation of Al 7075-Al2O3 Matrix Composite in Sea Water and Industrial Environment journal January 2014
Excessive porosity after liquid-phase sintering of elemental titanium powder blends journal May 2007
WC-Cu thermal barriers for fusion applications journal December 2018
Thermal conductivity measurements on wood materials with transient plane source technique journal January 2015
Electrochemical Salt Wasteform Development: A Review of Salt Treatment and Immobilization Options journal May 2020
Iodine Capture by Ag-Loaded Solid Sorbents Followed by Ag Recycling and Iodine Immobilization: An End-to-End Process journal February 2023
Consolidation of Tin Sulfide Chalcogels and Xerogels with and without Adsorbed Iodine journal November 2015
Chalcogenide Aerogels as Sorbents for Noble Gases (Xe, Kr) journal February 2017
Silver-Loaded Aluminosilicate Aerogels As Iodine Sorbents journal September 2017
Chalcogen-Based Aerogels As Sorbents for Radionuclide Remediation journal June 2013
A Two-Column Method for the Separation of Kr and Xe from Process Off-Gases journal July 2014
Forty years of durability assessment of nuclear waste glass by standard methods journal December 2021
Flash Method of Determining Thermal Diffusivity, Heat Capacity, and Thermal Conductivity journal September 1961
Thermal conductivity and interfacial conductance of AlN particle reinforced metal matrix composites journal March 2011
Fabrication of metal matrix composites by powder metallurgy: A review conference January 2018
An overview of solvent extraction processes developed in Europe for advanced nuclear fuel recycling, part 1 — heterogeneous recycling journal July 2020
An overview of solvent extraction processes developed in Europe for advanced nuclear fuel recycling, Part 2 — homogeneous recycling journal November 2021
Processing and performance assessment of particulate TiB2 reinforced aluminum MMC developed via a novel hybrid ultrasonic casting system journal August 2021
LVI. On the influence of obstacles arranged in rectangular order upon the properties of a medium journal December 1892
The Electrical Conductivity of Composite Media journal August 1956
The Elastic and Thermo-elastic Properties of Composite Media journal August 1956
A Mathematical Treatment of the Electric Conductivity and Capacity of Disperse Systems I. The Electric Conductivity of a Suspension of Homogeneous Spheroids journal November 1924
Submixture model to predict nepheline precipitation in waste glasses journal May 2016
Cermets: I, Fundamental Concepts Related to Micro‐structure and Physical Properties of Cermet Systems journal February 1956
Electric Current Activation of Sintering: A Review of the Pulsed Electric Current Sintering Process: Electric Current Activation of Sintering journal November 2010
Synroc technology: Perspectives and current status (Review) journal July 2020
The Use of Hot-Isostatic Pressing to Process Nuclear Waste Forms
  • Stewart, Martin W. A.; Moricca, Sam A.; Eddowes, Tina
  • ASME 2009 12th International Conference on Environmental Remediation and Radioactive Waste Management, Volume 1 https://doi.org/10.1115/ICEM2009-16253
conference January 2009
Nanoaerosols formation during the bubbling of lithium and beryllium fluorides molten salt to produce reactor radioisotopes journal December 2009
Hardmetals and Cermets journal August 1989
On the Conductivity of Dispersions journal January 1959
Conductivities in Emulsions journal January 1961
Thermal conductivity of advanced TiC reinforced metal matrix composites for polymer processing applications journal December 2013
Enhancement of Wettability of Aluminum Based Silicon Carbide Reinforced Particulate Metal Matrix Composite journal January 2014
The Effect of Rapid Microwave Sintering Process on the Electrical Conductivity, Thermal Conductivity and Mechanical Properties of Al-TiC Composites journal October 2018
Expanded Analysis of Hot Isostatic Pressed Iodine-Loaded Silver-Exchanged Mordenite report September 2014
Cermet high level waste forms report June 1978
Preparation of Four Large-format Hot Isostatically Pressed I-AgZ Waste Form Samples for Performance Testing report September 2018
Closed Fuel Cycle Waste Treatment Strategy report February 2015
Corrosion of Materials in Fused Hydroxides report March 1956
Literature survey: methods for the removal of iodine species from off-gases and liquid waste streams of nuclear power and nuclear fuel reprocessing plants, with emphasis on solid sorbents report January 1979
Immobilization of chloride-rich radioactive wastes produced by pyrochemical operations report August 1997
Retention of Halogens in Waste Glass report May 2010
Review of recent developments in iodine wasteform production journal December 2022
Recent advances in the removal of radioactive iodine by bismuth-based materials journal January 2023
Cermet Systems: Synthesis, Properties, and Applications journal June 2022
Abrasion and Erosion Resistance of Cermets: A Review journal December 2021
Wettability in Metal Matrix Composites journal June 2021
Metal Matrix Composites Reinforced by Nano-Particles—A Review journal March 2014
Powder Metallurgical Synthesis of Biodegradable Mg-Hydroxyapatite Composites for Biomedical Applications journal August 2015
Vitrification of wastes: from unwanted to controlled crystallization, a review journal December 2022
Thermal-expansion stresses in reinforced plastics journal October 1946