Interfacial Assembly and Jamming of Soft Nanoparticle Surfactants into Colloidosomes and Structured Liquids

Wang, Beibei; Yin, Bangqi; Yu, Hao; Zhang, Zhao; Wang, Guan; Shi, Shaowei; Gu, Xinggui; Yang, Wantai; Tang, Ben Zhong; Russell, Thomas P.

doi:10.1021/acsami.2c13414

Interfacial Assembly and Jamming of Soft Nanoparticle Surfactants into Colloidosomes and Structured Liquids

Journal Article · Mon Nov 28 00:00:00 EST 2022 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.2c13414· OSTI ID:2326972

Wang, Beibei ^[1]; Yin, Bangqi ^[1]; Yu, Hao ^[1]; Zhang, Zhao ^[1]; Wang, Guan ^[1]; ^[1]; ^[2]; ^[1]; ^[3]; ^[4]

Beijing University of Chemical Technology, Beijing (China)
Beijing University of Chemical Technology, Beijing (China); Beijing National Laboratory for Molecular Sciences, Beijing (China)
The Chinese University of Hong Kong, Shenzhen (Hong Kong)
University of Massachusetts, Amherst, MA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Materials Sciences Division

Nanoparticle surfactant (NPS) offers a powerful strategy to generate all-liquid constructs that integrate the inherent properties of the NPs into 3D architectures. In this report using the co-assembly of fluorescent polymeric nanoparticles and amine-functionalized polyhedral oligomeric silsesquioxane, the assembly and jamming behavior of a new type of NPS at the oil-water interface is uncovered. Unlike "solid" inorganic nanoparticles, "soft" polymeric nanoparticles can reorganize when jammed, leading to a relaxation and deformation of the interfacial assemblies, for example, the 3D printed sugar-coated haw stick-like liquid tubules. With NPS serving as emulsifiers, stable Pickering emulsions are prepared that can be converted into robust colloidosomes with pH responsiveness, showing numerous potential applications for encapsulation and controlled release.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: Army Research Office (ARO); Beijing National Laboratory for Molecular Sciences; National Natural Science Foundation of China; National Science Foundation of China; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2326972

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 48 Vol. 14; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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