Large magnetic anisotropy of a decorated spin-chain system K2Co3(MoO4)3(OH)2

Patel, Bhakti K.; Ye, Feng; Liyanage, W. C.; Buchanan, C. Charlotte; Gilbert, Dustin A.; Kolis, Joseph W.; Sanjeewa, Liurukara D.

doi:10.1039/d4dt00203b

Large magnetic anisotropy of a decorated spin-chain system K₂Co₃(MoO₄)₃(OH)₂

Journal Article · Thu Feb 15 00:00:00 EST 2024 · Dalton Transactions

DOI:https://doi.org/10.1039/d4dt00203b· OSTI ID:2324010

^[1]; ^[2]; Liyanage, W. C. ^[3]; Buchanan, C. Charlotte ^[3]; ^[3]; Kolis, Joseph W. ^[1]; ^[4]

Clemson Univ., SC (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Missouri, Columbia, MO (United States)

The magnetic structure of K₂Co₃(MoO₄)₃(OH)₂ is studied in detail. The material has a half-sawtooth one-dimensional (1-D) structure containing two unique Co²⁺ ions, one in the chain backbone and one on the apex of the sawtooth creating a series of isosceles triangles along the b-axis. These triangles can be a source of magnetic frustration. The ability to grow large single crystals enables detailed magnetic measurements with the crystals oriented in a magnetic field along the respective axes. It has a Curie–Weiss temperature θ_CW of 5.3(2) K with an effective magnetic moment of 4.8(3)μ_B/Co. The material is highly anisotropic with a sharp antiferromagnetic ordering transition at 7 K with a metamagnetic transition at 2 kOe. Neutron diffraction was used to determine the magnetic structure and revealed a magnetic structure with canted spins along the backbone of the chain while spins along the sawtooth caps maintained a colinear orientation, arranging antiferromagnetically relative to the backbone spins. In conclusion, the parallel chains arrange antiferromagnetically relative to each other along the c-axis and ferromagnetically along the a-axis.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States); University of Tennessee, Knoxville, TN (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: AC05-00OR22725; SC0021344

OSTI ID:: 2324010

Alternate ID(s):: OSTI ID: 2309812
OSTI ID: 3013109

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Vol. 53; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (46)

Alkali Transition‐Metal Molybdates: A Stepwise Approach to Geometrically Frustrated Systems Smith Pellizzeri, Tiffany M.; McMillen, Colin D.; Kolis, Joseph W. Chemistry – A European Journal, Vol. 26, Issue 3 https://doi.org/10.1002/chem.201904193	journal	November 2019
Theoretical and experimental developments in quantum spin liquid in geometrically frustrated magnets: a review Shaginyan, V. R.; Stephanovich, V. A.; Msezane, A. Z. Journal of Materials Science, Vol. 55, Issue 6 https://doi.org/10.1007/s10853-019-04128-w	journal	November 2019
Corelli: Efficient single crystal diffraction with elastic discrimination Rosenkranz, Stephan; Osborn, Raymond Pramana, Vol. 71, Issue 4 https://doi.org/10.1007/s12043-008-0259-x	journal	October 2008
Recent advances in magnetic structure determination by neutron powder diffraction Rodríguez-Carvajal, Juan Physica B: Condensed Matter, Vol. 192, Issue 1-2 https://doi.org/10.1016/0921-4526(93)90108-I	journal	October 1993
Critical phenomena and renormalization-group theory Pelissetto, Andrea; Vicari, Ettore Physics Reports, Vol. 368, Issue 6 https://doi.org/10.1016/S0370-1573(02)00219-3	journal	October 2002
Magnetic properties of six-coordinated high-spin cobalt(II) complexes: Theoretical background and its application Lloret, Francesc; Julve, Miguel; Cano, Joan Inorganica Chimica Acta, Vol. 361, Issue 12-13 https://doi.org/10.1016/j.ica.2008.03.114	journal	September 2008
Quantum Information and Algorithms for Correlated Quantum Matter Head-Marsden, Kade; Flick, Johannes; Ciccarino, Christopher J. Chemical Reviews, Vol. 121, Issue 5 https://doi.org/10.1021/acs.chemrev.0c00620	journal	December 2020
K₂Mn₃O(OH)(VO₄)(V₂O₇) with Sawtooth Chains of Multivalent Manganese Triangular Trimer Units: Magnetic Susceptibility Shrouding a Long-Range Antiferromagnetic Order of Ferromagnetic Triangles Yakubovich, Olga V.; Shvanskaya, Larisa V.; Kiriukhina, Galina V. Inorganic Chemistry, Vol. 62, Issue 35 https://doi.org/10.1021/acs.inorgchem.3c01100	journal	August 2023
Synthesis, Structure, and Magnetic Properties of A₂Cu₅(TeO₃)(SO₄)₃(OH)₄ (A = Na, K): The First Compounds with a 1D Kagomé Strip Lattice Tang, Yingying; Guo, Wenbin; Xiang, Hongping Inorganic Chemistry, Vol. 55, Issue 2 https://doi.org/10.1021/acs.inorgchem.5b01889	journal	January 2016
Investigation of a Structural Phase Transition and Magnetic Structure of Na ₂ BaFe(VO ₄ ) ₂ : A Triangular Magnetic Lattice with a Ferromagnetic Ground State Sanjeewa, Liurukara D.; Garlea, Vasile O.; McGuire, Michael A. Inorganic Chemistry, Vol. 56, Issue 24 https://doi.org/10.1021/acs.inorgchem.7b02024	journal	December 2017
Single Crystals of Cubic Rare-Earth Pyrochlore Germanates: RE ₂ Ge ₂ O ₇ (RE = Yb and Lu) Grown by a High-Temperature Hydrothermal Technique Sanjeewa, Liurukara D.; Ross, Kate A.; Sarkis, Colin L. Inorganic Chemistry, Vol. 57, Issue 20 https://doi.org/10.1021/acs.inorgchem.8b01810	journal	September 2018
Observation of a Large Magnetic Anisotropy and a Field-Induced Magnetic State in SrCo(VO ₄ )(OH): A Structure with a Quasi One-Dimensional Magnetic Chain Sanjeewa, Liurukara D.; Garlea, V. Ovidiu; Fishman, Randy S. Inorganic Chemistry, Vol. 59, Issue 2 https://doi.org/10.1021/acs.inorgchem.9b02427	journal	December 2019
Crystal Growth and Magnetic Properties of BaCo ₂ V ₂ O ₈ He, Zhangzhen; Fu, Desheng; Kyômen, Tôru Chemistry of Materials, Vol. 17, Issue 11 https://doi.org/10.1021/cm050760e	journal	May 2005
Crystal and Magnetic Structures and Physical Properties of a New Pyroxene NaMnGe ₂ O ₆ Synthesized under High Pressure Cheng, Jinguang; Tian, Wei; Zhou, Jianshi Journal of the American Chemical Society, Vol. 135, Issue 7 https://doi.org/10.1021/ja312038g	journal	February 2013
CoV ₂ O ₆ Single Crystals Grown in a Closed Crucible: Unusual Magnetic Behaviors with Large Anisotropy and ¹ / ₃ Magnetization Plateau He, Zhangzhen; Yamaura, Jun-Ichi; Ueda, Yutaka Journal of the American Chemical Society, Vol. 131, Issue 22 https://doi.org/10.1021/ja902623b	journal	June 2009
Spin liquids in frustrated magnets Balents, Leon Nature, Vol. 464, Issue 7286 https://doi.org/10.1038/nature08917	journal	March 2010
Fractionalized excitations in the spin-liquid state of a kagome-lattice antiferromagnet Han, Tian-Heng; Helton, Joel S.; Chu, Shaoyan Nature, Vol. 492, Issue 7429 https://doi.org/10.1038/nature11659	journal	December 2012
Emergent functions of quantum materials Tokura, Yoshinori; Kawasaki, Masashi; Nagaosa, Naoto Nature Physics, Vol. 13, Issue 11 https://doi.org/10.1038/nphys4274	journal	September 2017
The physics of quantum materials Keimer, B.; Moore, J. E. Nature Physics, Vol. 13, Issue 11 https://doi.org/10.1038/nphys4302	journal	October 2017
Magnetic states of coupled spin tubes with frustrated geometry in CsCrF4 Hagihala, Masato; Hayashida, Shohei; Avdeev, Maxim npj Quantum Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s41535-019-0152-5	journal	April 2019
Proximate spin liquid and fractionalization in the triangular antiferromagnet KYbSe2 Scheie, A. O.; Ghioldi, E. A.; Xing, J. Nature Physics, Vol. 20, Issue 1 https://doi.org/10.1038/s41567-023-02259-1	journal	November 2023
Hydrothermal synthesis as a route to mineralogically-inspired structures McMillen, Colin D.; Kolis, Joseph W. Dalton Transactions, Vol. 45, Issue 7 https://doi.org/10.1039/C5DT03424H	journal	January 2016
A frustrated ferrimagnet Cu ₅ (VO4) ₂ (OH) ₄ with a 1/5 magnetization plateau on a new spin-lattice of alternating triangular and honeycomb strips Zhang, Su-Yun; Guo, Wen-Bin; Yang, Ming Dalton Transactions, Vol. 44, Issue 47 https://doi.org/10.1039/C5DT03534A	journal	January 2015
Synthesis and magnetic properties of new tellurate compounds Na ₄ MTeO ₆ (M = Co and Ni) with a ferromagnetic spin-chain structure He, Zhangzhen; Guo, Wenbin; Cui, Meiyan Dalton Transactions, Vol. 46, Issue 15 https://doi.org/10.1039/C6DT04750E	journal	January 2017
Magnetic ordering in a frustrated bow-tie lattice Vera Stimpson, Laura J.; Rodriguez, Efrain E.; Brown, Craig M. Journal of Materials Chemistry C, Vol. 6, Issue 16 https://doi.org/10.1039/C7TC05187E	journal	January 2018
NaCo₂(SeO₃)₂(OH): competing magnetic ground states of a new sawtooth structure with 3d⁷ Co²⁺ ions Sanjeewa, Liurukara D.; Ovidiu Garlea, V.; Taddei, Keith M. Inorganic Chemistry Frontiers, Vol. 9, Issue 17 https://doi.org/10.1039/D2QI01072K	journal	January 2022
Field tunable magnetic transitions of CsCo₂(MoO₄)₂(OH): a triangular chain structure with a frustrated geometry Sanjeewa, Liurukara D.; Garlea, V. Ovidiu; Fishman, Randy S. Materials Chemistry Frontiers, Vol. 7, Issue 6 https://doi.org/10.1039/D2QM01272C	journal	January 2023
A suite-level review of the neutron single-crystal diffraction instruments at Oak Ridge National Laboratory Coates, L.; Cao, H. B.; Chakoumakos, B. C. Review of Scientific Instruments, Vol. 89, Issue 9 https://doi.org/10.1063/1.5030896	journal	September 2018
The magnetic order of a manganese vanadate system with two-dimensional striped triangular lattice Garlea, V. Ovidiu; McGuire, Michael A.; Sanjeewa, Liurukara D. AIP Advances, Vol. 8, Issue 10 https://doi.org/10.1063/1.5043124	journal	October 2018
The 2021 quantum materials roadmap Giustino, Feliciano; Lee, Jin Hong; Trier, Felix Journal of Physics: Materials, Vol. 3, Issue 4 https://doi.org/10.1088/2515-7639/abb74e	journal	October 2020
Paramagnetic and Optical Spectra of Divalent Cobalt in Cubic Crystalline Fields Low, W. Physical Review, Vol. 109, Issue 2 https://doi.org/10.1103/PhysRev.109.256	journal	January 1958
Magnon crystals and magnetic phases in a kagome-stripe antiferromagnet Acevedo, S.; Lamas, C. A.; Arlego, M. Physical Review B, Vol. 100, Issue 19 https://doi.org/10.1103/PhysRevB.100.195145	journal	November 2019
Complex magnetic order in the decorated spin-chain system Rb 2 Mn 3 ( MoO 4 ) 3 ( OH ) 2 Liu, Yaohua; Sanjeewa, Liurukara D.; Garlea, V. Ovidiu Physical Review B, Vol. 101, Issue 6 https://doi.org/10.1103/PhysRevB.101.064423	journal	February 2020
Floating, critical, and dimerized phases in a frustrated spin- 3 2 chain Chepiga, Natalia; Affleck, Ian; Mila, Frédéric Physical Review B, Vol. 101, Issue 17 https://doi.org/10.1103/PhysRevB.101.174407	journal	May 2020
Long-range magnetic order in quasi-one-dimensional chromium-based ( S = 3 2 ) pyroxenes ( Li , Na ) Cr ( Si , Ge ) 2 O 6 Vasiliev, A. N.; Ignatchik, O. L.; Sokolov, A. N. Physical Review B, Vol. 72, Issue 1 https://doi.org/10.1103/PhysRevB.72.012412	journal	July 2005
Complex magnetic behavior of the sawtooth Fe chains in Rb 2 Fe 2 O(AsO 4 ) 2 Garlea, V. Ovidiu; Sanjeewa, Liurukara D.; McGuire, Michael A. Physical Review B, Vol. 89, Issue 1 https://doi.org/10.1103/PhysRevB.89.014426	journal	January 2014
Magnetic correlations of the quasi-one-dimensional half-integer spin-chain antiferromagnets Sr M 2 V 2 O 8 ( M = Co, Mn) Bera, A. K.; Lake, B.; Stein, W. -D. Physical Review B, Vol. 89, Issue 9 https://doi.org/10.1103/PhysRevB.89.094402	journal	March 2014
Emergent 1/3 magnetization plateaus in pyroxene CoGeO3 Guo, H.; Zhao, L.; Baenitz, M. Physical Review Research, Vol. 3, Issue 3 https://doi.org/10.1103/PhysRevResearch.3.L032037	journal	August 2021
Zigzag magnetic order and possible Kitaev interactions in the spin-1 honeycomb lattice KNiAsO4 Taddei, K. M.; Garlea, V. O.; Samarakoon, A. M. Physical Review Research, Vol. 5, Issue 1 https://doi.org/10.1103/PhysRevResearch.5.013022	journal	January 2023
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Expanding Lorentz and spectrum corrections to large volumes of reciprocal space for single-crystal time-of-flight neutron diffraction Michels-Clark, Tara M.; Savici, Andrei T.; Lynch, Vickie E. Journal of Applied Crystallography, Vol. 49, Issue 2 https://doi.org/10.1107/S1600576716001369	journal	March 2016
Implementation of cross correlation for energy discrimination on the time-of-flight spectrometer CORELLI Ye, Feng; Liu, Yaohua; Whitfield, Ross Journal of Applied Crystallography, Vol. 51, Issue 2 https://doi.org/10.1107/S160057671800403X	journal	March 2018
Symmetry-Based Computational Tools for Magnetic Crystallography Perez-Mato, J. M.; Gallego, S. V.; Tasci, E. S. Annual Review of Materials Research, Vol. 45, Issue 1 https://doi.org/10.1146/annurev-matsci-070214-021008	journal	July 2015
Jana2020 – a new version of the crystallographic computing system Jana Petříček, Václav; Palatinus, Lukáš; Plášil, Jakub Zeitschrift für Kristallographie - Crystalline Materials, Vol. 238, Issue 7-8 https://doi.org/10.1515/zkri-2023-0005	journal	April 2023
Bilbao Crystallographic Server: I. Databases and crystallographic computing programs Aroyo, Mois Ilia; Perez-Mato, Juan Manuel; Capillas, Cesar Zeitschrift für Kristallographie - Crystalline Materials, Vol. 221, Issue 1 https://doi.org/10.1524/zkri.2006.221.1.15	journal	January 2006
SrNi(VO4)(OH): The High-Temperature Hydrothermal Synthesis and Magnetic Properties of an Adelite-Descloizite-Type Structure Sanjeewa, Liurukara D.; Pellizzeri, Tiffany M. Smith; McMillen, Colin D. Crystals, Vol. 12, Issue 10 https://doi.org/10.3390/cryst12101360	journal	September 2022

Similar Records

NaCo₂(SeO₃)₂(OH): competing magnetic ground states of a new sawtooth structure with 3d⁷ Co²⁺ ions

Journal Article · Sun Jul 10 20:00:00 EDT 2022 · Inorganic Chemistry Frontiers (Online) · OSTI ID:1883685

Field tunable magnetic transitions of CsCo₂(MoO₄)₂(OH): a triangular chain structure with a frustrated geometry

Journal Article · Sun Feb 12 19:00:00 EST 2023 · Materials Chemistry Frontiers · OSTI ID:1961941

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Large magnetic anisotropy of a decorated spin-chain system K2Co3(MoO4)3(OH)2

Citation Formats

References (46)

Similar Records

Related Subjects

Large magnetic anisotropy of a decorated spin-chain system K₂Co₃(MoO₄)₃(OH)₂