Engineered $\mathrm{Ru}$ on $\mathrm{HY}$ zeolite catalyst for continuous and selective hydrodeoxygenation of lignin phenolics to cycloalkanes under moderate conditions

Adarsh Kumar, Fnu; Kumar, Abhishek; Santosa, Daniel M.; Wang, Huamin; Zuo, Peng; Wang, Chongmin; Mittal, Ashutosh; Gieleciak, Rafal; Klein, Darryl P.; Manto, Michael; Yang, Bin

doi:10.1016/j.apcata.2024.119649

Engineered $$\mathrm{Ru}$$ on $$\mathrm{HY}$$ zeolite catalyst for continuous and selective hydrodeoxygenation of lignin phenolics to cycloalkanes under moderate conditions

Journal Article · Fri Mar 01 00:00:00 EST 2024 · Applied Catalysis. A, General

DOI:https://doi.org/10.1016/j.apcata.2024.119649· OSTI ID:2322501

Adarsh Kumar, Fnu ^[1]; Kumar, Abhishek ^[2]; Santosa, Daniel M. ^[2]; Wang, Huamin ^[2]; Zuo, Peng ^[3]; ^[3]; Mittal, Ashutosh ^[4]; Gieleciak, Rafal ^[5]; Klein, Darryl P. ^[6]; ^[6]; Yang, Bin ^[7]

Washington State University, Richland, WA (United States); National Renewable Energy Laboratory (NREL), Golden, CO (United States). Renewable Resources and Enabling Science Center
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)
National Renewable Energy Laboratory (NREL), Golden, CO (United States). Renewable Resources and Enabling Science Center
Natural Resources Canada, Devon (Canada)
Advanced Refining Technologies, LLC, Baltimore, MD (United States)
Washington State University, Richland, WA (United States)

Here we report a continuous selective hydrodeoxygenation (HDO) process of guaiacol conversion to cycloalkanes under 180 °C/1 MPa, which results in improved HDO chemistry for lignin-based jet fuel production. The incipient wetness impregnation method was modified to prepare an HY zeolite-supported Ru catalyst with better metal dispersion and acid site uniformity, which overcomes the low conversion and selectivity of previous literature. The modified catalyst (Ru-HY-60-MI) was tested in a continuous fixed bed reactor, resulting in increased HDO conversion of guaiacol to cycloalkanes compared to the unmodified catalyst. Pressure, temperature, and weight hourly space velocity-dependent tests validate guaiacol HDO over Ru-HY-60-MI catalyzed ring hydrogenation of guaiacol to 2-methoxycyclohexanol, acid-catalyzed demethoxylation and dehydration to cyclohexene, and further hydrogenation of cyclohexene to cyclohexane. These experiments enable exploring a continuous HDO process, demonstrate effectiveness for other ß-ß and a-O-4 lignin representatives and real lignin bio-oil, and pave the way towards commercialization of lignin-based jet fuel

View Accepted Manuscript (DOE)

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC05-76RL01830; AC36-08GO28308; EE0008250; EE0009257

OSTI ID:: 2322501

Alternate ID(s):: OSTI ID: 2320300
OSTI ID: 2329444

Report Number(s):: NREL/JA--2800-89356; PNNL-SA--195736

Journal Information:: Applied Catalysis. A, General, Journal Name: Applied Catalysis. A, General Vol. 676; ISSN 0926-860X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (78)

Experimental and First-Principles Evidence for Interfacial Activity of Ru/TiO ₂ for the Direct Conversion of m -Cresol to Toluene Omotoso, Taiwo O.; Baek, Byeongjin; Grabow, Lars C. ChemCatChem, Vol. 9, Issue 14 https://doi.org/10.1002/cctc.201700157	journal	July 2017
Vapor-Phase Hydrodeoxygenation of Guaiacol to Aromatics over Pt/HBeta: Identification of the Role of Acid Sites and Metal Sites on the Reaction Pathway Nie, Lei; Peng, Bo; Zhu, Xinli ChemCatChem, Vol. 10, Issue 5 https://doi.org/10.1002/cctc.201701413	journal	February 2018
Production of Jet Fuel-Range Hydrocarbons from Hydrodeoxygenation of Lignin over Super Lewis Acid Combined with Metal Catalysts Wang, Hongliang; Wang, Huamin; Kuhn, Eric ChemSusChem, Vol. 11, Issue 1 https://doi.org/10.1002/cssc.201701567	journal	November 2017
Tandem Hydrogenolysis–Hydrogenation of Lignin‐Derived Oxygenates over Integrated Dual Catalysts with Optimized Interoperations Fang, Huihuang; Chen, Weikun; Li, Shuang ChemSusChem, Vol. 12, Issue 23 https://doi.org/10.1002/cssc.201902029	journal	November 2019
Elucidating the Reaction Pathways of Veratrylglycero‐β‐Guaiacyl Ether Degradation over Metal‐Free Solid Acid Catalyst with Hydrogen** Ruan, Hao; Xu, Zhangyang; Kumar, Adarsh ChemSusChem, Vol. 16, Issue 6 https://doi.org/10.1002/cssc.202202001	journal	January 2023
Development of Bifunctional Hydrodeoxygenation Catalyst Rh‐HY for the Generation of Biomass‐Derived High‐Energy‐Density Fuels Granados Fócil, Andrés A.; Granados Fócil, Sergio; Conde Sotelo, Víctor M. Energy Technology, Vol. 7, Issue 6 https://doi.org/10.1002/ente.201801112	journal	April 2019
Design of ruthenium-zeolite nanocomposites for enhanced hydrocarbon synthesis from syngas Pedrolo, Débora R. Strossi; Ordomsky, Vitaly V.; Schwaab, Marcio Journal of Materials Science, Vol. 56, Issue 32 https://doi.org/10.1007/s10853-021-06457-1	journal	August 2021
Highly selective catalytic hydrodeoxygenation of guaiacol to cyclohexane over Pt/TiO2 and NiMo/Al2O3 catalysts He, Zhong; Wang, Xianqin Frontiers of Chemical Science and Engineering, Vol. 8, Issue 3 https://doi.org/10.1007/s11705-014-1435-9	journal	August 2014
Hydrodeoxygenation of guaiacol as model compound for pyrolysis oil on transition metal phosphide hydroprocessing catalysts Zhao, H. Y.; Li, D.; Bui, P. Applied Catalysis A: General, Vol. 391, Issue 1-2 https://doi.org/10.1016/j.apcata.2010.07.039	journal	January 2011
Vapor-phase hydrodeoxygenation of guaiacol on Al-MCM-41 supported Ni and Co catalysts Tran, Nga T. T.; Uemura, Yoshimitsu; Chowdhury, Sujan Applied Catalysis A: General, Vol. 512 https://doi.org/10.1016/j.apcata.2015.12.021	journal	February 2016
Hydrodeoxygenation of guaiacol over Ni@Pd and Ni@Pt bimetallic overlayer catalysts Lai, Qinghua; Zhang, Chen; Holles, Joseph H. Applied Catalysis A: General, Vol. 528 https://doi.org/10.1016/j.apcata.2016.09.009	journal	November 2016
Product tunable behavior of carbon nanotubes-supported Ni–Fe catalysts for guaiacol hydrodeoxygenation Fang, Huihuang; Zheng, Jianwei; Luo, Xiaolin Applied Catalysis A: General, Vol. 529 https://doi.org/10.1016/j.apcata.2016.10.011	journal	January 2017
Hydrodeoxygenation of guaiacol as a model compound of bio-oil in methanol over mesoporous noble metal catalysts Roldugina, E. A.; Naranov, E. R.; Maximov, A. L. Applied Catalysis A: General, Vol. 553 https://doi.org/10.1016/j.apcata.2018.01.008	journal	March 2018
Vapor-phase hydrodeoxygenation of guaiacol over carbon-supported Pd, Re and PdRe catalysts Thompson, Simon T.; Lamb, H. Henry Applied Catalysis A: General, Vol. 563 https://doi.org/10.1016/j.apcata.2018.06.031	journal	August 2018
Gas-phase hydrodeoxygenation of guaiacol over iron-based catalysts. Effect of gases composition, iron load and supports (silica and activated carbon) Olcese, R.; Bettahar, M. M.; Malaman, B. Applied Catalysis B: Environmental, Vol. 129 https://doi.org/10.1016/j.apcatb.2012.09.043	journal	January 2013
Highly-dispersed Ni on BEA catalyst prepared by ion-exchange-deposition-precipitation for improved hydrodeoxygenation activity Yan, Penghui; Mensah, Jim; Adesina, Adesoji Applied Catalysis B: Environmental, Vol. 267 https://doi.org/10.1016/j.apcatb.2020.118690	journal	June 2020
Role of metal support during ru-catalysed hydrodeoxygenation of biocrude oil Yan, Penghui; Mensah, Jim; Drewery, Matthew Applied Catalysis B: Environmental, Vol. 281 https://doi.org/10.1016/j.apcatb.2020.119470	journal	February 2021
Hydrodeoxygenation of guaiacol via in situ H2 generated through a water gas shift reaction over dispersed NiMoS catalysts from oil-soluble precursors: Tuning the selectivity towards cyclohexene Vutolkina, A. V.; Baigildin, I. G.; Glotov, A. P. Applied Catalysis B: Environmental, Vol. 312 https://doi.org/10.1016/j.apcatb.2022.121403	journal	September 2022
From biomass to advanced bio-fuel by catalytic pyrolysis/hydro-processing: Hydrodeoxygenation of bio-oil derived from biomass catalytic pyrolysis Wang, Yuxin; He, Tao; Liu, Kaituo Bioresource Technology, Vol. 108 https://doi.org/10.1016/j.biortech.2011.12.132	journal	March 2012
From lignin to valuable products–strategies, challenges, and prospects Wang, Hongliang; Pu, Yunqiao; Ragauskas, Arthur Bioresource Technology, Vol. 271 https://doi.org/10.1016/j.biortech.2018.09.072	journal	January 2019
Catalytic roles of metals and supports on hydrodeoxygenation of lignin monomer guaiacol Lee, Cho Rim; Yoon, Ji Sun; Suh, Young-Woong Catalysis Communications, Vol. 17 https://doi.org/10.1016/j.catcom.2011.10.011	journal	January 2012
Effect of hydrogen on the cracking mechanisms of cycloalkanes over zeolites Castaño, Pedro; Arandes, José M.; Olazar, Martin Catalysis Today, Vol. 150, Issue 3-4 https://doi.org/10.1016/j.cattod.2009.09.013	journal	March 2010
The use of CoMoS catalysts supported on carbon-coated alumina for hydrodeoxygenation of guaiacol and oleic acid Nikulshin, P. A.; Salnikov, V. A.; Varakin, A. N. Catalysis Today, Vol. 271 https://doi.org/10.1016/j.cattod.2015.07.032	journal	August 2016
Influence on nickel particle size on the hydrodeoxygenation of phenol over Ni/SiO 2 Mortensen, Peter M.; Grunwaldt, Jan-Dierk; Jensen, Peter A. Catalysis Today, Vol. 259 https://doi.org/10.1016/j.cattod.2015.08.022	journal	January 2016
High yield one-pot synthesis of high density and low freezing point jet-fuel-ranged blending from bio-derived phenol and cyclopentanol Nie, Genkuo; Dai, Yiying; Liu, Yanan Chemical Engineering Science, Vol. 207 https://doi.org/10.1016/j.ces.2019.06.050	journal	November 2019
Controlling phenolic hydrodeoxygenation by tailoring metal–O bond strength via specific catalyst metal type and particle size selection Duong, Nhung; Tan, Qiaohua; Resasco, Daniel E. Comptes Rendus Chimie, Vol. 21, Issue 3-4 https://doi.org/10.1016/j.crci.2017.07.008	journal	March 2018
Hydrodeoxygenation of lignin-derived phenolic compounds over bi-functional Ru/H-Beta under mild conditions Yao, Gang; Wu, Guangjun; Dai, Weili Fuel, Vol. 150 https://doi.org/10.1016/j.fuel.2015.02.035	journal	June 2015
Guaiacol hydrodeoxygenation as a model for lignin upgrading. Role of the support surface features on Ni-based alumina-silica catalysts Broglia, Francesca; Rimoldi, Luca; Meroni, Daniela Fuel, Vol. 243 https://doi.org/10.1016/j.fuel.2019.01.157	journal	May 2019
Gas-phase hydrodeoxygenation (HDO) of guaiacol over Pt/Al2O3 catalyst promoted by Nb2O5 Silva, Nathacha Kare G.; Ferreira, Rondinele A. R.; Ribas, Rogério M. Fuel, Vol. 287 https://doi.org/10.1016/j.fuel.2020.119509	journal	March 2021
Hydrodeoxygenation of guaiacol as a model compound of pyrolysis lignin-oil over NiCo bimetallic catalyst: Reactivity and kinetic study Tian, Zhipeng; Liang, Xuebin; Li, Rongxuan Fuel, Vol. 308 https://doi.org/10.1016/j.fuel.2021.122034	journal	January 2022
Lignin-based jet fuel and its blending effect with conventional jet fuel Yang, Zhibin; Xu, Zhangyang; Feng, Maoqi Fuel, Vol. 321 https://doi.org/10.1016/j.fuel.2022.124040	journal	August 2022
Hydrogenation of benzene and toluene over size controlled Pt/SBA-15 catalysts: Elucidation of the Pt particle size effect on reaction kinetics Pushkarev, Vladimir V.; An, Kwangjin; Alayoglu, Selim Journal of Catalysis, Vol. 292 https://doi.org/10.1016/j.jcat.2012.04.022	journal	August 2012
Carbon-supported bimetallic Pd–Fe catalysts for vapor-phase hydrodeoxygenation of guaiacol Sun, Junming; Karim, Ayman M.; Zhang, He Journal of Catalysis, Vol. 306 https://doi.org/10.1016/j.jcat.2013.05.020	journal	October 2013
Active sites of Ni2P/SiO2 catalyst for hydrodeoxygenation of guaiacol: A joint XAFS and DFT study Moon, Ji-Sue; Kim, Eung-Gun; Lee, Yong-Kul Journal of Catalysis, Vol. 311 https://doi.org/10.1016/j.jcat.2013.11.023	journal	March 2014
Titania-supported gold-based nanoparticles efficiently catalyze the hydrodeoxygenation of guaiacol Nguyen, Thanh-Son; Laurenti, Dorothée; Afanasiev, Pavel Journal of Catalysis, Vol. 344 https://doi.org/10.1016/j.jcat.2016.09.016	journal	December 2016
Quantification of acid site densities on zeolites in the presence of solvents via determination of extinction coefficients of adsorbed pyridine Gould, Nicholas S.; Xu, Bingjun Journal of Catalysis, Vol. 358 https://doi.org/10.1016/j.jcat.2017.11.016	journal	February 2018
Hydrodeoxygenation of guiacol over ion-exchanged ruthenium ZSM-5 and BEA zeolites Yan, Penghui; Kennedy, Eric; Stockenhuber, Michael Journal of Catalysis, Vol. 396 https://doi.org/10.1016/j.jcat.2021.02.013	journal	April 2021
Spray pyrolysis synthesis of bimetallic NiMo/Al2O3–TiO2 catalyst for hydrodeoxygenation of guaiacol: Effects of bimetallic composition and reduction temperature Phan, Dieu-Phuong; Vo, The Ky; Le, Van Nhieu Journal of Industrial and Engineering Chemistry, Vol. 83 https://doi.org/10.1016/j.jiec.2019.12.008	journal	March 2020
Utilization of lignin: A sustainable and eco-friendly approach Kumar, Adarsh; Kumar, Jitendra Journal of the Energy Institute, Vol. 93, Issue 1 https://doi.org/10.1016/j.joei.2019.03.005	journal	February 2020
Hydrodeoxygenation of guaiacol into cyclohexane over mesoporous silica supported Ni–ZrO2 catalyst López, Mónica; Palacio, Ruben; Mamede, Anne-Sophie Microporous and Mesoporous Materials, Vol. 309 https://doi.org/10.1016/j.micromeso.2020.110452	journal	December 2020
Shape selectivity of zeolite catalysts for the hydrodeoxygenation of biocrude oil and its model compounds Yan, Penghui; Bryant, Glenn; Li, Molly Meng-Jung Microporous and Mesoporous Materials, Vol. 309 https://doi.org/10.1016/j.micromeso.2020.110561	journal	December 2020
Ruthenium nanoparticles supported on zeolite Y as an efficient catalyst for selective hydrogenation of xylose to xylitol Mishra, Dinesh Kumar; Dabbawala, Aasif Asharaf; Hwang, Jin-Soo Journal of Molecular Catalysis A: Chemical, Vol. 376 https://doi.org/10.1016/j.molcata.2013.04.011	journal	September 2013
BTX from the gas-phase hydrodeoxygenation and transmethylation of guaiacol at room pressure Xu, Xiwei; Jiang, Enchen; Du, Yanhong Renewable Energy, Vol. 96 https://doi.org/10.1016/j.renene.2016.04.094	journal	October 2016
Hydrodeoxygenation of m-Cresol over Ru based catalysts: Influence of catalyst support on m-Cresol conversion and methylcyclohexane selectivity Kumar, Adarsh; Kumar, Avnish; Biswas, Bijoy Renewable Energy, Vol. 151 https://doi.org/10.1016/j.renene.2019.11.076	journal	May 2020
Catalytic routes for the conversion of lignocellulosic biomass to aviation fuel range hydrocarbons Wang, Hongliang; Yang, Bin; Zhang, Qian Renewable and Sustainable Energy Reviews, Vol. 120 https://doi.org/10.1016/j.rser.2019.109612	journal	March 2020
Lignin Biorefinery: New Horizons in Catalytic Hydrodeoxygenation for the Production of Chemicals Kumar, Adarsh; Jindal, Meenu; Maharana, Sonita Energy & Fuels, Vol. 35, Issue 21 https://doi.org/10.1021/acs.energyfuels.1c01651	journal	July 2021
Catalytic Hydrodeoxygenation of Guaiacol over Palladium Catalyst on Different Titania Supports Lu, Mohong; Du, Hu; Wei, Bin Energy & Fuels, Vol. 31, Issue 10 https://doi.org/10.1021/acs.energyfuels.7b01498	journal	September 2017
Hydrodeoxygenation of Guaiacol on Ru Catalysts: Influence of TiO ₂ –ZrO ₂ Composite Oxide Supports Lu, Mohong; Du, Hu; Wei, Bin Industrial & Engineering Chemistry Research, Vol. 56, Issue 42 https://doi.org/10.1021/acs.iecr.7b02569	journal	October 2017
Mesoporous ZSM-5 Zeolite-Supported Ru Nanoparticles as Highly Efficient Catalysts for Upgrading Phenolic Biomolecules Wang, Liang; Zhang, Jian; Yi, Xianfeng ACS Catalysis, Vol. 5, Issue 5 https://doi.org/10.1021/acscatal.5b00083	journal	March 2015
Effects of Lignin Structure on Hydrodeoxygenation Reactivity of Pine Wood Lignin to Valuable Chemicals Wang, Hongliang; Ben, Haoxi; Ruan, Hao ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 2 https://doi.org/10.1021/acssuschemeng.6b02563	journal	December 2016
Design of a High-Pressure Flow-Reactor System for Catalytic Hydrodeoxygenation: Guaiacol Conversion Catalyzed by Platinum Supported on MgO Nimmanwudipong, Tarit; Runnebaum, Ron C.; Brodwater, Kevin Energy & Fuels, Vol. 28, Issue 2 https://doi.org/10.1021/ef4020026	journal	January 2014
Hydrocarbon Liquid Production from Biomass via Hot-Vapor-Filtered Fast Pyrolysis and Catalytic Hydroprocessing of the Bio-oil Elliott, Douglas C.; Wang, Huamin; French, Richard Energy & Fuels, Vol. 28, Issue 9 https://doi.org/10.1021/ef501536j	journal	August 2014
Anisole and Guaiacol Hydrodeoxygenation Reaction Pathways over Selected Catalysts Peters, Jonathan E.; Carpenter, John R.; Dayton, David C. Energy & Fuels, Vol. 29, Issue 2 https://doi.org/10.1021/ef502551p	journal	January 2015
Conversion of Guaiacol on Noble Metal Catalysts: Reaction Performance and Deactivation Studies Gao, Danni; Schweitzer, Christopher; Hwang, Hyun Tae Industrial & Engineering Chemistry Research, Vol. 53, Issue 49 https://doi.org/10.1021/ie500495z	journal	March 2014
Platinum Nanoparticle Shape Effects on Benzene Hydrogenation Selectivity Bratlie, Kaitlin M.; Lee, Hyunjoo; Komvopoulos, Kyriakos Nano Letters, Vol. 7, Issue 10 https://doi.org/10.1021/nl0716000	journal	October 2007
Practical Use of Continuous Processing in Developing and Scaling Up Laboratory Processes Anderson, Neal G. Organic Process Research & Development, Vol. 5, Issue 6 https://doi.org/10.1021/op0100605	journal	October 2001
Selective production of arenes via direct lignin upgrading over a niobium-based catalyst Shao, Yi; Xia, Qineng; Dong, Lin Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms16104	journal	July 2017
Selective hydrogenolysis of catechyl lignin into propenylcatechol over an atomically dispersed ruthenium catalyst Wang, Shuizhong; Zhang, Kaili; Li, Helong Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-020-20684-1	journal	January 2021
Solvent-free microwave synthesis of ultra-small Ru-Mo2C@CNT with strong metal-support interaction for industrial hydrogen evolution Wu, Xueke; Wang, Zuochao; Zhang, Dan Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-24322-2	journal	June 2021
Dual metal nanoparticles within multicompartmentalized mesoporous organosilicas for efficient sequential hydrogenation Zou, Houbing; Dai, Jinyu; Suo, Jinquan Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-25226-x	journal	August 2021
Hydrogen spillover assisted by oxygenate molecules over nonreducible oxides Tan, Mingwu; Yang, Yanling; Yang, Ying Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-29045-6	journal	March 2022
Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity van Deelen, Tom W.; Hernández Mejía, Carlos; de Jong, Krijn P. Nature Catalysis, Vol. 2, Issue 11 https://doi.org/10.1038/s41929-019-0364-x	journal	November 2019
Size effects in Atomic-Level Epitaxial Redistribution Process of RuO2 over TiO2 Xiang, Guolei; Shi, Xuejun; Wu, Yulong Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00801	journal	November 2012
Water-based synthesis and cleaning methods for high purity ZnO nanoparticles – comparing acetate, chloride, sulphate and nitrate zinc salt precursors Pourrahimi, A. M.; Liu, D.; Pallon, L. K. H. RSC Adv., Vol. 4, Issue 67 https://doi.org/10.1039/C4RA06651K	journal	January 2014
Biomass-derived lignin to jet fuel range hydrocarbons via aqueous phase hydrodeoxygenation Wang, Hongliang; Ruan, Hao; Pei, Haisheng Green Chemistry, Vol. 17, Issue 12 https://doi.org/10.1039/C5GC01534K	journal	January 2015
ZnCl ₂ induced catalytic conversion of softwood lignin to aromatics and hydrocarbons Wang, Hongliang; Zhang, Libing; Deng, Tiansheng Green Chemistry, Vol. 18, Issue 9 https://doi.org/10.1039/C5GC02967H	journal	January 2016
The role of acid and metal sites in hydrodeoxygenation of guaiacol over Ni/Beta catalysts Yan, Penghui; Li, Molly Meng-Jung; Kennedy, Eric Catalysis Science & Technology, Vol. 10, Issue 3 https://doi.org/10.1039/C9CY01970G	journal	January 2020
Insights into the catalytic activity of Ru/NaY catalysts for efficient H₂ production through aqueous phase reforming Gogoi, Pranjal; Nagpure, Atul S.; Kandasamy, Prabu Sustainable Energy & Fuels, Vol. 4, Issue 2 https://doi.org/10.1039/C9SE00797K	journal	January 2020
Natural zeolite supported Ni catalysts for hydrodeoxygenation of anisole Yan, Penghui; Kennedy, Eric; Stockenhuber, Michael Green Chemistry, Vol. 23, Issue 13 https://doi.org/10.1039/D0GC04377J	journal	January 2021
Hydrodeoxygenation of guaiacol over orthorhombic molybdenum carbide: a DFT and microkinetic study Agrawal, Kushagra; Roldan, Alberto; Kishore, Nanda Catalysis Science & Technology, Vol. 12, Issue 3 https://doi.org/10.1039/D1CY01273H	journal	January 2022
Hydrodeoxygenation of lignin derived phenolics over a hydrous ruthenium oxide based catalyst(s): role of surface water molecules and acidity of the support Kumar, Adarsh; Thallada, Bhaskar Sustainable Energy & Fuels, Vol. 5, Issue 15 https://doi.org/10.1039/D1SE00102G	journal	January 2021
Noble-metal catalyzed hydrodeoxygenation of biomass-derived lignin to aromatic hydrocarbons Laskar, Dhrubojyoti D.; Tucker, Melvin P.; Chen, Xiaowen Green Chemistry, Vol. 16, Issue 2 https://doi.org/10.1039/c3gc42041h	journal	January 2014
Effect of palladium precursor and preparation method on the catalytic performance of Pd/SiO ₂ catalysts for benzene hydrogenation Redjel, Afef; Boudjahem, Abdel-Ghani; Bettahar, Mohammed Particulate Science and Technology, Vol. 36, Issue 6 https://doi.org/10.1080/02726351.2017.1295294	journal	March 2017
Catalytic Cracking of Cyclohexane and 1-Hexene Mixtures on Mono-, Bi-, and Tri-Zeolite Catalysts Potapenko, O. V.; Khudyakov, M. S.; Altynkovich, E. O. Kinetics and Catalysis, Vol. 60, Issue 1 https://doi.org/10.1134/S0023158419010117	journal	January 2019
High temperature catalytic hydrogenolysis and alkylation of anisole and phenol Kallury, R. K. M. R.; Tidwell, T. T.; Boocock, D. G. B. Canadian Journal of Chemistry, Vol. 62, Issue 11 https://doi.org/10.1139/v84-434	journal	November 1984
Continuous Catalytic Hydrodeoxygenation of Guaiacol over Pt/SiO2 and Pt/H-MFI-90 Hellinger, Melanie; Baier, Sina; Mortensen, Peter Catalysts, Vol. 5, Issue 3 https://doi.org/10.3390/catal5031152	journal	July 2015
Influence of Cobalt Precursor on Efficient Production of Commercial Fuels over FTS Co/SiC Catalyst de la Osa, Ana; Romero, Amaya; Dorado, Fernando Catalysts, Vol. 6, Issue 7 https://doi.org/10.3390/catal6070098	journal	July 2016
Hollow MFI Zeolite Supported Pt Catalysts for Highly Selective and Stable Hydrodeoxygenation of Guaiacol to Cycloalkanes Niu, Xiaopo; Feng, Fuxiang; Yuan, Gang Nanomaterials, Vol. 9, Issue 3 https://doi.org/10.3390/nano9030362	journal	March 2019

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Engineered $$\mathrm{Ru}$$ on $$\mathrm{HY}$$ zeolite catalyst for continuous and selective hydrodeoxygenation of lignin phenolics to cycloalkanes under moderate conditions

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